Photocatalytic Generation of CarbAnions for Organic Synthesis

Project Information

PHAROS

Grant agreement ID: 741623

DOI

10.3030/741623

Project closed

EC signature date 2 May 2017

Start date 1 September 2017

End date 31 August 2022

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 2 458 200,00

EU contribution

€ 2 458 200,00

Coordinated by

UNIVERSITAET REGENSBURG
Germany

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (26)

Redox-Neutral Photocatalytic C-H Carboxylation of Arenes and Styrenes with CO2

Author(s): Matthias Schmalzbauer, Thomas D. Svejstrup, Florian Fricke, Peter Brandt, Magnus J. Johansson, Giulia Bergonzini, Burkhard Koenig
Published in: Chem, Issue 6, 2020, Page(s) 2658–2672, ISSN 2451-9294
Publisher: Elsevier
DOI: 10.1016/j.chempr.2020.08.022

Effects of Light Intensity and Reaction Temperature on Photoreactions in Commercial Photoreactors

Author(s): Thomas D. Svejstrup, Anamitra Chatterjee, Denis Schekin, Thomas Wagner, Julia Zach, Magnus J. Johansson, Giulia Bergonzini, Burkhard König
Published in: ChemPhotoChem, Issue 5, 2021, Page(s) 808 – 814, ISSN 2367-0932
Publisher: Wiley
DOI: 10.1002/cptc.202100059

Deazaflavin reductive photocatalysis involves excited semiquinone radicals

Author(s): Andreas Graml, Tomáš Neveselý, Roger Jan Kutta, Radek Cibulka, Burkhard König
Published in: Nature Communications, Issue 11/1, 2020, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-020-16909-y

Mizoroki–Heck type reactions and synthesis of 1,4-dicarbonyl compounds by heterogeneous organic semiconductor photocatalysis

Author(s): Jagadish Khamrai, Saikat Das, Aleksandr Savateev, Markus Antonietti, Burkhard König
Published in: Green Chem, Issue 23, 2021, Page(s) 2017 - 2024, ISSN 1463-9262
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0gc03792c

Visible‐Light‐Promoted Metal‐Free Synthesis of (Hetero)Aromatic Nitriles from C(sp 3 )−H Bonds**

Author(s): Kathiravan Murugesan, Karsten Donabauer, Burkhard König
Published in: Angewandte Chemie, Issue 133/5, 2021, Page(s) 2469-2475, ISSN 0044-8249
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202011815

Photo-Induced Thiolate Catalytic Activation of Inert Caryl-Hetero Bondsfor Radical Borylation

Author(s): Shun Wang, Hua Wang, Burkhard Koenig
Published in: Chem, Issue 7, 2021, Page(s) 1653-1665, ISSN 2451-9294
Publisher: Cell Press
DOI: 10.1016/j.chempr.2021.04.016

Photocatalytic synthesis of tetra-substituted furans promoted by carbon dioxide†

Author(s): Ya-Ming Tian, Huaiju Wang, Ritu, Burkhard Koenig
Published in: Chemical Science, Issue 13, 2022, Page(s) 241, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1sc06403g

Photoinitiated Carbonyl-Metathesis: Deoxygenative Reductive Olefination of Aromatic Aldehydes via Photoredox Catalysis

Author(s): Shun Wang, Lokesh Nanjundappa, Johnny Hioe, Ruth Maria Gschwind, Burkhard Koenig
Published in: Chemical Science, 2019, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc00711c

Photocatalytic Barbier reaction – visible-light induced allylation and benzylation of aldehydes and ketones

Author(s): Anna Lucia Berger, Karsten Donabauer, Burkhard König
Published in: Chemical Science, Issue 9/36, 2018, Page(s) 7230-7235, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8sc02038h

Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis

Author(s): Veera Reddy Yatham, Peter Bellotti, Burkhard König
Published in: Chemical Communications, Issue 55/24, 2019, Page(s) 3489-3492, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cc00492k

Controllable Isomerization of Alkenes by Dual Visible-Light-Cobalt Catalysis

Author(s): Qing-Yuan Meng, Tobias Schirmer, Kousuke Katou, Burkhard König
Published in: Angewandte Chemie International Edition, 2019, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201900849

Photocarboxylation of Benzylic C–H Bonds

Author(s): Qing-Yuan Meng, Tobias E. Schirmer, Anna Lucia Berger, Karsten Donabauer, Burkhard König
Published in: Journal of the American Chemical Society, Issue 141/29, 2019, Page(s) 11393-11397, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b05360

Photocatalytic carbanion generation – benzylation of aliphatic aldehydes to secondary alcohols

Author(s): Karsten Donabauer, Mitasree Maity, Anna Lucia Berger, Gregory S. Huff, Stefano Crespi, Burkhard König
Published in: Chemical Science, Issue 10/19, 2019, Page(s) 5162-5166, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc01356c

Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes

Author(s): Indrajit Ghosh, Jagadish Khamrai, Aleksandr Savateev, Nikita Shlapakov, Markus Antonietti, Burkhard König
Published in: Science, Issue 365/6451, 2019, Page(s) 360-366, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.aaw3254

Birch‐Type Photoreduction of Arenes and Heteroarenes by Sensitized Electron Transfer

Author(s): Anamitra Chatterjee, Burkhard König
Published in: Angewandte Chemie International Edition, Issue 58/40, 2019, Page(s) 14289-14294, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201905485

Photochemical Functionalization of Helicenes

Author(s): Martin Jakubec, Indrajit Ghosh, Jan Storch, Burkhard König
Published in: Chemistry – A European Journal, Issue 26/2, 2019, Page(s) 543-547, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201904169

Photocatalytic carbanion generation from C–H bonds – reductant free Barbier/Grignard-type reactions

Author(s): Anna Lucia Berger, Karsten Donabauer, Burkhard König
Published in: Chemical Science, Issue 10/48, 2019, Page(s) 10991-10996, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc04987h

Synthetic Photoelectrochemistry

Author(s): Joshua P. Barham, Burkhard König
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201913767

Photocatalytic Synthesis of Polycyclic Indolones

Author(s): Tanguy Saget, Burkhard König
Published in: Chemistry - A European Journal, 2020, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202001324

Umpolung Difunctionalization of Carbonyls via Visible-Light Photoredox Catalytic Radical-Carbanion Relay

Author(s): Shun Wang, Bei-Yi Cheng, Matea Sršen, Burkhard König
Published in: Journal of the American Chemical Society, 2020, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c00629

Excited State Anions in Organic Transformations

Author(s): Matthias Schmalzbauer, Michela Marcon, and Burkhard Koenig
Published in: Angewandte Chemie, Issue 60, 2021, Page(s) 6270–6292, ISSN 1521-3757
Publisher: Wiley-VCh
DOI: 10.1002/anie.202009288

Photocatalytic (Het)arylation of C(sp3)−H Bonds with Carbon Nitride

Author(s): Saikat Das, Kathiravan Murugesan, Gonzalo J. Villegas Rodríguez, Jaspreet Kaur, Joshua P. Barham, Aleksandr Savateev, Markus Antonietti, Burkhard König
Published in: ACS catalysis, Issue 11, 2021, Page(s) 1593−1603, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.0c05694

Strategies for the Photocatalytic Generation of Carbanion Equivalents for Reductant-Free C−C Bond Formations

Author(s): Karsten Donabauer, Burkhard Koenig
Published in: Acc. Chem. Res., Issue 54, 2021, Page(s) 242−252, ISSN 1520-4898
Publisher: ACS
DOI: 10.1021/acs.accounts.0c00620

N -Arylation of NH -Sulfoximines via Dual Nickel Photocatalysis

Author(s): Alexander Wimmer, Burkhard König
Published in: Organic Letters, Issue 21/8, 2019, Page(s) 2740-2744, ISSN 1523-7060
Publisher: American Chemical Society
DOI: 10.1021/acs.orglett.9b00698

Visible-Light-Promoted Metal-Free Synthesis of (Hetero)AromaticNitriles from C(sp3)-H Bonds

Author(s): Kathiravan Murugesan, Karsten Donabauer, Burkhard Koenig
Published in: Angewandte Chemie, Issue 60, 2021, Page(s) 2439-2445, ISSN 1521-3773
Publisher: Wiley
DOI: 10.1002/anie.202011815

Photocatalytic Reductive Radical‐Polar Crossover for a Base‐Free Corey–Seebach Reaction

Author(s): Karsten Donabauer, Kathiravan Murugesan, Urša Rozman, Stefano Crespi, Burkhard König
Published in: Chemistry – A European Journal, 2020, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202003000