Shuttle Catalysis for Reversible Molecular Construction

Project Information

ShuttleCat

Grant agreement ID: 757608

DOI

10.3030/757608

Project closed

EC signature date 31 August 2017

Start date 1 January 2018

End date 31 December 2022

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 485 000,00

EU contribution

€ 1 485 000,00

Coordinated by

EIDGENOESSISCHE TECHNISCHE HOCHSCHULE ZUERICH
Switzerland

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (29)

Nickel‐Catalyzed Inter‐ and Intramolecular Aryl Thioether Metathesis by Reversible Arylation

Author(s): Tristan Delcaillau, Alessandro Bismuto, Zhong Lian, Bill Morandi
Published in: Angewandte Chemie International Edition, Issue 59/5, 2020, Page(s) 2110-2114, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201910436

Catalytic Carbochlorocarbonylation of Unsaturated Hydrocarbons via C−COCl Bond Cleavage

Author(s): Elliott H. Denton, Yong Ho Lee, Sven Roediger, Philip Boehm, Maximilian Fellert, Bill Morandi
Published in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202108818

Nickel-Catalyzed Reversible Functional Group Metathesis between Aryl Nitriles and Aryl Thioethers

Author(s): Tristan Delcaillau, Philip Boehm, Bill Morandi
Published in: Journal of the American Chemical Society, Issue 143/10, 2021, Page(s) 3723-3728, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c00529

Controlling Selectivity in Shuttle Hetero-difunctionalization Reactions: Electrochemical Transfer Halo-thiolation of Alkynes

Author(s): Xichang Dong, Martin Klein, Siegfried R. Waldvogel, Bill Morandi
Published in: Angewandte Chemie International Edition, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202213630

Late-stage diversification of indole skeletons through nitrogen atom insertion

Author(s): Allegra Franchino; Bill Morandi; Patrick Finkelstein; Julia Reisenbauer; Ori Green
Published in: Science, 2022, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.add1383

Palladium-Catalyzed Carbothiolation of Alkenes and Alkynes for the Synthesis of Heterocycles

Author(s): Tristan Delcaillau, Hendrik L. Schmitt, Philip Boehm, Eric Falk, Bill Morandi
Published in: ACS Catalysis, 2022, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.2c01178

Deaminative coupling of benzylamines and arylboronic acids

Author(s): Giedre Sirvinskaite, Julia C. Reisenbauer, Bill Morandi
Published in: Chemical Sciences, 2023, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2sc06055h

Palladium‐Catalyzed Decarbonylative Iodination of Aryl Carboxylic Acids Enabled by Ligand‐Assisted Halide Exchange

Author(s): Philip Boehm, Tristano Martini, Yong Ho Lee, Bastien Cacherat, Bill Morandi
Published in: Angewandte Chemie International Edition, 2021, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202103269

Mechanistic Investigation of the Nickel-Catalyzed Metathesis between Aryl Thioethers and Aryl Nitriles

Author(s): Philip Boehm, Patrick Müller, Patrick Finkelstein, Miguel A. Rivero-Crespo, Marc-Olivier Ebert, Nils Trapp, Bill Morandi
Published in: The Journal of American Chemical Society, 2022, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c01595

Development of an Operationally Simple, Scalable, and HCN-Free Transfer Hydrocyanation Protocol Using an Air-Stable Nickel Precatalyst

Author(s): Julia C. Reisenbauer, Benjamin N. Bhawal, Nicola Jelmini, and Bill Morandi
Published in: Organic Process Research and Development, 2022, ISSN 1083-6160
Publisher: American Chemical Society
DOI: 10.1021/acs.oprd.1c00442

Modular Cyclopentenone Synthesis through the Catalytic Molecular Shuffling of Unsaturated Acid Chlorides and Alkynes

Author(s): Yong Ho Lee, Elliott H. Denton, Bill Morandi
Published in: Journal of the American Chemical Society, Issue 142/50, 2020, Page(s) 20948-20955, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c10832

New Catalysis Concepts for Molecular Design and Feedstocks Valorization

Author(s): Philip Boehm, Bill Morandi
Published in: CHIMIA International Journal for Chemistry, Issue 74/9, 2020, Page(s) 724-729, ISSN 0009-4293
Publisher: Schweizerische Chemische Gedellschaft
DOI: 10.2533/chimia.2020.724

Shuttle arylation by Rh(I) catalyzed reversible carbon–carbon bond activation of unstrained alcohols

Author(s): Marius D.R. Lutz, Valentina C.M. Gasser, Bill Morandi
Published in: Chem, Issue 7/4, 2021, Page(s) 1108-1119, ISSN 2451-9294
Publisher: Cell press
DOI: 10.1016/j.chempr.2021.02.029

Preparation of Recyclable and Versatile Porous Poly(aryl thioether)s by Reversible Pd-Catalyzed C-S/C-S Metathesis

Author(s): Rivero Crespo, Miguel Ángel; id_orcid0000-0002-3860-0947; Toupalas, Georgios; Morandi, Bill
Published in: Journal of the American Chemical Society, 2021, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c09884

Merging shuttle reactions and paired electrolysis for reversible vicinal dihalogenations

Author(s): Xichang Dong, Johannes L. Roeckl, Siegfried R. Waldvogel, Bill Morandi
Published in: Science, Issue 371/6528, 2021, Page(s) 507-514, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.abf2974

Catalytic Isofunctional Reactions-Expanding the Repertoire of Shuttle and Metathesis Reactions

Author(s): Benjamin N. Bhawal, Bill Morandi
Published in: Angewandte Chemie International Edition, Issue 58/30, 2019, Page(s) 10074-10103, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201803797

Palladium-Catalyzed Intermolecular Aryliodination of Internal Alkynes

Author(s): Yong Ho Lee, Bill Morandi
Published in: Angewandte Chemie International Edition, Issue 58/19, 2019, Page(s) 6444-6448, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201812396

Transition metal-mediated metathesis between P–C and M–C bonds: Beyond a side reaction

Author(s): Yong Ho Lee, Bill Morandi
Published in: Coordination Chemistry Reviews, Issue 386, 2019, Page(s) 96-118, ISSN 0010-8545
Publisher: Elsevier BV
DOI: 10.1016/j.ccr.2018.12.001

Iridium-Catalyzed Hydrochlorination and Hydrobromination of Alkynes by Shuttle Catalysis

Author(s): Peng Yu, Alessandro Bismuto, Bill Morandi
Published in: Angewandte Chemie International Edition, Issue 59/7, 2020, Page(s) 2904-2910, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201912803

Nickel‐Catalyzed Cascade Annulation for the Rapid Synthesis of Carbocyclic Nitriles

Author(s): Xianjie Fang, Peng Yu, Suzanne Willems, Bill Morandi
Published in: Helvetica Chimica Acta, Issue 102/5, 2019, Page(s) e1900059, ISSN 0018-019X
Publisher: Verlag Helvetica Chimica Acta
DOI: 10.1002/hlca.201900059

Efficient access to unprotected primary amines by iron-catalyzed aminochlorination of alkenes

Author(s): Luca Legnani, Gabriele Prina-Cerai, Tristan Delcaillau, Suzanne Willems, Bill Morandi
Published in: Science, Issue 362/6413, 2018, Page(s) 434-439, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.aat3863

Overcoming Selectivity Issues in Reversible Catalysis: A Transfer Hydrocyanation Exhibiting High Kinetic Control

Author(s): Benjamin N. Bhawal, Julia C. Reisenbauer, Christian Ehinger, Bill Morandi
Published in: Journal of the American Chemical Society, Issue 142/25, 2020, Page(s) 10914-10920, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c03184

Palladium‐Catalyzed Chlorocarbonylation of Aryl (Pseudo)Halides Through In Situ Generation of Carbon Monoxide

Author(s): Philip Boehm, Sven Roediger, Alessandro Bismuto, Bill Morandi
Published in: Angewandte Chemie International Edition, 2020, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202005891

Metal-Catalyzed Carbon–Carbon Bond Cleavage of Unstrained Alcohols

Author(s): Marius D. R. Lutz, Bill Morandi
Published in: Chemical Reviews, 2020, ISSN 0009-2665
Publisher: American Chemical Society
DOI: 10.1021/acs.chemrev.0c00154

Intermolecular Pauson-Khand-Type Reaction of Vinyl Iodides with Alkynes and a CO Surrogate

Author(s): Philip Boehm, Elliott H. Denton, Joel Wick, and Bill Morandi
Published in: The Journal of Organic Chemistry, 2023, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.2c02465

Iron-Catalyzed Ring-Closing C−O/C−O Metathesis of Aliphatic Ethers

Author(s): Tobias Biberger, Szabolcs Makai, Zhong Lian, Bill Morandi
Published in: Angewandte Chemie International Edition, Issue 57/23, 2018, Page(s) 6940-6944, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201802563

Palladium-catalysed carboformylation of alkynes using acid chlorides as a dual carbon monoxide and carbon source

Author(s): Yong Ho Lee, Elliott H. Denton, Bill Morandi
Published in: Nature Chemistry, Issue 13/2, 2021, Page(s) 123-130, ISSN 1755-4330
Publisher: Nature Publishing Group
DOI: 10.1038/s41557-020-00621-x

Rhodium-Catalyzed Anti-Markovnikov Transfer Hydroiodination of Terminal Alkynes

Author(s): Philip Boehm, Niklas Kehl, Bill Morandi
Published in: Angewandte Chemie International Edition, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202214071

Activity-Based Approach for Selective Molecular CO2 Sensing

Author(s): Ori Green,Patrick Finkelstein,Miguel A. Rivero-Crespo,Marius D. R. Lutz,Michael K. Bogdos,Michael Burger,Jean-Christophe Leroux, Bill Morandi
Published in: The Journal of the American Chemical Society, 2022, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c02361

Intellectual Property Rights

Patent (2)

CATALYTIC C-X-BOND METATHESIS THROUGH ARYLATION

Application/Publication number: 18 709992
Date: 2018-03-04
Applicant(s): MAX PLANCK INSTITUT FUER KOHLENFORSCHUNG

PROCESS FOR THE TRANSITION METAL CATALYZED CYANATION OF ARYL/VINYL HALIDES

Application/Publication number: 20 18076789
Date: 2018-10-02
Applicant(s): MAX PLANCK INSTITUT FUER KOHLENFORSCHUNG