Silicon Alloying Anodes for High Energy Density Batteries comprising Lithium Rich Cathodes and Safe Ionic Liquid based Electrolytes for Enhanced High VoltagE Performance.

Project Information

Si-DRIVE

Grant agreement ID: 814464

DOI 10.3030/814464

Project closed

EC signature date 12 December 2018

Start date 1 January 2019

End date 31 July 2023

Funded under

• INDUSTRIAL LEADERSHIP - Leadership in enabling and industrial technologies - Advanced materials

Total cost € 7 999 492,50

EU contribution € 7 999 492,50

Coordinated by

UNIVERSITY OF LIMERICK
Ireland

Deliverables

Websites, patent fillings, videos etc. (3)

1ST Si-DRIVE workshop
Project web site
2nd Si-DRIVE workshop

2nd SiDRIVE workshop

Publications

Peer reviewed articles (23)

Analysis of the Phase Stability of LiMO2 Layered Oxides (M = Co, Mn, Ni)

Author(s): Mariarosaria Tuccillo, Oriele Palumbo, Michele Pavone, Ana Belen Muñoz-García, Annalisa Paolone, Sergio Brutti
Published in: Crystals, Issue 10/6, 2020, Page(s) 526, ISSN 2073-4352
Publisher: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/cryst10060526

Elucidating the Effect of Iron Doping on the Electrochemical Performance of Cobalt‐Free Lithium‐Rich Layered Cathode Materials

Author(s): Fanglin Wu, Guk‐Tae Kim, Matthias Kuenzel, Huang Zhang, Jakob Asenbauer, Dorin Geiger, Ute Kaiser, Stefano Passerini
Published in: Advanced Energy Materials, Issue 9/43, 2019, Page(s) 1902445, ISSN 1614-6832
Publisher: Wiley-VCH Verlag
DOI: 10.1002/aenm.201902445

Performances of different DFT functionals to calculate the anodic limit of fluorinated sulphonyl-imide anions for lithium cells

Author(s): A. Paolone, S. Brutti
Published in: Journal of Physics: Conference Series, Issue 2090, 2021, Page(s) 012078, ISSN 1742-6596
Publisher: IOP Publishing Ltd
DOI: 10.1088/1742-6596/2090/1/012078

Synthesis, Physical Properties and Electrochemical Applications of Two Ionic Liquids Containing the Asymmetric (Fluoromethylsulfonyl)(Trifluoromethylsulfonyl)imide Anion

Author(s): Oriele Palumbo; Giovanni Battista Appetecchi; Giovanna Maresca; Jean-Blaise Brubach; Pascale Roy; Simone Di Muzio; Francesco Trequattrini; Delphine Bordignon; Florine Legrand; Anaïs Falgayrat; Rongying Lin; Sebastien Fantini; Annalisa Paolone
Published in: Applied sciences 12 (2022): 4524-1–4524-11. doi:10.3390/app12094524, Issue 18, 2022, ISSN 2523-3971
Publisher: MDPI
DOI: 10.3390/app12094524

Protic Ionic Liquids‐Based Crosslinked Polymer Electrolytes: A New Class of Solid Electrolytes for Energy Storage Devices

Author(s): Timo Stettner, Gabriele Lingua, Marisa Falco, Andrea Balducci, Claudio Gerbaldi
Published in: Energy Technology, 2020, Page(s) 2000742, ISSN 2194-4288
Publisher: Wiley-VCH Verlag
DOI: 10.1002/ente.202000742

A Copper Silicide Nanofoam Current Collector for Directly Grown Si Nanowire Networks and their Application as Lithium‐Ion Anodes

Author(s): Ibrahim Saana Aminu, Hugh Geaney, Sumair Imtiaz, Temilade E. Adegoke, Nilotpal Kapuria, Gearoid A. Collins, Kevin M. Ryan
Published in: Advanced Functional Materials, Issue 30/38, 2020, Page(s) 2003278, ISSN 1616-301X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/adfm.202003278

Towards more flexibility and transparency in life cycle inventories for Lithium-ion batteries

Author(s): Eleonora Crenna, Marcel Gauch, Rolf Widmer, Patrick Wäger, Roland Hischier
Published in: Resources, Conservation and Recycling, Issue Volume 170, July, 2021, 2021, Page(s) 105619, ISSN 0921-3449
Publisher: Elsevier BV

On the influence of second use, future battery technologies, and battery lifetime on the maximum recycled content of future electric vehicle batteries in Europe.

Author(s): Mohammad Abdelbaky; Jef Peeters; Wim Dewulf
Published in: Waste Management, Issue 4, 2021, Page(s) 1-9, ISSN 0956-053X
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.wasman.2021.02.032

A novel phosphonium ionic liquid electrolyte for high-voltage and high-energy lithium-metal batteries

Author(s): F. Wu, A.R. Schür, G.-T. Kim, X. Dong, M. Kuenzel, T. Diemant, G. D’Orsi, E. Simonetti, M. De Francesco, M. Bellusci, G.B. Appetecchi, S. Passerini
Published in: Energy Storage Materials, Issue e42, 2021, Page(s) 826-835, ISSN 2405-8297
Publisher: Elsevier
DOI: 10.1016/j.ensm.2021.08.030

Influence of Carbonate-Based Additives on the Electrochemical Performance of Si NW Anodes Cycled in an Ionic Liquid Electrolyte

Author(s): Killian Stokes, Tadhg Kennedy, Guk-Tae Kim, Hugh Geaney, Dylan Storan, Fathima Laffir, Giovanni Battista Appetecchi, Stefano Passerini, Kevin M. Ryan
Published in: Nano Letters, 2020, ISSN 1530-6984
Publisher: American Chemical Society
DOI: 10.1021/acs.nanolett.0c01774

Lignin for energy applications – state of the art, life cycle, technoeconomic analysis and future trends

Author(s): Anne Beaucamp; Muhammad Muddasar; Ibrahim Saana Amiinu; Marina Moraes Leite; Mario Culebras; Kenneth Latha; María C. Gutiérrez; Daily Rodriguez-Padron; Francisco del Monte; Tadhg Kennedy; Kevin M. Ryan; Rafael Luque; Maria-Magdalena Titirici; Maurice N. Collins
Published in: Green Chemistry, Issue 20, 2022, ISSN 1463-9270
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2gc02724k

Comparison of the Performances of Different Computational Methods to Calculate the Electrochemical Stability of Selected Ionic Liquids

Author(s): Annalisa Paolone; Sergio Brutti
Published in: Materials, Issue 14 (12), 2021, Page(s) 3221, ISSN 1996-1944
Publisher: MDPI Open Access Publishing
DOI: 10.3390/ma14123221

Reducing Capacity and Voltage Decay of Co‐Free Li 1.2 Ni 0.2 Mn 0.6 O 2 as Positive Electrode Material for Lithium Batteries Employing an Ionic Liquid‐Based Electrolyte

Author(s): Fanglin Wu, Guk‐Tae Kim, Thomas Diemant, Matthias Kuenzel, Annika Regitta Schür, Xinpei Gao, Bingsheng Qin, Dorothea Alwast, Zenonas Jusys, Rolf Jürgen Behm, Dorin Geiger, Ute Kaiser, Stefano Passerini
Published in: Advanced Energy Materials, Issue 10/34, 2020, Page(s) 2001830, ISSN 1614-6832
Publisher: Wiley-VCH Verlag
DOI: 10.1002/aenm.202001830

Forecasting the EU recycling potential for batteries from electric vehicles

Author(s): Mohammad Abdelbaky, Jef R. Peeters, Joost R. Duflou, Wim Dewulf
Published in: Procedia CIRP, Issue 90, 2020, Page(s) 432-436, ISSN 2212-8271
Publisher: Procedia CIRP
DOI: 10.1016/j.procir.2020.01.109

So similar, yet so different: the case of the ionic liquids N-trimethyl-N(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)imide and N,N-diethyl-N-methyl-N(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)imide

Author(s): Oriele Palumbo; Angelo Sarra; Jean-Blaise Brubach; Francesco Trequattrini; Adriano Cimini; Sergio Brutti; Giovanni Battista Appetecchi; Elisabetta Simonetti; Giovanna Maresca; Sébastien Fantini; Rongying Lin; Anaïs Falgayrat; Pascale Roy; Annalisa Paolone
Published in: Frontiers in Physics 10 (2022): 851279-1–851279-11. doi:10.3389/fphy.2022.851279, Issue 18, 2022, ISSN 0429-7725
Publisher: Frontiers in Physics 10
DOI: 10.3389/fphy.2022.851279

Li1.4Al0.4Ge0.4Ti1.4(PO4)3 promising NASICON-structured glass-ceramic electrolyte for all-solid-state Li-based batteries: Unravelling the effect of diboron trioxide

Author(s): S. Saffirio, M. Falco, G.B. Appetecchi, F. Smeacetto, C. Gerbaldi
Published in: Journal of the European Ceramic Society, Issue e42, 2021, Page(s) 1023-1032, ISSN 0955-2219
Publisher: Elsevier BV
DOI: 10.1016/j.jeurceramsoc.2021.11.014

Copper Silicide Nanowires as Hosts for Amorphous Si Deposition as a Route to Produce High Capacity Lithium-Ion Battery Anodes

Author(s): Killian Stokes, Hugh Geaney, Martin Sheehan, Dana Borsa, Kevin M. Ryan
Published in: Nano Letters, Issue 19/12, 2019, Page(s) 8829-8835, ISSN 1530-6984
Publisher: American Chemical Society
DOI: 10.1021/acs.nanolett.9b03664

Decomposition temperatures and vapour pressures of selected ionic liquids for electrochemical applications

Author(s): Adriano Cimini; Oriele Palumbo; E. Simonetti; M. De Francesco; Giovanni Battista Appetecchi; Sébastien Fantini; Rongying Lin; A. Falgayrat; Annalisa Paolone
Published in: Journal of Thermal Analysis and Calorimetry, Issue 3, 2020, Page(s) e142, ISSN 1572-8943
Publisher: Springer
DOI: 10.1007/s10973-020-10334-5

Ionic liquid electrolytes for high-voltage, lithium-ion batteries

Author(s): Brutti, S.; Simonetti, E.; De Francesco, M.; Sarra, A.; Paolone, A.; Palumbo, O.; Fantini, S.; Lin, R.; Falgayrat, A.; Choi, H.; Kuenzel, M.; Passerini, S.; Appetecchi, G. B.
Published in: Journal of Power Sources, Issue 479, 2020, ISSN 0378-7753
Publisher: Elsevier BV
DOI: 10.1016/j.jpowsour.2020.228791

Enabling safe and stable Li metal batteries with protic ionic liquid electrolytes and high voltage cathodes

Author(s): Gabriele Lingua, Marisa Falco, Timo Stettner, Claudio Gerbaldi, Andrea Balducci
Published in: Journal of Power Sources, Issue 481, 2021, Page(s) 228979, ISSN 0378-7753
Publisher: Elsevier BV
DOI: 10.1016/j.jpowsour.2020.228979

A bilayer polymer electrolyte encompassing pyrrolidinium-based RTIL for binder-free silicon few-layer graphene nanocomposite anodes for Li-ion battery

Author(s): M. Falco, S. Palumbo, G. Lingua, L. Silvestri, M. Winter, R. Lin, V. Pellegrini, F. Bonaccorso, Jijeesh R. Nair, C. Gerbaldi
Published in: Electrochemistry Communications, Issue 118, 2020, Page(s) 106807, ISSN 1388-2481
Publisher: Elsevier BV
DOI: 10.1016/j.elecom.2020.106807

Thermodynamics of the Hydrolysis of Lithium Salts: Pathways to the Precipitation of Inorganic SEI Components in Li-Ion Batteries

Author(s): Simone Di Muzio; Annalisa Paolone; Sergio Brutti
Published in: Journal of The Electrochemical Society, Issue 5, 2021, Page(s) 100514, ISSN 0000-0000
Publisher: IOP Publishing Limited
DOI: 10.1149/1945-7111/ac2aca

End-of-Life Electric Vehicle Battery Stock Estimation in Ireland through Integrated Energy and Circular Economy Modelling

Author(s): Narjes Fallah, Colin Fitzpatrick, Sheila Killian, Michael Johnson
Published in: Resources, Conservation and Recycling, Issue Volume 174, November, 2021, 2021, Page(s) 105753, ISSN 0921-3449
Publisher: Elsevier BV
DOI: 10.1016/j.resconrec.2021.105753

Conference proceedings (1)

Comparing the environmental performance of industrial recycling routes for lithium nickel-cobalt-manganese oxide 111 vehicle batteries

Author(s): Mohammad Abdelbaky, Lilian Schwich, Eleonora Crenna, Jef R. Peeters, Roland Hischier, Bernd Friedrich, Wim Dewulf
Published in: Procedia CIRP, Issue Volume 98, March, 2021, 2021, Page(s) 97-102, ISSN 2212-8271
Publisher: Elsevier Ltd.
DOI: 10.1016/j.procir.2021.01.012