Objective
Gold catalysis has become an extremely attractive research field these last decades as it has been considered one of the most effective methodologies for constructing carbon-carbon or carbon-heteroatom bonds. However, the development of enantioselective catalysis mediated by gold is relatively slow, mainly due to (i) the preferred linear two-coordinated mode of AuI complexes in the activation of alkynes, thus making the π-activation substrates distant from the chiral site, and (ii) the lack of mechanism data for enantioselective gold(I)-catalyzed transformations. In this project, PGOLDCAT, we will focus on the synthesis of novel gold clusters, and silver analogues, for the catalytic activation of small molecules. The project includes the study of their catalytic performance in standard reactions and mechanism investigations by comparing the catalytic performance of gold clusters and silver analogues, together with kinetic studies and intermediates optimization by theoretical calculation. Finally, PGOLDCAT will study the application of these new architectures on developing a general asymmetric synthesis of 1,4-enynes. Overall, this research project will expand enantioselective AuI catalysis, giving insights into the gold-catalyzed mechanisms, and applying these catalysts to organic synthetic methodologies. The fellowship will also allow the experienced researcher to increase her network of contacts and follow a personalized career development plan to advance in her path towards an independent academic position.
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- natural sciences chemical sciences inorganic chemistry transition metals
- natural sciences chemical sciences organic chemistry hydrocarbons
- natural sciences chemical sciences catalysis
- natural sciences chemical sciences organic chemistry amines
- natural sciences mathematics applied mathematics mathematical model
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Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
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H2020-EU.1.3. - EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions
MAIN PROGRAMME
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H2020-EU.1.3.2. - Nurturing excellence by means of cross-border and cross-sector mobility
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Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
MSCA-IF-EF-ST - Standard EF
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Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
(opens in new window) H2020-MSCA-IF-2016
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Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.
43007 TARRAGONA
Spain
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.