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Nanopores for New Molecular Nitrogen Chemistry

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Publications

Confinement of Iodine Molecules into Triple-Helical Chains within Robust Metal–Organic Frameworks

Author(s): Xinran Zhang, Ivan da Silva, Harry G. W. Godfrey, Samantha K. Callear, Sergey A. Sapchenko, Yongqiang Cheng, Inigo Vitórica-Yrezábal, Mark D. Frogley, Gianfelice Cinque, Chiu C. Tang, Carlotta Giacobbe, Catherine Dejoie, Svemir Rudić, Anibal J. Ramirez-Cuesta, Melissa A. Denecke, Sihai Yang, Martin Schröder
Published in: Journal of the American Chemical Society, Issue 139/45, 2017, Page(s) 16289-16296, ISSN 0002-7863
DOI: 10.1021/jacs.7b08748

Porous Metal–Organic Polyhedral Frameworks with Optimal Molecular Dynamics and Pore Geometry for Methane Storage

Author(s): Yong Yan, Daniil I. Kolokolov, Ivan da Silva, Alexander G. Stepanov, Alexander J. Blake, Anne Dailly, Pascal Manuel, Chiu C. Tang, Sihai Yang, Martin Schröder
Published in: Journal of the American Chemical Society, Issue 139/38, 2017, Page(s) 13349-13360, ISSN 0002-7863
DOI: 10.1021/jacs.7b05453

Supramolecular networks stabilise and functionalise black phosphorus

Author(s): Vladimir V. Korolkov, Ivan G. Timokhin, Rolf Haubrichs, Emily F. Smith, Lixu Yang, Sihai Yang, Neil R. Champness, Martin Schröder, Peter H. Beton
Published in: Nature Communications, Issue 8/1, 2017, ISSN 2041-1723
DOI: 10.1038/s41467-017-01797-6

Unusual and Tunable Negative Linear Compressibility in the Metal–Organic Framework MFM-133(M) (M = Zr, Hf)

Author(s): Yong Yan, Alice E. O’Connor, Gopikkaa Kanthasamy, George Atkinson, David R. Allan, Alexander J. Blake, Martin Schröder
Published in: Journal of the American Chemical Society, Issue 140/11, 2018, Page(s) 3952-3958, ISSN 0002-7863
DOI: 10.1021/jacs.7b11747

Reversible adsorption of nitrogen dioxide within a robust porous metal–organic framework

Author(s): Xue Han, Harry G. W. Godfrey, Lydia Briggs, Andrew J. Davies, Yongqiang Cheng, Luke L. Daemen, Alena M. Sheveleva, Floriana Tuna, Eric J. L. McInnes, Junliang Sun, Christina Drathen, Michael W. George, Anibal J. Ramirez-Cuesta, K. Mark Thomas, Sihai Yang, Martin Schröder
Published in: Nature Materials, Issue 17/8, 2018, Page(s) 691-696, ISSN 1476-1122
DOI: 10.1038/s41563-018-0104-7

Locating the binding domains in a highly selective mixed matrix membrane via synchrotron IR microspectroscopy

Author(s): Nicholas M. Jacques, Peter R. E. Rought, Detlev Fritsch, Mathew Savage, Harry G. W. Godfrey, Lei Li, Tamoghna Mitra, Mark D. Frogley, Gianfelice Cinque, Sihai Yang, Martin Schröder
Published in: Chemical Communications, Issue 54/23, 2018, Page(s) 2866-2869, ISSN 1359-7345
DOI: 10.1039/c7cc08932e

Enhancement of CO 2 Uptake and Selectivity in a Metal–Organic Framework by the Incorporation of Thiophene Functionality

Author(s): Vsevolod A. Bolotov, Konstantin A. Kovalenko, Denis G. Samsonenko, Xue Han, Xinran Zhang, Gemma L. Smith, Laura J. MCormick, Simon J. Teat, Sihai Yang, Matthew J. Lennox, Alice Henley, Elena Besley, Vladimir P. Fedin, Danil N. Dybtsev, Martin Schröder
Published in: Inorganic Chemistry, Issue 57/9, 2018, Page(s) 5074-5082, ISSN 0020-1669
DOI: 10.1021/acs.inorgchem.8b00138

Characterisation of redox states of metal–organic frameworks by growth on modified thin-film electrodes

Author(s): Tamoghna Mitra, Florian Moreau, Adam Nevin, Carlo U. Perotto, Alex Summerfield, E. Stephen Davies, Elizabeth A. Gibson, Timothy L. Easun, Martin Schröder
Published in: Chemical Science, Issue 9/31, 2018, Page(s) 6572-6579, ISSN 2041-6520
DOI: 10.1039/c8sc00803e

Direct observation of supramolecular binding of light hydrocarbons in vanadium( iii ) and ( iv ) metal–organic framework materials

Author(s): Zhenzhong Lu, Harry G. W. Godfrey, Ivan da Silva, Yongqiang Cheng, Mathew Savage, Pascal Manuel, Svemir Rudić, Anibal J. Ramirez-Cuesta, Sihai Yang, Martin Schröder
Published in: Chemical Science, Issue 9/13, 2018, Page(s) 3401-3408, ISSN 2041-6520
DOI: 10.1039/c8sc00330k

Polycatenated 2D Hydrogen-Bonded Binary Supramolecular Organic Frameworks (SOFs) with Enhanced Gas Adsorption and Selectivity

Author(s): Jian Lü, Cristina Perez-Krap, Fabien Trousselet, Yong Yan, Nada H. Alsmail, Bahar Karadeniz, Nicholas M. Jacques, William Lewis, Alexander J. Blake, François-Xavier Coudert, Rong Cao, Martin Schröder
Published in: Crystal Growth & Design, Issue 18/4, 2018, Page(s) 2555-2562, ISSN 1528-7483
DOI: 10.1021/acs.cgd.8b00153

High Volumetric Hydrogen Adsorption in a Porous Anthracene-Decorated Metal–Organic Framework

Author(s): Yong Yan, Ivan da Silva, Alexander J. Blake, Anne Dailly, Pascal Manuel, Sihai Yang, Martin Schröder
Published in: Inorganic Chemistry, Issue 57/19, 2018, Page(s) 12050-12055, ISSN 0020-1669
DOI: 10.1021/acs.inorgchem.8b01607

Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Framework

Author(s): Harry G. W. Godfrey, Ivan da Silva, Lydia Briggs, Joseph H. Carter, Christopher G. Morris, Mathew Savage, Timothy L. Easun, Pascal Manuel, Claire A. Murray, Chiu C. Tang, Mark D. Frogley, Gianfelice Cinque, Sihai Yang, Martin Schröder
Published in: Angewandte Chemie International Edition, Issue 57/45, 2018, Page(s) 14778-14781, ISSN 1433-7851
DOI: 10.1002/anie.201808316

Host–guest selectivity in a series of isoreticular metal–organic frameworks: observation of acetylene-to-alkyne and carbon dioxide-to-amide interactions

Author(s): Jack D. Humby, Oguarabau Benson, Gemma L. Smith, Stephen P. Argent, Ivan da Silva, Yongqiang Cheng, Svemir Rudić, Pascal Manuel, Mark D. Frogley, Gianfelice Cinque, Lucy K. Saunders, Iñigo J. Vitórica-Yrezábal, George F. S. Whitehead, Timothy L. Easun, William Lewis, Alexander J. Blake, Anibal J. Ramirez-Cuesta, Sihai Yang, Martin Schröder
Published in: Chemical Science, Issue 10/4, 2019, Page(s) 1098-1106, ISSN 2041-6520
DOI: 10.1039/c8sc03622e

Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework

Author(s): Joseph H. Carter, Xue Han, Florian Y. Moreau, Ivan da Silva, Adam Nevin, Harry G. W. Godfrey, Chiu C. Tang, Sihai Yang, Martin Schröder
Published in: Journal of the American Chemical Society, Issue 140/46, 2018, Page(s) 15564-15567, ISSN 0002-7863
DOI: 10.1021/jacs.8b08433

Enhancement of Proton Conductivity in Nonporous Metal–Organic Frameworks: The Role of Framework Proton Density and Humidity

Author(s): Simona Pili, Peter Rought, Daniil I. Kolokolov, Longfei Lin, Ivan da Silva, Yongqiang Cheng, Christopher Marsh, Ian P. Silverwood, Victoria García Sakai, Ming Li, Jeremy J. Titman, Lyndsey Knight, Luke L. Daemen, Anibal J. Ramirez-Cuesta, Chiu C. Tang, Alexander G. Stepanov, Sihai Yang, Martin Schröder
Published in: Chemistry of Materials, Issue 30/21, 2018, Page(s) 7593-7602, ISSN 0897-4756
DOI: 10.1021/acs.chemmater.8b02765

Optimal Binding of Acetylene to a Nitro-Decorated Metal–Organic Framework

Author(s): Thien D. Duong, Sergey A. Sapchenko, Ivan da Silva, Harry G. W. Godfrey, Yongqiang Cheng, Luke L. Daemen, Pascal Manuel, Anibal J. Ramirez-Cuesta, Sihai Yang, Martin Schröder
Published in: Journal of the American Chemical Society, Issue 140/47, 2018, Page(s) 16006-16009, ISSN 0002-7863
DOI: 10.1021/jacs.8b08504

Modulating proton diffusion and conductivity in metal–organic frameworks by incorporation of accessible free carboxylic acid groups

Author(s): Peter Rought, Christopher Marsh, Simona Pili, Ian P. Silverwood, Victoria García Sakai, Ming Li, Martyn S. Brown, Stephen P. Argent, Inigo Vitorica-Yrezabal, George Whitehead, Mark R. Warren, Sihai Yang, Martin Schröder
Published in: Chemical Science, 2019, ISSN 2041-6520
DOI: 10.1039/c8sc03022g

Post-synthetic modulation of the charge distribution in a metal–organic framework for optimal binding of carbon dioxide and sulfur dioxide

Author(s): Lei Li, Ivan da Silva, Daniil I. Kolokolov, Xue Han, Jiangnan Li, Gemma Smith, Yongqiang Cheng, Luke L. Daemen, Christopher G. Morris, Harry G. W. Godfrey, Nicholas M. Jacques, Xinran Zhang, Pascal Manuel, Mark D. Frogley, Claire A. Murray, Anibal J. Ramirez-Cuesta, Gianfelice Cinque, Chiu C. Tang, Alexander G. Stepanov, Sihai Yang, Martin Schroder
Published in: Chemical Science, 2019, ISSN 2041-6520
DOI: 10.1039/c8sc01959b

Reversible MOF-Based Sensors for the Electrical Detection of Iodine Gas

Author(s): Leo J. Small, Ryan C. Hill, James L. Krumhansl, Mara E. Schindelholz, Zhihengyu Chen, Karena W. Chapman, Xinran Zhang, Sihai Yang, Martin Schröder, Tina M. Nenoff
Published in: ACS Applied Materials & Interfaces, Issue 11/31, 2019, Page(s) 27982-27988, ISSN 1944-8244
DOI: 10.1021/acsami.9b09938

Capture of nitrogen dioxide and conversion to nitric acid in a porous metal–organic framework

Author(s): Jiangnan Li, Xue Han, Xinran Zhang, Alena M. Sheveleva, Yongqiang Cheng, Floriana Tuna, Eric J. L. McInnes, Laura J. McCormick McPherson, Simon J. Teat, Luke L. Daemen, Anibal J. Ramirez-Cuesta, Martin Schröder, Sihai Yang
Published in: Nature Chemistry, Issue 11/12, 2019, Page(s) 1085-1090, ISSN 1755-4330
DOI: 10.1038/s41557-019-0356-0

Integration of mesopores and crystal defects in metal-organic frameworks via templated electrosynthesis

Author(s): Xinchen Kang, Kai Lyu, Lili Li, Jiangnan Li, Louis Kimberley, Bin Wang, Lifei Liu, Yongqiang Cheng, Mark D. Frogley, Svemir Rudić, Anibal J. Ramirez-Cuesta, Robert A. W. Dryfe, Buxing Han, Sihai Yang, Martin Schröder
Published in: Nature Communications, Issue 10/1, 2019, ISSN 2041-1723
DOI: 10.1038/s41467-019-12268-5

Reversible coordinative binding and separation of sulfur dioxide in a robust metal–organic framework with open copper sites

Author(s): Gemma L. Smith, Jennifer E. Eyley, Xue Han, Xinran Zhang, Jiangnan Li, Nicholas M. Jacques, Harry G. W. Godfrey, Stephen P. Argent, Laura J. McCormick McPherson, Simon J. Teat, Yongqiang Cheng, Mark D. Frogley, Gianfelice Cinque, Sarah J. Day, Chiu C. Tang, Timothy L. Easun, Svemir Rudić, Anibal J. Ramirez-Cuesta, Sihai Yang, Martin Schröder
Published in: Nature Materials, Issue 18/12, 2019, Page(s) 1358-1365, ISSN 1476-1122
DOI: 10.1038/s41563-019-0495-0

Analysis by synchrotron X-ray scattering of the kinetics of formation of an Fe-based metal-organic framework with high CO 2 adsorption

Author(s): Harry G. W. Godfrey, Lydia Briggs, Xue Han, William J. F. Trenholme, Christopher G. Morris, Mathew Savage, Louis Kimberley, Oxana V. Magdysyuk, Michael Drakopoulos, Claire A. Murray, Chiu C. Tang, Mark D. Frogley, Gianfelice Cinque, Sihai Yang, Martin Schröder
Published in: APL Materials, Issue 7/11, 2019, Page(s) 111104, ISSN 2166-532X
DOI: 10.1063/1.5121644

Iodine Adsorption in a Redox-Active Metal–Organic Framework: Electrical Conductivity Induced by Host−Guest Charge-Transfer

Author(s): Xinran Zhang, Ivan da Silva, Rodrigo Fazzi, Alena M. Sheveleva, Xue Han, Ben F. Spencer, Sergey A. Sapchenko, Floriana Tuna, Eric J. L. McInnes, Ming Li, Sihai Yang, Martin Schröder
Published in: Inorganic Chemistry, Issue 58/20, 2019, Page(s) 14145-14150, ISSN 0020-1669
DOI: 10.1021/acs.inorgchem.9b02176

Porous metal–organic frameworks as emerging sorbents for clean air

Author(s): Xue Han, Sihai Yang, Martin Schröder
Published in: Nature Reviews Chemistry, Issue 3/2, 2019, Page(s) 108-118, ISSN 2397-3358
DOI: 10.1038/s41570-019-0073-7

Understanding Hysteresis in Carbon Dioxide Sorption in Porous Metal–Organic Frameworks

Author(s): Sergey A. Sapchenko, Marina O. Barsukova, Rodion V. Belosludov, Konstantin A. Kovalenko, Denis G. Samsonenko, Artem S. Poryvaev, Alena M. Sheveleva, Matvey V. Fedin, Artem S. Bogomyakov, Danil N. Dybtsev, Martin Schröder, Vladimir P. Fedin
Published in: Inorganic Chemistry, Issue 58/10, 2019, Page(s) 6811-6820, ISSN 0020-1669
DOI: 10.1021/acs.inorgchem.9b00016

Observation of binding of carbon dioxide to nitro-decorated metal–organic frameworks

Author(s): Thien D. Duong, Sergey A. Sapchenko, Ivan da Silva, Harry G. W. Godfrey, Yongqiang Cheng, Luke L. Daemen, Pascal Manuel, Mark D. Frogley, Gianfelice Cinque, Anibal J. Ramirez-Cuesta, Sihai Yang, Martin Schröder
Published in: Chemical Science, Issue 11/20, 2020, Page(s) 5339-5346, ISSN 2041-6520
DOI: 10.1039/c9sc04294f