Objective The overarching goal of this proposal is to develop a novel experimental framework for quantifying the total specific surface area of organic matter and the wettability of pores in shales, and interpreting the displacement mechanism between gas and water by using a selective adsorption approach coupled with independent verified electron microscope measurements. The overarching goal of the project will be achieved through the following scientific objectives. First, a 3D structural model of the hydrophobic and hydrophilic site distribution in shales at around 50 nm resolution by combining FIB-SEM and high resolution TEM will be developed. This will provide an independent verification for later site-selective adsorption studies. Second, a vapour adsorption method by researching and verifying the most suitable probing vapours and the most reliable measuring approach will be developed. This will create a novel experimental framework for quantifying the total specific surface area of organic matter and the wettability of pores in shales, which will be verified by a previously-built 3D structural model. Last, the displacement mechanism between water and gas will be disclosed by determining the influence of hydrophobic and hydrophilic sites in shales using sequential adsorption and in situ NMR. This will be the essential theoretical part of the work for developing next generation enhanced gas recovery techniques through non-aqueous fluid injection and heat stimulation. The outputs of this project will disclose the chemical/wetting nature of pore systems in shales, which will be essential for improving current fluid transport models in shales by considering surface chemistry properties and developing the next generation of environmentally-friendly shale gas recovery technology through non-aqueous fluid injection and heat stimulation in order to serve shale gas development in the EU, U.S. and China. Fields of science natural sciencesphysical sciencesopticsmicroscopyengineering and technologyenvironmental engineeringenergy and fuelsfossil energynatural gas Keywords ACOSVA Programme(s) H2020-EU.1.3. - EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions Main Programme H2020-EU.1.3.2. - Nurturing excellence by means of cross-border and cross-sector mobility Topic(s) MSCA-IF-2017 - Individual Fellowships Call for proposal H2020-MSCA-IF-2017 See other projects for this call Funding Scheme MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF) Coordinator THE UNIVERSITY OF NOTTINGHAM Net EU contribution € 195 454,80 Address University Park NG7 2RD Nottingham United Kingdom See on map Region East Midlands (England) Derbyshire and Nottinghamshire Nottingham Activity type Higher or Secondary Education Establishments Links Contact the organisation Opens in new window Website Opens in new window Participation in EU R&I programmes Opens in new window HORIZON collaboration network Opens in new window Total cost € 195 454,80
