Understanding negative gas adsorption in highly porous networks for the design of pressure amplifying materials

Project Information

AMPLIPORE

Grant agreement ID: 742743

DOI 10.3030/742743

Project closed

EC signature date 30 May 2017

Start date 1 September 2017

End date 28 February 2023

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 2 363 125,00

EU contribution € 2 363 125,00

Coordinated by

TECHNISCHE UNIVERSITAET DRESDEN
Germany

Publications

Peer reviewed articles (21)

Unraveling the Guest-Induced Switchability in the Metal-Organic Framework DUT-13(Zn)

Author(s): Bodo Felsner, Volodymyr Bon, Jack D Evans, Friedrich Schwotzer, Ronny Grünker, Irena Senkovska , Stefan Kaskel
Published in: Chemistry Europe, 2021, ISSN 1521-3765
Publisher: Wiley
DOI: 10.1002/chem.202100599

Four-dimensional metal-organic frameworks

Author(s): Jack D. Evans, Volodymyr Bon, Irena Senkovska, Hui-Chun Lee, Stefan Kaskel
Published in: Nature Communications, Issue 11/1, 2020, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-020-16527-8

Charting the Complete Thermodynamic Landscape of Gas Adsorption for a Responsive Metal–Organic Framework

Author(s): Ruben Goeminne, Simon Krause, Stefan Kaskel, Toon Verstraelen, Jack D. Evans
Published in: Journal of the American Chemical Society, 2021, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c00522

Reversible switching between positive and negative thermal expansion in a metal–organic framework DUT-49

Author(s): Bikash Garai,Volodymyr Bon, Anastasia A. Efimova, Martin Gerlach, Irena Senkovska, Stefan Kaskel
Published in: Journal Materials Chemistry A, 2020, ISSN 2050-7488
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0ta06830f

Engineering micromechanics of soft porous crystals for negative gas adsorption

Author(s): Simon Krause, Jack D. Evans, Volodymyr Bon, Irena Senkovska, Sebastian Ehrling, Paul Iacomi, Daniel M. Többens, Dirk Wallacher, Manfred S. Weiss, Bin Zheng, Pascal G. Yot, Guillaume Maurin, Philip L. Llewellyn, François-Xavier Coudert, Stefan Kaskel
Published in: Chemical Science, Issue 11/35, 2020, Page(s) 9468-9479, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0sc03727c

Chemically Stable Carbazole-Based Imine Covalent Organic Frameworks with Acidochromic Response for Humidity Control Applications.

Author(s): L. H. Gilmanova; Volodymyr Bon; Leonid Shupletsov; Darius Pohl; Marcus Rauche; Eike Brunner; Stefan Kaskel
Published in: Journal of the American Chemical Society (JACS), Issue 6, 2021, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c07148

Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks

Author(s): Simon Krause, Jack D. Evans, Volodymyr Bon, Irena Senkovska, Paul Iacomi, Felicitas Kolbe, Sebastian Ehrling, Erik Troschke, Jürgen Getzschmann, Daniel M. Többens, Alexandra Franz, Dirk Wallacher, Pascal G. Yot, Guillaume Maurin, Eike Brunner, Philip L. Llewellyn, François-Xavier Coudert, Stefan Kaskel
Published in: Nature Communications, Issue 10/1, 2019, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-019-11565-3

Exploring the thermodynamic criteria for responsive adsorption processes

Author(s): Jack D. Evans, Simon Krause, Stefan Kaskel, Martin B. Sweatman, Lev Sarkisov
Published in: Chemical Science, 2019, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9sc01299k

Adsorption Contraction Mechanics: Understanding Breathing Energetics in Isoreticular Metal–Organic Frameworks

Author(s): Simon Krause, Jack D. Evans, Volodymyr Bon, Irena Senkovska, Sebastian Ehrling, Ulrich Stoeck, Pascal G. Yot, Paul Iacomi, Philip Llewellyn, Guillaume Maurin, François-Xavier Coudert, Stefan Kaskel
Published in: The Journal of Physical Chemistry C, Issue 122/33, 2018, Page(s) 19171-19179, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.8b04549

The effect of crystallite size on pressure amplification in switchable porous solids

Author(s): Simon Krause, Volodymyr Bon, Irena Senkovska, Daniel M. Többens, Dirk Wallacher, Renjith S. Pillai, Guillaume Maurin, Stefan Kaskel
Published in: Nature Communications, Issue 9/1, 2018, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-018-03979-2

New insights into solvent-induced structural changes of 13 C labelled metal–organic frameworks by solid state NMR

Author(s): Marcus Rauche, Sebastian Ehrling, Simon Krause, Irena Senkovska, Stefan Kaskel, Eike Brunner
Published in: Chemical Communications, Issue 55/62, 2019, Page(s) 9140-9143, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cc04298a

Metal–organic frameworks in Germany: From synthesis to function

Author(s): Jack D. Evans, Bikash Garai, Helge Reinsch, Weijin Li, Stefano Dissegna, Volodymyr Bon, Irena Senkovska, Roland A. Fischer, Stefan Kaskel, Christoph Janiak, Norbert Stock, Dirk Volkmer
Published in: Coordination Chemistry Reviews, Issue 380, 2019, Page(s) 378-418, ISSN 0010-8545
Publisher: Elsevier BV
DOI: 10.1016/j.ccr.2018.10.002

The Role of Temperature and Adsorbate on Negative Gas Adsorption in the Mesoporous Metal-Organic Framework DUT-49

Author(s): Simon Krause, Jack D. Evans, Volodymyr Bon, Irene Senkovska, François-Xavier Coudert, Daniel M Többens, Dirk Wallacher, Nico Grimm, Stefan Kaskel
Published in: Faraday Discussions, 2020, ISSN 1359-6640
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0fd00013b

Impact of Defects and Crystal Size on Negative Gas Adsorption in DUT-49 Analyzed by In Situ 129 Xe NMR Spectroscopy

Author(s): Simon Krause, Florian S. Reuter, Sebastian Ehrling, Volodymyr Bon, Irena Senkovska, Stefan Kaskel, Eike Brunner
Published in: Chemistry of Materials, Issue 32/11, 2020, Page(s) 4641-4650, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.0c01059

High-Pressure in Situ 129 Xe NMR Spectroscopy: Insights into Switching Mechanisms of Flexible Metal–Organic Frameworks Isoreticular to DUT-49

Author(s): Felicitas Kolbe, Simon Krause, Volodymyr Bon, Irena Senkovska, Stefan Kaskel, Eike Brunner
Published in: Chemistry of Materials, Issue 31/16, 2019, Page(s) 6193-6201, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.9b02003

Tunable Flexibility and Porosity of the Metal–Organic Framework DUT-49 through Postsynthetic Metal Exchange

Author(s): Bikash Garai, Volodymyr Bon, Simon Krause, Friedrich Schwotzer, Martin Gerlach, Irena Senkovska, Stefan Kaskel
Published in: Chemistry of Materials, Issue 32/2, 2020, Page(s) 889-896, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.9b04769

Integration of Fluorescent Functionality into Pressure-Amplifying Metal–Organic Frameworks

Author(s): Francesco Walenszus, Jack D. Evans, Volodymyr Bon, Friedrich Schwotzer, Irena Senkovska, Stefan Kaskel
Published in: Chemistry of Materials, 2021, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.1c01804

Molecular Diffusion in a Flexible Mesoporous Metal–Organic Framework over the Course of Structural Contraction

Author(s): Francesco Walenszus, Volodymyr Bon, Jack D. Evans, Stefan Kaskel, Muslim Dvoyashkin
Published in: The Journal of Physical Chemistry Letters, 2020, Page(s) 9696–9701, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.0c02745

Massive Pressure Amplification by Stimulated Contraction of Mesoporous Frameworks

Author(s): Dr. Volodymyr Bon, Dr. Simon Krause, Dr. Irena Senkovska, Nico Grimm, Dr. Dirk Wallacher, Dr. Daniel M. Többens, Prof. Stefan Kaskel
Published in: Angewandte Chemie, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202100549

Unraveling Structure and Dynamics in Porous Frameworks via Advanced In Situ Characterization Techniques

Author(s): Volodymyr Bon, Eike Brunner, Andreas Pöppl, Stefan Kaskel
Published in: Advanced Functional Materials, Issue 30/41, 2020, Page(s) 1907847, ISSN 1616-301X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/adfm.201907847

Cooperative light-induced breathing of soft porous crystals via azobenzene buckling

Author(s): Simon Krause, Jack D. Evans, Volodymyr Bon, Stefano Crespi, Wojciech Danowski, Wesley R. Browne, Sebastian Ehrling, Francesco Walenszus, Dirk Wallacher, Nico Grimm, Daniel M. Többens, Manfred S. Weiss, Stefan Kaskel, Ben L. Feringa
Published in: Nature Communications, Issue (2022) 13:1951, 2022, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-022-29149-z

Intellectual Property Rights

Trademark (1)

Dynadiff

Application/Publication number: EUTM 018619566
Date: 2021-12-10