Ru–Zn Heterobimetallic Complexes

Project Information

RuZn

Grant agreement ID: 792674

DOI 10.3030/792674

Project closed

EC signature date 15 March 2018

Start date 1 June 2018

End date 31 July 2020

Funded under

• EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions

Total cost € 183 454,80

EU contribution € 183 454,80

Coordinated by

UNIVERSITY OF BATH
United Kingdom

Objective

Fedor Miloserdov (FMM, the fellow) alongside Prof. Mike Whittlesey (MKW, University of Bath, UK) designed the RuZn proposal that deals with heterobimetallic late transition metal – Lewis acidic metal complexes, particularly ones featuring an unsupported Ru–Zn bond. Having similar properties with other Pt-group metals, Ru is more than order of magnitude cheaper. The cooperativity between Ru and Lewis acidic metal (Zn) can enhance the stability, selectivity and reactivity of the catalytic system and lead to new catalytic applications of ruthenium complexes, making them more appealing for both academia and industry. The rationale for the RuZn project is the 2016 report by MKW on the convenient approach to a novel complex with an unsupported Ru–Zn bond. FMM is going to synthesize a family of new Ru–Zn complexes with different ligand environments and systematically study their reactivity and stability in order to find suitable catalytic applications. The RuZn proposal aims not only at developing a new range of ruthenium catalysts, but will also provide FMM a unique opportunity to work on the cutting edge of science, as well as improve his skills in leadership, teaching, mentoring and grant-management. As an interdisciplinary part of the program, FMM will have a secondment with Prof. Stuart Macgregor (SAM) at Heriot-Watt university (Edinburgh, UK), where he will acquire knowledge in computational chemistry while studying the Ru–Zn bonding and reactivity.

Fields of science (EuroSciVoc)

CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques.

• natural sciences › chemical sciences › inorganic chemistry › transition metals
• natural sciences › chemical sciences › catalysis

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Programme(s)

• H2020-EU.1.3. - EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions Main Programme
• H2020-EU.1.3.2. - Nurturing excellence by means of cross-border and cross-sector mobility

Topic(s)

• MSCA-IF-2017 - Individual Fellowships

Call for proposal

H2020-MSCA-IF-2017

Funding Scheme

MSCA-IF-EF-ST - Standard EF

Coordinator

UNIVERSITY OF BATH

• Net EU contribution: € 183 454,80
• Address: CLAVERTON DOWN ; BA2 7AY Bath ; United Kingdom
• Activity type: Higher or Secondary Education Establishments
• Total cost: € 183 454,80