Plasma Enabled and Graphene Allowed Synthesis of Unique nano Structures

Project Information

PEGASUS

Grant agreement ID: 766894

DOI 10.3030/766894

Project closed

EC signature date 30 August 2017

Start date 1 November 2017

End date 31 May 2022

Funded under

• EXCELLENT SCIENCE - Future and Emerging Technologies (FET)

Total cost € 3 999 633,75

EU contribution € 3 764 276,25

Coordinated by

IST-ID ASSOCIACAO DO INSTITUTO SUPERIOR TECNICO PARA A INVESTIGACAO E O DESENVOLVIMENTO
Portugal

Deliverables

Demonstrators, pilots, prototypes (1)

Protocol for NG/MO and GMOP composites

Delivery of fabrication procedure protocol for assembling of NG/MO and GMOP composites.

Documents, reports (2)

N-graphene electrochemical properties

Assessment of electrochemical properties of N-graphene free standing sheets to be used as supercapacitor electrode material.

Data management plan

Data management plan delivery.

Websites, patent fillings, videos etc. (3)

Website Creation

Creation of website of the project with general information, participants, etc.

Manufacturing 3D vertical NG with MO polymers

Large scale growth for manufacturing of 3D networks of vertical NG sheets decorated with MO nanoparticles and wrapped with conductive polymers affixed on Ni-foams.

Manufacturing of 3D vertical graphene/N-graphenes

Homogeneous large scale growth for manufacturing of 3D networks of vertical graphehe/N-graphene sheets affixed on Ni-foams with tailored heights, thicknesses and spacing between nanowalls.

Open Research Data Pilot (1)

Open Research Data Pilot/Materials

Material and electrochemical characteristics of free-standing NG/MO, GMOP and verticla Graphenes/N-graphenes on Ni foams.

Publications

Peer reviewed articles (32)

Label-Free Mycotoxin Raman Identification by High-Performing Plasmonic Vertical Carbon Nanostructures

Author(s): N. M. Santhosh, V. Shvalya, M. Modic, N. Hojnik, J. Zavašnik, J. Olenik, M. Košiček, G. Filipič, I. Abdulhalim, U. Cvelbar
Published in: Small, Issue 17, 2021, ISSN 1613-6829
Publisher: © Wiley-VCH GmbH, Weinheim
DOI: 10.1002/smll.202103677

Controlling the flux of reactive species: a case study on thin film deposition in an aniline/argon plasma

Author(s): D. Sciacqua, C. Pattyn, A. Jagodar, E. von Wahl, T. Lecas, T. Strunskus, E. Kovacevic and J. Berndt
Published in: Scientific Reports, Issue 10/1, 2020, ISSN 2045-2322
Publisher: Nature Publishing Group
DOI: 10.1038/s41598-020-72634-y

Double-discharge plasma system for deposition of carbon nanostructures

Author(s): S Marinov, V Vachkov, I Ivanov and Zh Kissovski
Published in: Journal of Physics: Conference Series, Issue 2240, 2022, ISSN 1742-6596
Publisher: IOP Publisher
DOI: 10.1088/1742-6596/2240/1/012020

Free-Standing Graphene-carbon as negative and FeCoS as positive electrode for Asymmetric supercapacitor

Author(s): K. K. Upadhyay, N. Bundaleska, M. Abrashev, J. Kissovski, N. Bundaleski, O. M. N. D. Teodoro, A. M. Ferro, R. P. Silva, A. Dias, E. Felizardo, E. Tatarova, M.F. Montemor.
Published in: Journal of Energy Storage, Issue 50, 2022, ISSN 2352-152X
Publisher: Elsevier
DOI: 10.1016/j.est.2022.104637

Hydrophilic to hydrophobic: Ultrafast conversion of cellulose nanofibrils by cold plasma fluorination

Author(s): A. Oberlintner, V. Shvalya, A. Vasudevan, D. Vengust, B. Likozar, U. Cvelbar, U. Novak
Published in: Applied Surface Science, Issue 581, 2022, ISSN 0169-4332
Publisher: Elsevier BV
DOI: 10.1016/j.apsusc.2021.152276

Measurement and control of the substrate temperature in vertical graphene nanosheets deposition

Author(s): V. Vachkov and Zh. Kissovski
Published in: Journal of Physics: Conference Series, Issue 1492, 2020, ISSN 1742-6596
Publisher: IOP Publishing
DOI: 10.1088/1742-6596/1492/1/012061

Prospects for microwave plasma synthesized N graphene in secondary electron emission mitigation applications

Author(s): N. Bundaleska, A. Dias, N. Bundaleski, E. Felizardo, J. Henriques, D. Tsyganov, M. Abrashev, E. Valcheva, J. Kissovski, A. M. Ferraria, A. M. Botelho do Rego, A. Almeida, J. Zavašnik, U. Cvelbar, O. M. N. D. Teodoro, Th. Strunskus and E. Tatarova
Published in: Scientific Reports, Issue 10, 2020, ISSN 2045-2322
Publisher: Nature Publishing Group
DOI: 10.1038/s41598-020-69844-9

Controlled deposition of plasma-polyaniline thin film by PECVD: Understanding the influence of aniline to argon ratio

Author(s): C. Pattyn, D. Sciacqua, L. Kwiedor, A. Jagodar, T. Strunskus, F. Traeger, Th. Lecas, E. Kovacevic, J. Berndt.
Published in: Plasma Processes and Polymers, Issue 19/5, 2022, ISSN 1612-8869
Publisher: Wiley
DOI: 10.1002/ppap.202100233

Nitrogen incorporation in graphene nanowalls via plasma processes: Experiments and simulations

Author(s): A. Jagodar, J. Berndt, E. von Wahl, T. Strunskus, T. Lecas, E. Kovacevic and P. Brault.
Published in: Applied Surface Science, Issue 591, 2022, ISSN 0169-4332
Publisher: Elsevier BV
DOI: 10.1016/j.apsusc.2022.153165

Microwave plasma enabled synthesis of free standing carbon nanostructures at atmospheric pressure conditions

Author(s): N. Bundaleska, D. Tsyganov, A. Dias, E. Felizardo, J. Henriques, F. M. Dias, M. Abrashev, J. Kissovski, E. Tatarova
Published in: Physical Chemistry Chemical Physics, Issue 20/20, 2018, Page(s) 13810-13824, ISSN 1463-9076
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8cp01896k

Towards universal plasma-enabled platform for the advanced nanofabrication: plasma physics level approach

Author(s): O. Baranov, S. Xu, K. Ostrikov, B. B. Wang, U. Cvelbar, K. Bazaka, I. Levchenko
Published in: Reviews of Modern Plasma Physics, Issue 2/1, 2018, ISSN 2367-3192
Publisher: Springer
DOI: 10.1007/s41614-018-0016-7

Oriented Carbon Nanostructures by Plasma Processing: Recent Advances and Future Challenges

Author(s): Neelakandan Santhosh, Gregor Filipič, Elena Tatarova, Oleg Baranov, Hiroki Kondo, Makoto Sekine, Masaru Hori, Kostya Ostrikov, Uroš Cvelbar
Published in: Micromachines, Issue 9/11, 2018, Page(s) 565, ISSN 2072-666X
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/mi9110565

Oxygen plasmas: a sharp chisel and handy trowel for nanofabrication

Author(s): K. Bazaka, O. Baranov, U. Cvelbar, B. Podgornik, Y. Wang, S. Huang, L. Xu, J. W. M. Lim, I. Levchenko, S. Xu
Published in: Nanoscale, Issue 10/37, 2018, Page(s) 17494-17511, ISSN 2040-3364
Publisher: Royal Society of Chemistry
DOI: 10.1039/c8nr06502k

Large-scale synthesis of free-standing N-doped graphene using microwave plasma

Author(s): N. Bundaleska, J. Henriques, M. Abrashev, A. M. Botelho do Rego, A. M. Ferraria, A. Almeida, F. M. Dias, E. Valcheva, B. Arnaudov, K. K. Upadhyay, M. F. Montemor, E. Tatarova
Published in: Scientific Reports, Issue 8/1, 2018, ISSN 2045-2322
Publisher: Nature Publishing Group
DOI: 10.1038/s41598-018-30870-3

Microwave plasma-based direct synthesis of free-standing N-graphene

Author(s): D. Tsyganov, N. Bundaleska, A. Dias, J. Henriques, E. Felizardo, M. Abrashev, J. Kissovski, A. M. Botelho do Rego, A. M. Ferraria, E. Tatarova
Published in: Physical Chemistry Chemical Physics, Issue 22/8, 2020, Page(s) 4772-4787, ISSN 1463-9076
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9cp05509f

Transparent elongation and compressive strain sensors based on aligned carbon nanowalls embedded in polyurethane

Author(s): Petr Slobodian, Pavel Riha, Hiroki Kondo, Uroš Cvelbar, Robert Olejnik, Jiri Matyas, Makoto Sekine, Masaru Hori
Published in: Sensors and Actuators A: Physical, Issue 306, 2020, Page(s) 111946, ISSN 0924-4247
Publisher: Elsevier BV
DOI: 10.1016/j.sna.2020.111946

Free-standing N-Graphene as conductive matrix for Ni(OH)2 based supercapacitive electrodes

Author(s): Kush K. Upadhyay, N. Bundaleska, M. Abrashev, N. Bundaleski, O.M.N.D. Teodoro, I. Fonseca, André Mão de Ferro, Rui Pedro Silva, E. Tatarova, M.F. Montemor
Published in: Electrochimica Acta, Issue 334, 2020, Page(s) 135592, ISSN 0013-4686
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.electacta.2019.135592

Tuning and fine morphology control of natural resource-derived vertical graphene

Author(s): S. Alancherry, M.V. Jacob, K. Prasad, J. Joseph, O. Bazaka, R. Neupane, O.K. Varghese, O. Baranov, S. Xu, I. Levchenko, K. Bazaka
Published in: Carbon, Issue 159, 2020, Page(s) 668-685, ISSN 0008-6223
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.carbon.2019.10.060

Low total electron yield graphene coatings produced by electrophoretic deposition

Author(s): R. Aguincha, N. Bundaleski, N. Bundaleska, M. Novaković, J. Henriques, Z. Rakočević, E. Tatarova, O.M.N.D. Teodoro
Published in: Applied Surface Science, Issue 504, 2020, Page(s) 143870, ISSN 0169-4332
Publisher: Elsevier BV
DOI: 10.1016/j.apsusc.2019.143870

Structure and photoluminescence properties of MoO3−/graphene nanoflake hybrid nanomaterials formed via surface growth

Author(s): B.B. Wang, X.X. Zhong, B.M. Ming, M.K. Zhu, Y.A. Chen, U. Cvelbar, K. Ostrikov
Published in: Applied Surface Science, Issue 480, 2019, Page(s) 1054-1062, ISSN 0169-4332
Publisher: Elsevier BV
DOI: 10.1016/j.apsusc.2019.02.183

Nanocarbon phase transformations controlled by solubility of carbon species in gold nanoparticles

Author(s): B.B. Wang, X.L. Qu, X.X. Zhong, Y.A. Chen, K. Zheng, U. Cvelbar, K. Ostrikov
Published in: Diamond and Related Materials, Issue 88, 2018, Page(s) 282-289, ISSN 0925-9635
Publisher: Elsevier BV
DOI: 10.1016/j.diamond.2018.08.001

N-Graphene Nanowalls via Plasma Nitrogen Incorporation and Substitution: The Experimental Evidence

Author(s): Neelakandan M. Santhosh, Gregor Filipič, Eva Kovacevic, Andrea Jagodar, Johannes Berndt, Thomas Strunskus, Hiroki Kondo, Masaru Hori, Elena Tatarova, Uroš Cvelbar
Published in: Nano-Micro Letters, Issue 12/1, 2020, ISSN 2150-5551
Publisher: Open Access Science Online
DOI: 10.1007/s40820-020-0395-5

Formation and behavior of negative ions in low pressure aniline-containing RF plasmas

Author(s): Cedric Pattyn, Eva Kovacevic, Thomas Strunskus, Thomas Lecas, Johannes Berndt
Published in: Scientific Reports, Issue 9/1, 2019, ISSN 2045-2322
Publisher: Nature Publishing Group
DOI: 10.1038/s41598-019-47425-9

N-Graphene-Metal-Oxide(Sulfide) hybrid Nanostructures: Single-step plasma-enabled approach for energy storage applications

Author(s): A. Dias, N. Bundaleska, E. Felizardo, D. Tsyganov, A. Almeida, A.M. Ferraria, A.M. Botelho do Rego, M. Abrashev, T. Strunskus, N.M. Santhosh, U. Cvelbar, J. Zavašnik, M.F. Montemor, M.M. Almeida, P.A. Carvalho, J. Kissovski, L.L. Alves, E. Tatarova
Published in: Chemical Engineering Journal, Issue 430, 2022, ISSN 1385-8947
Publisher: Elsevier BV
DOI: 10.1016/j.cej.2021.133153

Simultaneous Synthesis and Nitrogen Doping of Free-Standing Graphene Applying Microwave Plasma

Author(s): D. Tsyganov, N. Bundaleska, J. Henriques, E. Felizardo, A. Dias, M. Abrashev, J. Kissovski, A. M. Botelho do Rego, A. M. Ferraria and E. Tatarova
Published in: Materials, Issue 13, 2020, ISSN 1996-1944
Publisher: MDPI Open Access Publishing
DOI: 10.3390/ma13184213

Advanced Carbon–Nickel Sulfide Hybrid Nanostructures: Extending the Limits of Battery-Type Electrodes for Redox-Based Supercapacitor Applications

Author(s): N.M. Santhosh, K.K. Upadhyay, P. Stražar, G. Filipič, J. Zavašnik, A. Mão de Ferro, R.P. Silva, E. Tatarova, M. de F. Montemor, U. Cvelbar
Published in: ACS Applied Materials and Interfaces, Issue 13, 2021, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.1c03053

Low-temperature low-power PECVD synthesis of vertically aligned graphene

Author(s): S. Hussain, E. Kovacevic, J. Berndt, N.M. Santhosh, C. Pattyn, A. Dias, T. Strunskus, M.-R. Ammar, A. Jagodar, M. Gaillard, C. Boulmer-Leborgne, U. Cvelbar
Published in: Nanotechnology, Issue 31, 2020, ISSN 0957-4484
Publisher: Institute of Physics Publishing
DOI: 10.1088/1361-6528/ab9b4a

Thermal stability studies of plasma deposited hydrogenated carbon nitride nanostructures

Author(s): E. Kovacevic, T. Strunskus, N. M. Santhosh, J. Zavašnik, W.E.S. Unger, T. Sauvage, M.-R. Ammar, U. Cvelbar, J. Berndt
Published in: Carbon, Issue 184, 2021, ISSN 0008-6223
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.carbon.2021.08.008

Simulations of a capacitor with graphene electrodes

Author(s): V Vachkov, Zh Kissovski
Published in: Journal of Physics: Conference Series, Issue 2240, 2022, ISSN 1742-6596
Publisher: IOP Publisher
DOI: 10.1088/1742-6596/2240/1/012036

Deposition of vertical carbon nanosheets by MPECVD at atmospheric pressure

Author(s): S. Marinov, V. Vachkov, Zh. Kissovski
Published in: Journal of Physics: Conference Series, Issue 1492, 2020, ISSN 1742-6596
Publisher: IOP Publishing
DOI: 10.1088/1742-6596/1492/1/012032

Oriented Carbon Nanostructures from Plasma Reformed Resorcinol-Formaldehyde Polymer Gels for Gas Sensor Applications

Author(s): N.M. Santhosh, A. Vasudevan, A. Jurov, G. Filipič, J. Zavašnik, U. Cvelbar
Published in: Nanomaterials, Issue 10, 2020, ISSN 2079-4991
Publisher: MDPI
DOI: 10.3390/nano10091704

Advancing Li-ion storage performance with hybrid vertical carbon/Ni3S2-based electrodes

Author(s): N.M. Santhosh, N. Shaji, P. Stražar, G. Filipič, J. Zavašnik, C.W. Ho, M. Nanthagopal, C.W. Lee, U. Cvelbar
Published in: Journal of Energy Chemistry, Issue 67, 2022, ISSN 2095-4956
Publisher: Elsevier BV
DOI: 10.1016/j.jechem.2021.09.034