Safe and Prelithiated hIgh energy DEnsity batteries based on sulphur Rocksalt and silicon chemistries

Informations projet

SPIDER

N° de convention de subvention: 814389

DOI

10.3030/814389

Projet clôturé

Date de signature de la CE 12 Decembre 2018

Date de début 1 Janvier 2019

Date de fin 31 Août 2022

Financé au titre de

• INDUSTRIAL LEADERSHIP - Leadership in enabling and industrial technologies - Advanced materials

Coût total

€ 7 975 192,50

Contribution de l’UE

€ 7 975 192,50

Coordonné par

COMMISSARIAT A L ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
France

Periodic Reporting for period 3 - SPIDER (Safe and Prelithiated hIgh energy DEnsity batteries based on sulphur Rocksalt and silicon chemistries)

Période du rapport: 2021-09-01 au 2022-08-31

Résumé du contexte et des objectifs généraux du projet

Demand for electric vehicles (EVs) is rapidly increasing and, according to the European Green Vehicle Initiative Association (EGVIA), a significant increase of acceptance of EVs can come only via further and significant cost reductions and limitations of disadvantages compared to other propulsion technologies such as driving range, durability, “re-fueling” time and safety.
Knowledge-based improvements of Li-ion battery cost, performance, recyclability and safety are thus needed to enable electric vehicles to rapidly gain market share. It will reduce greenhouse gases (GHG) and air pollutants. Several SPIDER partners are identified by the European Battery Alliance as central and strategic for the creation of the needed European battery value chain. It will contribute to the development of a new, market competitive European battery cell chemistry and materials technology that will allow reduction of dependence from foreign supply, and build the knowledge base for creation of a competitive European automotive cell production.
The SPIDER project (H2020 Grant Agreement n° 814389) proposes a multidisciplinary approach to develop safe and long-lifetime, high energy density cells. This approach is based on new materials, improved chemistries, new industrially relevant manufacturing process steps and complimented by in-depth characterization, safety, modelling and Life-cycle-(cost) analysis studies.

SPIDER focuses on six main objectives:
- Increase cell energy density by 65% vs. State of the Art with non-critical, sustainable materials
- Reach power density of 800W/kg
- Reach 50% cost reduction for batteries by 2022
- Increase cycle life to 2000 cycles by 2022
- Increase cell safety by increasing thermal runaway temperature above 200°C and limiting the thermal energy dissipation to 4 kW/kg
- Develop a circular value chain for sustainable, recyclable (60 wt%) batteries in Europe.

SPIDER technologies will be implemented on 4 successive advanced Li-ion cell generations in which several concepts will be successively introduced: high capacity anode and cathode materials, prelithiation and advanced electrolyte formulations.
To this end, the project is organised in 8 work packages:
WP1 : End User Specifications
WP2: Prelithiation process development
WP3: Active materials development
WP4: Advanced safe electrolytes
WP5: Cell Manufacturing
WP6: Characterizations, modelling and tests (electrical and abusive)
WP7: Preparation of Market Entry within Circular value chain
WP8: Project and IP Management, Dissemination and Communication activities.

Travail effectué depuis le début du projet jusqu’à la fin de la période considérée dans le rapport et principaux résultats atteints jusqu’à présent

Since the beginning of the project, 37 deliverables were submitted with among them 4 public deliverables: D3.1 “Report on the benchmarking of state of the art materials”, D8.2 “Data Management Plan”, D8.3 “Communication tools” and "SPIDER Workshop"

The dissemination of the results was performed though 11 publications published, 4 participations in conference and the organization of SPIDER Workshop.

SPIDER has been supported by the Horizon Results Booster (HRB) for the definition of the exploitation strategy of the project. A second Exploitation Strategy Seminar (ESS 2) has been organized by the Expert of HRB with CEA and CRF and was held online on the 1st of April 2022. The ESS 2 was focused on two key exploitable results (KER), indentifies by the consortium:
- KER1: SPIDER cell with improved energy density and lower life cycle GHG emissions
- KER2: Life Cycle Assessment Models for the targeted novel battery technologies

The work performed resulted in the preparation of four cell generations: Gen0 [NMC811/Si-Carbon], Gen1 [NMC811/Si-Carbon with Prelithiation], Gen2 [NMC83%Ni / High capacity Si-Carbon with Prelithiation] and Gen3 [NMC83%Ni / Si-Carbon with Prelithiation]. Gen3 cells presented the best calculated energy density at 264 Wh/kg, it is 20% more than state of the art. The capacity loss for Gen3 cells is around 17% after 180 cycles @25°C / C-rate C / SOC 10-90. The cost reduction is evaluated at 13% in comparison with the baseline at the beginning of the project. Thanks to electrolyte developments the thermal runaway temperature has increased from 156°C with Gen 0 electrolytes to temperatures higher than 200°C and the recycling efficiency reached 64.8%.

In addition to the performance of the cells prepared, the conclusions of the actions are as follows:
• Direct contact prelithiation by mechanical application of Li metal film was successfully applied and shown significant improvements in cell performance
• Regarding the cathode material Li2TiS3 was not enough stable to be used in classic cells using liquid electrolytes however it could be used as a new cathode material for all solid state batteries without Co and Ni. Works performed on anode materials shown a tradeoff has to be found between capacity and cycle life.
• The electrolytes developments improved the safety and pave the way for further works on artificial SEIs using ionomer coatings and use of EC/PC-based electrolytes.
• Different cell chemistries were upscaled to pouch cell level. Si-based anode formulations were developed at industrial scale with high loading levels (4.5 mAh/cm2) and high specific capacity (up to 980 mAh/g) and high nickel NMC811 cathode formulations, both NMP-based and water-based, were manufactured with comparable capacity retention upon cycling.

Progrès au-delà de l’état des connaissances et impact potentiel prévu (y compris l’impact socio-économique et les conséquences sociétales plus larges du projet jusqu’à présent)

EV sales are predicted to grow considerably in the upcoming years, but the final success of increased EV deployment will depend on four main criteria: autonomy, cost, life cycle and safety of the vehicle.
P-HEV, EV and E-buses will be powered by Li-ion (11 B$ in 2020 & 22 B$ in 2025). However, EV technology is still far from achieving the commercial success of internal combustion engine vehicles.

SPIDER aimed to develop a next generation Li-ion battery with the potential to provide the technological progress that is necessary to accelerate the deployment rates of EVs. SPIDER developments are based on three main innovations :
- High capacity materials: By combining high energy active materials, SPIDER targets to reach 400 Wh/kg (+65% versus the state of the art) by the end of the project (or 450 Wh/kg by 2030).
- Prelithiation: SPIDER will implement a prelithiation step in the cell manufacturing process in order to achieve 2000 cycles at 50% DoD in EV and in total 5000 cycles considering also the second life with SPIDER batteries.
- Advanced electrolyte formulation: SPIDER will develop intrinsically safe liquid electrolyte formulations specifically designed for SPIDER chemistry and allowing (i)- Stabilized cycling of Si-Gr anode and (ii)- Low reactivity vs. the charged anode.

SPIDER also addressed characterization challenges, investigating phenomena and problems at the interfaces to then optimize SPIDER cells.

Regarding the socio-economical impacts, SPIDER batteries are expected to provide extremely flexible energy storage that can be used in all industries, especially in EVs, with markets worth billions of euros: a mass market could create 500,000 to 1.1 million net additional jobs in Europe by 2030 through innovations in the automotive sector. The partners all plan to hire new staff in order to exploit project results.

Automated High-Throughput Screening (HTS) equipment available at FZJ