Cooperative Catalysis: Using Interdisciplinary Chemical Systems to Develop New Cooperative Catalysts

Project Information

CoopCat

Grant agreement ID: 756575

DOI

10.3030/756575

Project closed

EC signature date 23 November 2017

Start date 1 February 2018

End date 31 January 2024

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 445 000,00

EU contribution

€ 1 445 000,00

Coordinated by

AGENCIA ESTATAL CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS
Spain

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (29)

A highly constrained <i>cis</i>-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation

Author(s): Nereida Hidalgo; Felipe de la Cruz-Martínez; M. Trinidad Martín; M. Carmen Nicasio; Jesús Campos
Published in: Chemical Communications, 2022, ISSN 1364-548X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2cc03089f

A Cavity-Shaped Gold(I) Fragment Enables CO2 Insertion into Au-OH and Au-NH Bonds

Author(s): Miquel Navarro; Markus Holzapfel; Jesús Campos
Published in: Inorganic Chemistry, 2023, ISSN 1520-510X
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c00751

Do transition metal sigma complexes of main group metal E–C bonds exist?

Author(s): Marina Pérez-Jiménez; Jesús Campos
Published in: Polyhedron, 2023, ISSN 1873-3719
Publisher: Elsevier
DOI: 10.1016/j.poly.2023.116610

Dicoordinate Au(I)–Ethylene Complexes as Hydroamination Catalysts

Author(s): Miquel Navarro; Macarena G. Alférez; Morgane de Sousa; Juan Miranda-Pizarro; Jesús Campos
Published in: ACS Catalysis, 2022, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.1c05823

Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity

Author(s): Nereida Hidalgo; Carlos Romero-Pérez; Celia Maya; Israel Fernández; Jesús Campos
Published in: Organometallics, 2021, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.1c00088

Shape Selectivity in the Gold‐Catalyzed Hydration of Alkynes Using a Cavity‐Shaped Phosphine

Author(s): Miquel Navarro; Markus Holzapfel; Jesús Campos
Published in: ChemPlusChem, 2023, ISSN 2192-6506
Publisher: Wiley-VCH Verlag
DOI: 10.1002/cplu.202300231

A dicoordinate gold(I)–ethylene complex

Author(s): Miquel Navarro; Juan Miranda-Pizarro; Juan J. Moreno; Carlos Navarro-Gilabert; Israel Fernández; Jesús Campos
Published in: Chemical Communications, 2021, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc02769g

Small molecule activation with bimetallic systems: a landscape of cooperative reactivity

Author(s): Miquel Navarro; Juan José Moreno; Marina Pérez-Jiménez; Jesús Campos
Published in: Chemical Communications, 2022, ISSN 1364-548X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2cc04296g

A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium

Author(s): Marta Fernández-Buenestado; Rosie J. Somerville; Joaquín López-Serrano; Jesús Campos
Published in: Chemical Communications, 2023, ISSN 1364-548X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3cc02447d

Dehydrogenative Double C-H Bond Activation in a Germylene-Rhodium Complex.

Author(s): Sonia Bajo; María M. Alcaide; Joaquín López-Serrano; Jesús Campos
Published in: Chemistry - A European Journal, 2021, ISSN 1521-3765
Publisher: John Wiley & Sons
DOI: 10.1002/chem.202102529

Enhanced Dihydrogen Activation by Mononuclear Iridium(II) Compounds: A Mechanistic Study

Author(s): Nereida Hidalgo; Juan José Moreno; Inés García‐Rubio; Jesús Campos
Published in: Angewandte Chemie International Edition, 2022, ISSN 1521-3773
Publisher: Wiley-VCH
DOI: 10.1002/ange.202206831

Divergent CO2 Activation by Tuning the Lewis Acid in Iron-Based Bimetallic Systems

Author(s): Helena Corona; Marina Pérez‐Jiménez; Felipe de la Cruz‐Martínez; Israel Fernández; Jesús Campos
Published in: Angewandte Chemie International Edition, 2022, ISSN 1521-3773
Publisher: John Wiley & Sons
DOI: 10.1002/anie.202207581

Reversible Hydride Migration from C5Me5 to Rh(I) revealed by a Cooperative Bimetallic Approach

Author(s): Macarena G Alferez, Juan J Moreno, Nereida Hidalgo, Jesus Campos
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202008442

Mechanism of Dihydrogen Splitting by An Apparent Bimetallic Frustrated Lewis Pair based on Ir(III)/Pt(0)

Author(s): Juan J. Moreno; Alejandra Pita‐Milleiro; Ana Luque‐Gómez; María F. Espada; Joaquín López‐Serrano; Jesús Campos
Published in: Zeitschrift für anorganische und allgemeine Chemie, 2023, ISSN 1521-3749
Publisher: John Wiley & Sons
DOI: 10.1002/zaac.202300003

Unmasking the constitution and bonding of the proposed lithium nickelate “Li₃NiPh₃(solv)₃”: revealing the hidden C₆H₄ ligand

Author(s): Rosie J. Somerville; Andryj M. Borys; Marina Perez-Jimenez; Ainara Nova; David Balcells; Lorraine A. Malaspina; Simon Grabowsky; Ernesto Carmona; Eva Hevia; Jesús Campos
Published in: Chemical Science, 2022, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2sc01244h

Polarized Au(I)/Rh(I) bimetallic pairs cooperatively trigger ligand non-innocence and bond activation

Author(s): Macarena G. Alférez; Juan J. Moreno; Celia Maya; Jesús Campos
Published in: Dalton Transactions, 2023, ISSN 1477-9234
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3dt00410d

Cooperativity in Transition Metal Tetrylene Complexes.

Author(s): Somerville, Rosie J.; Campos, Jesús
Published in: European Journal of Inorganic Chemistry, 2021, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202100460

Base-Promoted, Remote C–H Activation at a Cationic (η 5 -C 5 Me 5 )Ir(III) Center Involving Reversible C–C Bond Formation of Bound C 5 Me 5

Author(s): Juan J. Moreno, María F. Espada, Jesús Campos, Joaquín López-Serrano, Stuart A. Macgregor, Ernesto Carmona
Published in: Journal of the American Chemical Society, Issue 141/6, 2019, Page(s) 2205-2210, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b11752

Reactivity of a gold( i )/platinum(0) frustrated Lewis pair with germanium and tin dihalides

Author(s): Nereida Hidalgo, Sonia Bajo, Juan José Moreno, Carlos Navarro-Gilabert, Brandon Q. Mercado, Jesús Campos
Published in: Dalton Transactions, Issue 48/25, 2019, Page(s) 9127-9138, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9dt00702d

Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag( i ) metal-only Lewis pair

Author(s): Nereida Hidalgo, Celia Maya, Jesús Campos
Published in: Chemical Communications, 2019, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cc03008e

Reactivity of a trans -[H–MoMo–H] unit towards alkenes and alkynes: bimetallic migratory insertion, H-elimination and other reactions

Author(s): Marina Pérez-Jiménez, Jesús Campos, Joaquín López-Serrano, Ernesto Carmona
Published in: Chemical Communications, Issue 54/66, 2018, Page(s) 9186-9189, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cc04945a

Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems

Author(s): Nereida Hidalgo, Juan José Moreno, Marina Pérez‐Jiménez, Celia Maya, Joaquín López‐Serrano, Jesús Campos
Published in: Chemistry – A European Journal, Issue 26/27, 2020, Page(s) 5982-5993, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201905793

Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs

Author(s): Nereida Hidalgo, Juan José Moreno, Marina Pérez-Jiménez, Celia Maya, Joaquín López-Serrano, Jesús Campos
Published in: Organometallics, Issue 39/13, 2020, Page(s) 2534-2544, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.0c00330

A Versatile Approach to Access Trimetallic Complexes Based on Trisphosphinite Ligands

Author(s): Juan Miranda-Pizarro, Macarena G. Alférez, M. Dolores Fernández-Martínez, Eleuterio Álvarez, Celia Maya, Jesús Campos
Published in: Molecules, Issue 25/3, 2020, Page(s) 593, ISSN 1420-3049
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/molecules25030593

Metal‐Only Lewis Pairs of Rhodium with s, p and d‐Block Metals

Author(s): Sonia Bajo, Macarena G. Alférez, María M. Alcaide, Joaquín López-Serrano, Jesus Campos
Published in: Chemistry – A European Journal, 2020, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202003167

Donor‐Acceptor Activation of Carbon Dioxide

Author(s): Marina Pérez‐Jiménez; Helena Corona; Felipe de la Cruz‐Martínez; Jesús Campos
Published in: Chemistry - A European Journal, 2023, ISSN 1521-3765
Publisher: John Wiley & Sons
DOI: 10.1002/chem.202301428

Unveiling the Latent Reactivity of Cp* Ligands (C5Me5-) toward Carbon Nucleophiles on an Iridium Complex

Author(s): Alejandra Pita-Milleiro; Macarena G. Alférez; Juan J. Moreno; María F. Espada; Celia Maya; Jesús Campos
Published in: Inorganic Chemistry, 2023, ISSN 1520-510X
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.2c04381

Mechanistic Investigations on Hydrogenation, Isomerization and Hydrosilylation Reactions Mediated by a Germyl‐Rhodium System

Author(s): Sonia Bajo; Cyril A. Theulier; Jesús Campos
Published in: ChemCatChem, 2022, ISSN 1867-3899
Publisher: Wiley-VCH
DOI: 10.1002/cctc.202200838

Structural Snapshots of π‐Arene Bonding in a Gold Germylene Cation

Author(s): Sonia Bajo, María M. Alcaide, Joaquín López‐Serrano, Jesús Campos
Published in: Chemistry – A European Journal, Issue 26/67, 2020, Page(s) 15519-15523, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202004566