CORDIS - EU research results
CORDIS

Cooperative Catalysis: Using Interdisciplinary Chemical Systems to Develop New Cooperative Catalysts

Publications

A highly constrained <i>cis</i>-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation

Author(s): Nereida Hidalgo; Felipe de la Cruz-Martínez; M. Trinidad Martín; M. Carmen Nicasio; Jesús Campos
Published in: Chemical Communications, Issue 1364548X, 2022, ISSN 1364-548X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2cc03089f

A Cavity-Shaped Gold(I) Fragment Enables CO2 Insertion into Au-OH and Au-NH Bonds

Author(s): Miquel Navarro; Markus Holzapfel; Jesús Campos
Published in: Inorganic Chemistry, 2023, ISSN 1520-510X
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.3c00751

Dicoordinate Au(I)–Ethylene Complexes as Hydroamination Catalysts

Author(s): Miquel Navarro; Macarena G. Alférez; Morgane de Sousa; Juan Miranda-Pizarro; Jesús Campos
Published in: ACS Catalysis, 2022, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.1c05823

Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity

Author(s): Nereida Hidalgo; Carlos Romero-Pérez; Celia Maya; Israel Fernández; Jesús Campos
Published in: Organometallics, 2021, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.1c00088

Shape Selectivity in the Gold‐Catalyzed Hydration of Alkynes Using a Cavity‐Shaped Phosphine

Author(s): Miquel Navarro; Markus Holzapfel; Jesús Campos
Published in: ChemPlusChem, 2023, ISSN 2192-6506
Publisher: Wiley-VCH Verlag
DOI: 10.1002/cplu.202300231

A dicoordinate gold(I)–ethylene complex

Author(s): Miquel Navarro; Juan Miranda-Pizarro; Juan J. Moreno; Carlos Navarro-Gilabert; Israel Fernández; Jesús Campos
Published in: Chemical Communications, 2021, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1cc02769g

Small molecule activation with bimetallic systems: a landscape of cooperative reactivity

Author(s): Miquel Navarro; Juan José Moreno; Marina Pérez-Jiménez; Jesús Campos
Published in: Chemical Communications, 2022, ISSN 1364-548X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2cc04296g

A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium

Author(s): Marta Fernández-Buenestado; Rosie J. Somerville; Joaquín López-Serrano; Jesús Campos
Published in: Chemical Communications, 2023, ISSN 1364-548X
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3cc02447d

Dehydrogenative Double C-H Bond Activation in a Germylene-Rhodium Complex.

Author(s): Sonia Bajo; María M. Alcaide; Joaquín López-Serrano; Jesús Campos
Published in: Chemistry - A European Journal, 2021, ISSN 1521-3765
Publisher: John Wiley & Sons
DOI: 10.1002/chem.202102529

Enhanced Dihydrogen Activation by Mononuclear Iridium(II) Compounds: A Mechanistic Study

Author(s): Nereida Hidalgo; Juan José Moreno; Inés García‐Rubio; Jesús Campos
Published in: Angewandte Chemie International Edition, Issue 15213773, 2022, ISSN 1521-3773
Publisher: Wiley-VCH
DOI: 10.1002/ange.202206831

Divergent CO2 Activation by Tuning the Lewis Acid in Iron-Based Bimetallic Systems

Author(s): Helena Corona; Marina Pérez‐Jiménez; Felipe de la Cruz‐Martínez; Israel Fernández; Jesús Campos
Published in: Angewandte Chemie International Edition, 2022, ISSN 1521-3773
Publisher: John Wiley & Sons
DOI: 10.1002/anie.202207581

Reversible Hydride Migration from C5Me5 to Rh(I) revealed by a Cooperative Bimetallic Approach

Author(s): Macarena G Alferez, Juan J Moreno, Nereida Hidalgo, Jesus Campos
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202008442

Mechanism of Dihydrogen Splitting by An Apparent Bimetallic Frustrated Lewis Pair based on Ir(III)/Pt(0)

Author(s): Juan J. Moreno; Alejandra Pita‐Milleiro; Ana Luque‐Gómez; María F. Espada; Joaquín López‐Serrano; Jesús Campos
Published in: Zeitschrift für anorganische und allgemeine Chemie, 2023, ISSN 1521-3749
Publisher: John Wiley & Sons
DOI: 10.1002/zaac.202300003

Unmasking the constitution and bonding of the proposed lithium nickelate “Li<sub>3</sub>NiPh<sub>3</sub>(solv)<sub>3</sub>”: revealing the hidden C<sub>6</sub>H<sub>4</sub> ligand

Author(s): Rosie J. Somerville; Andryj M. Borys; Marina Perez-Jimenez; Ainara Nova; David Balcells; Lorraine A. Malaspina; Simon Grabowsky; Ernesto Carmona; Eva Hevia; Jesús Campos
Published in: Chemical Science, 2022, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2sc01244h

Polarized Au(I)/Rh(I) bimetallic pairs cooperatively trigger ligand non-innocence and bond activation

Author(s): Macarena G. Alférez; Juan J. Moreno; Celia Maya; Jesús Campos
Published in: Dalton Transactions, 2023, ISSN 1477-9234
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3dt00410d

Cooperativity in Transition Metal Tetrylene Complexes.

Author(s): Somerville, Rosie J.; Campos, Jesús
Published in: European Journal of Inorganic Chemistry, 2021, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202100460

Base-Promoted, Remote C–H Activation at a Cationic (η 5 -C 5 Me 5 )Ir(III) Center Involving Reversible C–C Bond Formation of Bound C 5 Me 5

Author(s): Juan J. Moreno, María F. Espada, Jesús Campos, Joaquín López-Serrano, Stuart A. Macgregor, Ernesto Carmona
Published in: Journal of the American Chemical Society, Issue 141/6, 2019, Page(s) 2205-2210, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.8b11752

Reactivity of a gold( i )/platinum(0) frustrated Lewis pair with germanium and tin dihalides

Author(s): Nereida Hidalgo, Sonia Bajo, Juan José Moreno, Carlos Navarro-Gilabert, Brandon Q. Mercado, Jesús Campos
Published in: Dalton Transactions, Issue 48/25, 2019, Page(s) 9127-9138, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9dt00702d

Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag( i ) metal-only Lewis pair

Author(s): Nereida Hidalgo, Celia Maya, Jesús Campos
Published in: Chemical Communications, 2019, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cc03008e

Reactivity of a trans -[H–MoMo–H] unit towards alkenes and alkynes: bimetallic migratory insertion, H-elimination and other reactions

Author(s): Marina Pérez-Jiménez, Jesús Campos, Joaquín López-Serrano, Ernesto Carmona
Published in: Chemical Communications, Issue 54/66, 2018, Page(s) 9186-9189, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cc04945a

Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems

Author(s): Nereida Hidalgo, Juan José Moreno, Marina Pérez‐Jiménez, Celia Maya, Joaquín López‐Serrano, Jesús Campos
Published in: Chemistry – A European Journal, Issue 26/27, 2020, Page(s) 5982-5993, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201905793

Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs

Author(s): Nereida Hidalgo, Juan José Moreno, Marina Pérez-Jiménez, Celia Maya, Joaquín López-Serrano, Jesús Campos
Published in: Organometallics, Issue 39/13, 2020, Page(s) 2534-2544, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.0c00330

A Versatile Approach to Access Trimetallic Complexes Based on Trisphosphinite Ligands

Author(s): Juan Miranda-Pizarro, Macarena G. Alférez, M. Dolores Fernández-Martínez, Eleuterio Álvarez, Celia Maya, Jesús Campos
Published in: Molecules, Issue 25/3, 2020, Page(s) 593, ISSN 1420-3049
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/molecules25030593

Metal‐Only Lewis Pairs of Rhodium with s, p and d‐Block Metals

Author(s): Sonia Bajo, Macarena G. Alférez, María M. Alcaide, Joaquín López-Serrano, Jesus Campos
Published in: Chemistry – A European Journal, 2020, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202003167

Donor‐Acceptor Activation of Carbon Dioxide

Author(s): Marina Pérez‐Jiménez; Helena Corona; Felipe de la Cruz‐Martínez; Jesús Campos
Published in: Chemistry - A European Journal, 2023, ISSN 1521-3765
Publisher: John Wiley & Sons
DOI: 10.1002/chem.202301428

Unveiling the Latent Reactivity of Cp* Ligands (C5Me5-) toward Carbon Nucleophiles on an Iridium Complex

Author(s): Alejandra Pita-Milleiro; Macarena G. Alférez; Juan J. Moreno; María F. Espada; Celia Maya; Jesús Campos
Published in: Inorganic Chemistry, 2023, ISSN 1520-510X
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.2c04381

Mechanistic Investigations on Hydrogenation, Isomerization and Hydrosilylation Reactions Mediated by a Germyl‐Rhodium System

Author(s): Sonia Bajo; Cyril A. Theulier; Jesús Campos
Published in: ChemCatChem, Issue 18673899, 2022, ISSN 1867-3899
Publisher: Wiley-VCH
DOI: 10.1002/cctc.202200838

Structural Snapshots of π‐Arene Bonding in a Gold Germylene Cation

Author(s): Sonia Bajo, María M. Alcaide, Joaquín López‐Serrano, Jesús Campos
Published in: Chemistry – A European Journal, Issue 26/67, 2020, Page(s) 15519-15523, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202004566

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