Towards Next-generation Eco-efficient PHOTO and EMULSION Polymerisations Imparting Synergy to Process, Products and Applications

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Photoreactor design for aerosol photopolymerisation

A 2nd generation of aerosol photoreactor professionally designed by PESCHL is built It is destined to be put to the market and meet well defined specifications nonsticking wall reactor positive radiation geometry with linear LED arrays modular volume mirrorlike polished interior trim

Monitoring flash kinetics

Fast kinetics of thiolene miniemulsion in the matter seconds are addressed by timeresolved techniques such as realtime nearinfrared or Raman spectroscopy

Data Management Plan (DMP)

The consortium will take part to the Open Research Data Pilot ORD Pilot whose focus is on encouraging good data management by offering access and reuse of the research data generated by PHOTOEMULSION The typical data to be covered include the underlying data ie the data needed to validate the results presented in the scientific publication and other raw data not directly attributable to a publication but judged relevant according to the judgement of the project coordinator and his partners Firstly the stakeholders commit to deposit these research data in a research data repository online research data archive eg OpenAIRE Secondly they will take measures to enable third parties to access and exploit these new data free of any charges the abovementioned research data In order to conciliate best research practice and obligation to protect results our approach in terms of research data will be to be as open as possible and as closed as necessary This means that some selected sensitive datasets will not be made accessible because for example they can reasonably be expected to be commercially or industrially exploited or for other legitimate reasons that could be justified by the coordinator

Management of visible teaching using the set of online courses

Publications

Thiol-Functional Polymer Nanoparticles via Aerosol Photopolymerization

Auteurs: Narmin Suvarli, Iris Perner-Nochta, Jürgen Hubbuch, Michael Wörner
Publié dans: Polymers, 2021, ISSN 2073-4360
Éditeur: MDPI
DOI: 10.3390/polym13244363

Immobilization of β-Galactosidase by Encapsulation of Enzyme-Conjugated Polymer Nanoparticles Inside Hydrogel Microparticles

Auteurs: Narmin Suvarli, Lukas Wenger, Christophe Serra, Iris Perner-Nochta, Jürgen Hubbuch, Michael Wörner
Publié dans: Front Bioeng Biotechnol., 2021, ISSN 2296-4185
Éditeur: Frontiers
DOI: 10.3389/fbioe.2021.818053

Water‐Soluble Photoinitiators from Dimethylamino‐Substituted Monoacylphosphine Oxide for Hydrogel and Latex Preparation

Auteurs: Cuong Minh Quoc Le, Tatiana Petitory, Xingyu Wu, Arnaud Spangenberg, Joanna Ortyl, Mariusz Galek, Lorena Infante, Héloïse Thérien‐Aubin, Abraham Chemtob
Publié dans: Macromolecular Chemistry and Physics, 2021, Page(s) 2100217, ISSN 1022-1352
Éditeur: John Wiley & Sons Ltd.
DOI: 10.1002/macp.202100217

Synthesis of Spherical Nanoparticle Hybrids via Aerosol Thiol-Ene Photopolymerization and Their Bioconjugation

Auteurs: Narmin Suvarli, Max Frentzel, Jürgen Hubbuch, Iris Perner-Nochta, Michael Wörner *
Publié dans: Nanomaterials, 2022, ISSN 2079-4991
Éditeur: MDPI
DOI: 10.3390/nano12030577

Role of thiol oxidation by air in the mechanism of the self-initiated thermal thiol–ene polymerization

Auteurs: Cuong Minh Quoc Le, Fabrice Morlet-Savary, Abraham Chemtob
Publié dans: Polymer Chemistry, Numéro 12/45, 2021, Page(s) 6594-6605, ISSN 1759-9954
Éditeur: Royal Society of Chemistry
DOI: 10.1039/d1py01301g

Emulsion Templated Porous Poly(thiol-enes): Influence of Photopolymerisation, Emulsion Composition, and Phase Behaviour on the Porous Structure and Morphology

Auteurs: Viola Hobiger; Muzafera Paljevac; Peter Krajnc
Publié dans: Polymers, Numéro 14, 2022, Page(s) 1338-1349, ISSN 2073-4360
Éditeur: MDPI
DOI: 10.5281/zenodo.6602568

Semi‐Crystalline Poly(thioether) Prepared by Visible‐Light‐Induced Organocatalyzed Thiol‐ene Polymerization in Emulsion

Auteurs: Cuong Minh Quoc Le; Gautier Schrodj; Ibrahima Ndao; Brahim Bessif; Barbara Heck; Thomas Pfohl; Günter Reiter; Justine Elgoyhen; Radmila Tomovska; Abraham Chemtob
Publié dans: Macromolecular Rapid Communication, Numéro 1, 2022, ISSN 1521-3927
Éditeur: Wiley
DOI: 10.1002/marc.202100740

Ab Initio Batch Emulsion Thiol–Ene Photopolymerization

Auteurs: Cuong Minh Quoc Le, Marc Schmutz, Abraham Chemtob
Publié dans: Macromolecules, Numéro 53/7, 2020, Page(s) 2369-2379, ISSN 0024-9297
Éditeur: American Chemical Society
DOI: 10.1021/acs.macromol.0c00265

Self-Seeding Procedure for Obtaining Stacked Block Copolymer Lamellar Crystals in Solution

Auteurs: Brahim Bessif, Thomas Pfohl, Günter Reiter
Publié dans: Polymers, Numéro 13/11, 2021, Page(s) 1676, ISSN 2073-4360
Éditeur: MDPI
DOI: 10.3390/polym13111676

Photopolymerizable precursors for degradable biomaterials based on acetal moieties

Auteurs: Barbara Dellago, Alexander Ricke, Theresa Geyer, Robert Liska, Stefan Baudis
Publié dans: European Polymer Journal, Numéro 154, 2021, Page(s) 110536, ISSN 0014-3057
Éditeur: Pergamon Press Ltd.
DOI: 10.1016/j.eurpolymj.2021.110536

Controlled Switching from the Growth of Monolamellar Polymer Crystals to the Formation of Stacks of Uniquely Oriented Lamellae

Auteurs: Weixiang Chen, Brahim Bessif, Renate Reiter, Jun Xu, Günter Reiter
Publié dans: Macromolecules, Numéro 54/17, 2021, Page(s) 8135-8142, ISSN 0024-9297
Éditeur: American Chemical Society
DOI: 10.1021/acs.macromol.1c01390

Thiol-ene emulsion step polymerization in a photochemical stirred tank reactor: Molecular weight, cyclization, and fragmentation

Auteurs: Cuong Minh Quoc Le, Abraham Chemtob
Publié dans: J. Polym. Sci., Numéro 16879422, 2022, ISSN 1687-9422
Éditeur: Hindawi
DOI: 10.1002/pol.20220402

In Situ Dissolution and Swelling of Confined Lamellar Polymer Crystals through Exposure to Humid Air

Auteurs: Brahim Bessif; Thomas Pfohl; Barbara Heck; Yaser Alshetwi; Emna Khechine; Jun Xu; Günter Reiter
Publié dans: Macromolecules, Numéro 15205835, 2022, ISSN 1520-5835
Éditeur: ACS
DOI: 10.1021/acs.macromol.2c00496

Nanoconfinement in miniemulsion increases reaction rates of thiol–ene photopolymerization and yields high molecular weight polymers

Auteurs: Lorena Infante Teixeira, Katharina Landfester, Héloïse Thérien-Aubin
Publié dans: Polymer Chemistry, Numéro 13, 2022, Page(s) 2831-2841, ISSN 1759-9962
Éditeur: RSC
DOI: 10.1039/d2py00350c

Photopolymerization in dispersed systems

Auteurs: Florent Jasinski, Per B. Zetterlund, André M. Braun, Abraham Chemtob
Publié dans: Progress in Polymer Science, Numéro 84, 2018, Page(s) 47-88, ISSN 0079-6700
Éditeur: Elsevier BV
DOI: 10.1016/j.progpolymsci.2018.06.006

Thiol–Ene Cross-linking of Poly(ethylene glycol) within High Internal Phase Emulsions: Degradable Hydrophilic PolyHIPEs for Controlled Drug Release

Auteurs: Viola Hobiger, Anna Zahoranova, Stefan Baudis, Robert Liska, Peter Krajnc
Publié dans: Macromolecules, Numéro 54/22, 2021, Page(s) 10370-10380, ISSN 0024-9297
Éditeur: American Chemical Society
DOI: 10.1021/acs.macromol.1c01240

Effect of surfactant concentration and monomer polarity on particle nucleation in emulsion step polymerization of dithiol with diene

Auteurs: Cuong Minh Quoc Le, Marc Schmutz, Abraham Chemtob
Publié dans: Colloid Polymer Science, 2022, ISSN 1435-1536
Éditeur: Springer
DOI: 10.1007/s00396-022-04993-z

Selective Oxidation of Polysulfide Latexes to Produce Polysulfoxide and Polysulfone in a Waterborne Environment

Auteurs: Lorena Infante Teixeira, Katharina Landfester, Héloïse Thérien-Aubin
Publié dans: Macromolecules, Numéro 54/8, 2021, Page(s) 3659-3667, ISSN 0024-9297
Éditeur: American Chemical Society
DOI: 10.1021/acs.macromol.1c00382

Droplet nucleation in miniemulsion thiol–ene step photopolymerization

Auteurs: Cuong Minh Quoc Le, Loïc Vidal, Marc Schmutz, Abraham Chemtob
Publié dans: Polymer Chemistry, 2021, ISSN 1759-9954
Éditeur: Royal Society of Chemistry
DOI: 10.1039/d1py00139f

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