Multiscale chemical engineering of functional metal halides

Luminescent Lead Halide Ionic Liquids for High-Spatial-Resolution Fast Neutron Imaging

Author(s): Viktoriia Morad; Kyle M. McCall; Kostiantyn Sakhatskyi; Eberhard Lehmann; Bernhard Walfort; Adrian S. Losko; Pavel Trtik; Markus Strobl; Sergii Yakunin; Maksym V. Kovalenko
Published in: ACS Photonics, Issue 1, 2021, Page(s) 3357–3364, ISSN 2330-4022
Publisher: American Chemical Society
DOI: 10.1021/acsphotonics.1c01348

The Rb 7 Bi 3−3 x Sb 3 x Cl 16 Family: A Fully Inorganic Solid Solution with Room‐Temperature Luminescent Members

Author(s): Bogdan M. Benin, Kyle M. McCall, Michael Wörle, Viktoriia Morad, Marcel Aebli, Sergii Yakunin, Yevhen Shynkarenko, Maksym V. Kovalenko
Published in: Angewandte Chemie International Edition, Issue 59/34, 2020, Page(s) 14490-14497, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202003822

Supramolecular Approach for Fine-Tuning of the Bright Luminescence from Zero-Dimensional Antimony(III) Halides

Author(s): Viktoriia Morad, Sergii Yakunin, Maksym V. Kovalenko
Published in: ACS Materials Letters, Issue 2/7, 2020, Page(s) 845-852, ISSN 2639-4979
Publisher: American Chemical Society
DOI: 10.1021/acsmaterialslett.0c00174

The dark exciton ground state promotes photon-pair emission in individual perovskite nanocrystals

Author(s): P. Tamarat, L. Hou, J. Trebbia, A. Swarnkar, L. Biadala, Y. Louyer, M.I. Bodnarchuk, M.V. Kovalenko, J. Even & B. Lounis
Published in: Nature Communications, 2020, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-020-19740-7

Intrinsic Formamidinium Tin Iodide Nanocrystals by Suppressing the Sn(IV) Impurities

Author(s): Dmitry N. Dirin; Anna Vivani; Marios Zacharias; Taras V. Sekh; Ihor Cherniukh; Sergii Yakunin; Federica Bertolotti; Marcel Aebli; Richard D. Schaller; Alexander Wieczorek; Sebastian Siol; Claudia Cancellieri; Lars P. H. Jeurgens; Norberto Masciocchi; Antonietta Guagliardi; Laurent Pedesseau; Jacky Even; Maksym V. Kovalenko; Maryna I. Bodnarchuk
Published in: ACS Nanoletters, Issue 1, 2023, ISSN 1530-6992
Publisher: American Chemical Society
DOI: 10.1021/acs.nanolett.2c04927

Highly Concentrated, Zwitterionic Ligand-Capped Mn2+:CsPb(BrxCl1–x)3 Nanocrystals as Bright Scintillators for Fast Neutron Imaging

Author(s): Federico Montanarella, Kyle M. McCall*, Kostiantyn Sakhatskyi, Sergii Yakunin, Pavel Trtik, Caterina Bernasconi, Ihor Cherniukh, David Mannes, Maryna I. Bodnarchuk, Markus Strobl, Bernhard Walfort, and Maksym V. Kovalenko
Published in: ACS Energy Letters, 2021, ISSN 2380-8195
Publisher: American Chemical Society
DOI: 10.1021/acsenergylett.1c01923

Lone-Pair-Induced Structural Ordering in the Mixed-Valent 0D Metal-Halides Rb23BiIIIxSbIII7–xSbV2Cl54 (0 ≤ x ≤ 7)

Author(s): Bogdan M. Benin, Kyle M. McCall, Michael Wörle, Dominique Borgeaud, Thomas Vonderach, Kostiantyn Sakhatskyi, Sergii Yakunin, Detlef Günther, and Maksym V. Kovalenko
Published in: Chemistry of Materials, 2021, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.0c04491

Efficient Lone-Pair-Driven Luminescence: Structure–Property Relationships in Emissive 5s 2 Metal Halides

Author(s): Kyle M. McCall, Viktoriia Morad, Bogdan M. Benin, Maksym V. Kovalenko
Published in: ACS Materials Letters, Issue 2/9, 2020, Page(s) 1218-1232, ISSN 2639-4979
Publisher: American Chemical Society
DOI: 10.1021/acsmaterialslett.0c00211

Colloidal CsPbX3 Nanocrystals with Thin Metal Oxide Gel Coatings

Author(s): Dominic Guggisberg, Sergii Yakunin, Christoph Neff, Marcel Aebli, Detlef Günther, Maksym V. Kovalenko*, and Dmitry N. Dirin
Published in: Chemistry of Materials, 2023, ISSN 1520-5002
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.2c03562

Ultra-narrow room-temperature emission from single CsPbBr3 perovskite quantum dots

Author(s): G. Rainò, N. Yazdani, S.C. Boehme, M. Kober-Czerny, C. Zhu, F. Krieg, M.D. Rossell, R. Erni, V. Wood, I. Infante and M.V. Kovalenko
Published in: Nature Communications, 2022, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.3929/ethz-b-000552631

Crystal Structure, Morphology, and Surface Termination of Cyan-Emissive, Six-Monolayers-Thick CsPbBr 3 Nanoplatelets from X-ray Total Scattering

Author(s): Federica Bertolotti, Georgian Nedelcu, Anna Vivani, Antonio Cervellino, Norberto Masciocchi, Antonietta Guagliardi, Maksym V. Kovalenko
Published in: ACS Nano, Issue 13/12, 2019, Page(s) 14294-14307, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.9b07626

On the Mechanism of Alkylammonium Ligands Binding to the Surface of CsPbBr3 Nanocrystals

Author(s): Andriy Stelmakh; Marcel Aebli; Andrij Baumketner; Maksym V. Kovalenko
Published in: Chemistry of Materials, 33 (15), Issue 1, 2021, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.29363/nanoge.incnc.2021.009

Solid-State NMR and NQR Spectroscopy of Lead-Halide Perovskite Materials

Author(s): Laura Piveteau, Viktoriia Morad, Maksym V. Kovalenko
Published in: Journal of the American Chemical Society, Issue 142/46, 2020, Page(s) 19413-19437, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c07338

Perovskite-type superlattices from lead halide perovskite nanocubes

Author(s): I. Cherniukh, G. Rainò, T. Stöferle, M. Burian, A. Travesset, D. Naumenko, H. Amenitsch, R. Erni, R.F. Mahrt, M.I. Bodnarchuk & M.V. Kovalenko
Published in: Nature, 2021, ISSN 0028-0836
Publisher: Nature Publishing Group
DOI: 10.1038/s41586-021-03492-5

Exploiting the Lability of Metal Halide Perovskites for Doping Semiconductor Nanocomposites

Author(s): Mariano Calcabrini; Aziz Genç; Aziz Genç; Yu Liu; Tobias Kleinhanns; Seungho Lee; Dmitry N. Dirin; Dmitry N. Dirin; Quinten A. Akkerman; Quinten A. Akkerman; Maksym V. Kovalenko; Maksym V. Kovalenko; Jordi Arbiol; Maria Ibáñez
Published in: ACS Energy Letters, Issue 2, 2021, ISSN 2380-8195
Publisher: American Chemical Society
DOI: 10.1021/acsenergylett.0c02448

Polaron and Spin Dynamics in Organic–Inorganic Lead Halide Perovskite Nanocrystals

Author(s): Megha Shrivastava, Maryna I. Bodnarchuk, Abhijit Hazarika, Joseph M. Luther, Matthew C. Beard, Maksym V. Kovalenko, K. V. Adarsh
Published in: Advanced Optical Materials, Issue 8/24, 2020, Page(s) 2001016, ISSN 2195-1071
Publisher: Wiley
DOI: 10.1002/adom.202001016

Seed-Crystal-Induced Cold Sintering Toward Metal Halide Transparent Ceramic Scintillators

Author(s): K. Han, K. Sakhatskyi, J. Jin, Q. Zhang, M.V. Kovalenko, Z. Xia
Published in: Advanced Materials, 2022, ISSN 0935-9648
Publisher: United Nations Industrial Developement Organization
DOI: 10.1002/adma.202110420

Assessing the Drawbacks and Benefits of Ion Migration in Lead Halide Perovskites

Author(s): K. Sakhatskyi, R.A. John, A. Guerrero, S. Tsarev, S. Sabisch, T. Das, G.J. Matt, S. Yakunin, I. Cherniukh, M. Kotyrba, Y. Berezovska, M.I. Bodnarchuk, S. Chakraborty, J. Bisquert, and M.V. Kovalenko
Published in: ACS Energy Letters, Issue 7, 2022, Page(s) 3401–3414, ISSN 2380-8195
Publisher: American Chemical Society
DOI: 10.1021/acsenergylett.2c01663

Ligands Mediate Anion Exchange between Colloidal Lead-Halide Perovskite Nanocrystals

Author(s): E. Scharf, F. Krieg, O. Elimelech, M. Oded, A. Levi, D.N. Dirin, M.V. Kovalenko, and U. Banin
Published in: Nano Letters, 2022, ISSN 1530-6984
Publisher: American Chemical Society
DOI: 10.3929/ethz-b-000553528

Hybrid 0D Antimony Halides as Air-Stable Luminophores for High-Spatial-Resolution Remote Thermography

Author(s): Viktoriia Morad, Sergii Yakunin, Bogdan M. Benin, Yevhen Shynkarenko, Matthias J. Grotevent, Ivan Shorubalko, Simon C. Boehme, Maksym V. Kovalenko
Published in: Advanced Materials, 2021, ISSN 0935-9648
Publisher: United Nations Industrial Developement Organization
DOI: 10.1002/adma.202007355

White CsPbBr 3 : Characterizing the One‐Dimensional Cesium Lead Bromide Polymorph

Author(s): Marcel Aebli, Bogdan M. Benin, Kyle M. McCall, Viktoriia Morad, Debora Thöny, Hansjörg Grützmacher, Maksym V. Kovalenko
Published in: Helvetica Chimica Acta, Issue 103/7, 2020, ISSN 0018-019X
Publisher: Verlag Helvetica Chimica Acta
DOI: 10.1002/hlca.202000080

Bright Blue and Green Luminescence of Sb(III) in Double Perovskite Cs 2 MInCl 6 (M = Na, K) Matrices

Author(s): Agnieszka Noculak, Viktoriia Morad, Kyle M. McCall, Sergii Yakunin, Yevhen Shynkarenko, Michael Wörle, Maksym V. Kovalenko
Published in: Chemistry of Materials, Issue 32/12, 2020, Page(s) 5118-5124, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.0c01004

Radiative lifetime-encoded unicolour security tags using perovskite nanocrystals

Author(s): S. Yakunin, J. Chaaban, B.M. Benin, I. Cherniukh, C. Bernasconi, A. Landuyt, Y. Shynkarenko, S. Bolat, C. Hofer, Y.E. Romanyuk, S. Cattaneo, S.I. Pokutnyi, R.D. Schaller, M.I. Bodnarchuk, D. Poulikakos & M.V. Kovalenko
Published in: Nature Communications, 2021, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-021-21214-3

Room-Temperature Anomalous Coherent Excitonic Optical Stark Effect in Metal Halide Perovskite Quantum Dots

Author(s): Megha Shrivastava, Franziska Krieg, Dipendranath Mandal, Ajay K. Poonia, Santu K. Bera, Maksym V. Kovalenko, and K. V. Adarsh*
Published in: Nano Letters, 2022, ISSN 1530-6984
Publisher: American Chemical Society
DOI: 10.1021/acs.nanolett.1c04471

Direct Synthesis of Quaternary Alkylammonium-Capped Perovskite Nanocrystals for Efficient Blue and Green Light-Emitting Diodes

Author(s): Yevhen Shynkarenko, Maryna I. Bodnarchuk, Caterina Bernasconi, Yuliia Berezovska, Vladyslav Verteletskyi, Stefan T. Ochsenbein, Maksym V. Kovalenko
Published in: ACS Energy Letters, Issue 4/11, 2019, Page(s) 2703-2711, ISSN 2380-8195
Publisher: America Chemical Society
DOI: 10.1021/acsenergylett.9b01915

Superradiant emission from self-assembled light emitters: From molecules to quantum dots

Author(s): G. Rainò, H. Utzat, M.G. Bawendi, M.V. Kovalenko
Published in: MRS Bulletin, Issue 45, 2020, Page(s) 841-849, ISSN 1938-1425
Publisher: Materials Research Society
DOI: 10.1557/mrs.2020.250

Stable Ultraconcentrated and Ultradilute Colloids of CsPbX 3 (X = Cl, Br) Nanocrystals Using Natural Lecithin as a Capping Ligand

Author(s): Franziska Krieg, Quy K. Ong, Max Burian, Gabriele Rainò, Denys Naumenko, Heinz Amenitsch, Adrian Süess, Matthias J. Grotevent, Frank Krumeich, Maryna I. Bodnarchuk, Ivan Shorubalko, Francesco Stellacci, Maksym V. Kovalenko
Published in: Journal of the American Chemical Society, Issue 141/50, 2019, Page(s) 19839-19849, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.9b09969

Unraveling the Origin of the Long Fluorescence Decay Component of Cesium Lead Halide Perovskite Nanocrystals

Author(s): Michael A. Becker, Caterina Bernasconi, Maryna I. Bodnarchuk, Gabriele Rainò, Maksym V. Kovalenko, David J. Norris, Rainer F. Mahrt, Thilo Stöferle
Published in: ACS Nano, Issue 14/11, 2020, Page(s) 14939-14946, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.0c04401

Hybrid Metal Halides with Multiple Photoluminescence Centers

Author(s): Mingze Li, Jun Zhou, Guojun Zhou, Maxim S. Molokeev, Jing Zhao, Viktoriia Morad, Maksym V. Kovalenko, Zhiguo Xia
Published in: Angewandte Chemie International Edition, Issue 58/51, 2019, Page(s) 18670-18675, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.201911419

Hot Excitons Cool in Metal Halide Perovskite Nanocrystals as Fast as CdSe Nanocrystals

Author(s): D.P. Strandell, D. Zenatti, P. Nagpal, A. Ghosh, D.N. Dirin, M.V. Kovalenko, and P. Kambhampati
Published in: ACS Nano, 2023, ISSN 1936-086X
Publisher: American Chemical Society
DOI: 10.1021/acsnano.3c10301

Bulk and Nanocrystalline Cesium Lead-Halide Perovskites as Seen by Halide Magnetic Resonance

Author(s): Laura Piveteau, Marcel Aebli, Nuri Yazdani, Marthe Millen, Lukas Korosec, Franziska Krieg, Bogdan M. Benin, Viktoriia Morad, Christophe Piveteau, Toni Shiroka, Aleix Comas-Vives, Christophe Copéret, Aaron M. Lindenberg, Vanessa Wood, René Verel, Maksym V. Kovalenko
Published in: ACS Central Science, Issue 6/7, 2020, Page(s) 1138-1149, ISSN 2374-7943
Publisher: American Chemical Society
DOI: 10.1021/acscentsci.0c00587

Hot Carrier Dynamics in Perovskite Nanocrystal Solids: Role of the Cold Carriers, Nanoconfinement, and the Surface

Author(s): Thomas R. Hopper, Andrei Gorodetsky, Ahhyun Jeong, Franziska Krieg, Maryna I. Bodnarchuk, Marios Maimaris, Marine Chaplain, Thomas J. Macdonald, Xiaokun Huang, Robert Lovrincic, Maksym V. Kovalenko, Artem A. Bakulin
Published in: Nano Letters, Issue 20/4, 2020, Page(s) 2271-2278, ISSN 1530-6984
Publisher: American Chemical Society
DOI: 10.1021/acs.nanolett.9b04491

Size- and Temperature-Dependent Lattice Anisotropy and Structural Distortion in CsPbBr₃ Quantum Dots by Reciprocal Space X-ray Total Scattering Analysis

Author(s): F. Bertolotti, N. Dengo, A. Cervellino, M.I. Bodnarchuk, C. Bernasconi, I. Cherniukh, Y. Berezovska, S.C. Boehme, M.V. Kovalenko, N. Masciocchi, A. Guagliardi
Published in: Small Structures, 2023, ISSN 2688-4062
Publisher: Wiley
DOI: 10.1002/sstr.202300264

Designer Phospholipid Capping Ligands for Soft Metal Halide Nanocrystals

Author(s): V. Morad, A. Stelmakh, M. Svyrydenko, L.G. Feld, S.C. Boehme, M. Aebli, J. Affolter, C.J. Kaul, N.J. Schrenker, S. Bals, Y. Sahin, D.N. Dirin, I. Cherniukh, G. Raino, A. Baumketner, M.V. Kovalenko
Published in: Nature, 2023, ISSN 1476-4687
Publisher: Nature
DOI: 10.1038/s41586-023-06932-6

Enhancing Multiexcitonic Emission in Metal-Halide Perovskites by Quantum Confinement

Author(s): D. Strandell, D. Dirin, D. Zenatti, P. Nagpal, A. Ghosh, G. Raino, M.V. Kovalenko, and P. Kambhampati
Published in: ACS Nano, 2023, ISSN 1936-086X
Publisher: American Chemical Society
DOI: 10.1021/acsnano.3c06497

Expanding the 0D Rb 7 M 3 X 16 (M=Sb, Bi; X=Br, I) Family: Dual‐Band Luminescence in Rb 7 Sb 3 Br 16

Author(s): Kyle M. McCall, Bogdan M. Benin, Michael Wörle, Thomas Vonderach, Detlef Günther, Maksym V. Kovalenko
Published in: Helvetica Chimica Acta, 2020, ISSN 0018-019X
Publisher: Verlag Helvetica Chimica Acta
DOI: 10.1002/hlca.202000206

Manganese(II) in Tetrahedral Halide Environment: Factors Governing Bright Green Luminescence

Author(s): Viktoriia Morad, Ihor Cherniukh, Lena Pöttschacher, Yevhen Shynkarenko, Sergii Yakunin, Maksym V. Kovalenko
Published in: Chemistry of Materials, Issue 31/24, 2019, Page(s) 10161-10169, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.9b03782

Structural Diversity in Multicomponent Nanocrystal Superlattices Comprising Lead Halide Perovskite Nanocubes

Author(s): Ihor Cherniukh; Taras V. Sekh; Gabriele Rainò; Olivia J. Ashton; Max Burian; Alex Travesset; Modestos Athanasiou; Andreas Manoli; Rohit Abraham John; Mariia Svyrydenko; Viktoriia Morad; Yevhen Shynkarenko; Federico Montanarella; Denys Naumenko; Heinz Amenitsch; Grigorios Itskos; Rainer F. Mahrt; Thilo Stöferle; Rolf Erni; Maksym V. Kovalenko; Maryna I. Bodnarchuk
Published in: Crossref, Issue 5, 2022, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.1c10702

Colloidal-ALD-Grown Core/Shell CdSe/CdS Nanoplatelets as Seen by DNP Enhanced PASS–PIETA NMR Spectroscopy

Author(s): Laura Piveteau, Dmitry N. Dirin, Christopher P. Gordon, Brennan J. Walder, Ta-Chung Ong, Lyndon Emsley, Christophe Copéret, Maksym V. Kovalenko
Published in: Nano Letters, Issue 20/5, 2020, Page(s) 3003-3018, ISSN 1530-6984
Publisher: American Chemical Society
DOI: 10.1021/acs.nanolett.9b04870

Strongly Confined CsPbBr<sub>3</sub> Quantum Dots as Quantum Emitters and Building Blocks for Rhombic Superlattices

Author(s): Boehme, Simon C; Bodnarchuk, Maryna I; Burian, Max; Bertolotti, Federica; Cherniukh, Ihor; Bernasconi, Caterina; Zhu, Chenglian; Erni, Rolf; Amenitsch, Heinz; Naumenko, Denys; Andrusiv, Hordii; Semkiv, Nazar; John, Rohit Abraham; Baldwin, Alan; Galkowski, Krzysztof; Masciocchi, Norberto; Stranks, Samuel D; Rainò, Gabriele; Guagliardi, Antonietta; Kovalenko, Maksym V
Published in: ACS Nano, 17 (3), Issue 1, 2023, ISSN 1936-086X
Publisher: American Chemical Society
DOI: 10.1021/acsnano.2c07677

Local Structure of Multinary Hybrid Lead Halide Perovskites Investigated by Nuclear Quadrupole Resonance Spectroscopy

Author(s): Marcel Aebli; Nikolaus Porenta; Nina Aregger; Maksym V. Kovalenko
Published in: Chemistry of Materials, 33 (17), Issue 1, 2021, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.1c01945

Shape-Directed Co-Assembly of Lead Halide Perovskite Nanocubes with Dielectric Nanodisks into Binary Nanocrystal Superlattices

Author(s): I. Cherniukh, G. Rainò, T.V. Sekh, C. Zhu, Y. Shynkarenko, R.A. John, E. Kobiyama, R.F. Mahrt, T. Stöferle, R. Erni, M.V. Kovalenko, and M.I. Bodnarchuk
Published in: ACS Nano, 2021, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.1c06047

Size Segregation and Atomic Structural Coherence in Spontaneous Assemblies of Colloidal Cesium Lead Halide Nanocrystals

Author(s): Federica Bertolotti; Anna Vivani; Fabio Ferri; Pietro Anzini; Antonio Cervellino; Maryna I. Bodnarchuk; Georgian Nedelcu; Caterina Bernasconi; Maksym V. Kovalenko; Norberto Masciocchi; Antonietta Guagliardi
Published in: Chemistry of Materials, 34 (2), Issue 4, 2022, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.1c03162

Controlling the nucleation and growth kinetics of lead halide perovskite quantum dots

Author(s): Q.A. Akkerman, T.P.T. Nguyen, S.C. Boehme, F. Montanarella, D.N. Dirin, P. Wechsler, F. Beiglböck, G. Raino, R. Erni, C. Katan, J. Even, M.V. Kovalenko
Published in: Science, 2022, ISSN 1095-9203
Publisher: AAAS
DOI: 10.21203/rs.3.rs-1236393/v1

Colloidal aziridinium lead bromide quantum dots

Author(s): M.I. Bodnarchuk, L.G. Feld, C. Zhu, S.C. Boehme, F. Bertolotti, J. Avaro, M. Aebli, S.H. Mir, N. Masciocchi, R. Erni, S. Chakraborty, A. Guagliardi, G. Rainò, M.V. Kovalenko
Published in: Research Square, 2023
Publisher: Research Square
DOI: 10.21203/rs.3.rs-3671642/v1

Lead-Free Low-Dimensional Main Group Metal Halides: New Self-Trapped Excitonic Emitters and Their Applications

Author(s): Benin, Bogdan M.
Published in: 2020
Publisher: Benin, Bogdan M., ETH Zürich
DOI: 10.3929/ethz-b-000446190

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