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IONGELS: FROM NEW CHEMISTRY TOWARD EMERGING APPLICATIONS

Deliverables

Guidelines biodegradable iongels

Report on the biocompatible/biodegradable iongels and electronically

Networking event reports

All the networking event will be reported in one single report at the end of the project

Project webpage

The details of the project website will be reported

PEDOT/biopolymer dispersions

Protocols for preparation of functionalized PEDOT/biopolymer dispersions and new semiconjugated polymers

Guidelines conducting polymer iongels

Report on conducting polymer iongels (preparation and characterization)

Synthesis of precursors

Protocols for the reproducible synthesis of precursor compounds, including biocompatible protic ionic liquids, deep eutectic solvents, and biodegradable poly(ionic liquids)

Publications

Water Soluble Cationic Poly(3,4‐Ethylenedioxythiophene) PEDOT‐N as a Versatile Conducting Polymer for Bioelectronics

Author(s): Daniela Minudri, Daniele Mantione, Antonio Dominguez‐Alfaro, Sergio Moya, Eliana Maza, Christian Bellacanzone, Maria Rosa Antognazza, David Mecerreyes
Published in: Advanced Electronic Materials, Issue 6/10, 2020, Page(s) 2000510, ISSN 2199-160X
Publisher: Wiley
DOI: 10.1002/aelm.202000510

Emerging Ionic Soft Materials Based on Deep Eutectic Solvents.

Author(s): Liliana C. Tomé and David Mecerreyes
Published in: The Journal of Physical Chemistry B, Issue 124(39), 2020, Page(s) 8465-8478, ISSN 1520-6106
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcb.0c04769

Mixed Ionic-Electronic Conductors Based on PEDOT:PolyDADMA and Organic Ionic Plastic Crystals

Author(s): Rafael Del Olmo, Nerea Casado, Jorge L. Olmedo-Martínez, Xiaoen Wang, Maria Forsyth
Published in: Polymers, Issue 12/9, 2020, Page(s) 1981, ISSN 2073-4360
Publisher: MDPI
DOI: 10.3390/polym12091981

Direct ink writing of PEDOT eutectogels as substrate-free dry electrodes for electromyography

Author(s): Ana Aguzin, Antonio Dominguez-Alfaro, Miryam Criado-Gonzalez, Santiago Velasco-Bosom, Matías L. Picchio, Nerea Casado, Eleni Mitoudi-Vagourdi, Roque J. Minari, George G. Malliaras and David Mecerreyes.
Published in: Materials Horizons, Issue 10, 2023, Page(s) 2516-2524, ISSN 2051-6355
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3mh00310h

Catechol-containing acrylic Poly(ionic liquid) Hydrogels as Bioinspired Filters for Water Decontamination

Author(s): Antonela Gallastegui, Luca Porcarelli, Rodrigo E. Palacios, M. Lorena Gómez, and David Mecerreyes
Published in: ACS Applied Polymer Materials, Issue 1/7, 2019, Page(s) 1887-1895, ISSN 2637-6105
Publisher: ACS Publications
DOI: 10.1021/acsapm.9b00443

A Low‐Swelling Polymeric Mixed Conductor Operating in Aqueous Electrolytes

Author(s): Tommaso Nicolini, Jokubas Surgailis, Achilleas Savva, Alberto Scaccabarozzi, Rana Nakar, Damien Thuau, Guillaume Wantz, Lee Richter, Olivier Dautel, Georges Hadziioannou, Natalie Stingelin
Published in: Advanced Materials, Issue 33, 2, 2021, Page(s) 2005723, ISSN 1521-4095
Publisher: Wiley
DOI: 10.1002/adma.202005723

Single‐Ion Conducting Poly(Ethylene Oxide Carbonate) as Solid Polymer Electrolyte for Lithium Batteries

Author(s): Leire Meabe, Nicolas Goujon, Chunmei Li, Michel Armand, Maria Forsyth, David Mecerreyes
Published in: Batteries & Supercaps, Issue 3/1, 2019, Page(s) 68-75, ISSN 2566-6223
Publisher: Wiley
DOI: 10.1002/batt.201900119

Conducting Polymer-Ionic Liquid Electrode Arrays for High-Density Surface Electromyography

Author(s): Santiago Velasco-Bosom, Nuzli Karam, Alejandro Carnicer-Lombarte, Johannes Gurke, Nerea Casado, Liliana C. Tomé, David Mecerreyes, George G. Malliaras
Published in: Advanced Healthcare Materials, Issue 10(17), 2021, Page(s) 2100374, ISSN 2192-2659
Publisher: World Scientific
DOI: 10.1002/adhm.202100374

Proton trap effect on catechol-pyridine redox polymer nanoparticles as organic electrodes for lithium batteries

Author(s): A. Gallastegi, D. Minudri, N. Casado, N. Goujon, F. Ruiperez, N. Patil, C. Detrembleur, R. Marcilla, D. Mecerreyes
Published in: Sustainable Energy & Fuels, Issue 4, 2020, Page(s) 3934-3972, ISSN 2398-4902
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0se00531b

Digital Light 3D Printing of PEDOT-Based Photopolymerizable Inks for Biosensing

Author(s): Naroa Lopez-Larrea; Miryam Criado-Gonzalez; Antonio Dominguez-Alfaro; Nuria Alegret; Isabel del Agua; Bastien Marchiori; David Mecerreyes
Published in: ACS Applied Polymer Materials, Issue 4(9), 2022, Page(s) 6749-6759, ISSN 2637-6105
Publisher: American Chemical Society
DOI: 10.1021/acsapm.2c01170

3D Printable and Biocompatible Iongels for Body Sensor Applications.

Author(s): Gisela C. Luque, Matías L. Picchio, Ana P. S. Martins, Antonio Dominguez-Alfaro, Nicolás Ramos, Isabel del Agua, Bastien Marchiori, David Mecerreyes, Roque J. Minari, Liliana C. Tomé
Published in: Advanced Electronic Materials, Issue 7(8), 2021, Page(s) 2100178, ISSN 2199-160X
Publisher: Wiley
DOI: 10.1002/aelm.202100178

Elastic and Thermoreversible Iongels by Supramolecular PVA/Phenol Interactions.

Author(s): Gisela C. Luque, Matías L. Picchio, Ana P. S. Martins, Antonio Dominguez‐Alfaro, Liliana C. Tomé, David Mecerreyes, Roque J. Minari
Published in: Macromolecular Bioscience, Issue 20(11), 2020, Page(s) 2000119, ISSN 1616-5187
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/mabi.202000119

Tailoring PEDOT properties for applications in bioelectronics.

Author(s): Mary J.Donahue, Ana Sanchez-Sanchez, Sahika Inal, Jing Qu, Roisin M.Owens, David Mecerreyes, George G. Malliaras, David C. Martin
Published in: Materials Science and Engineering: R, Issue 10, 2020, Page(s) 100546, ISSN 0927-796X
Publisher: Elsevier BV
DOI: 10.1016/j.mser.2020.100546

Cation Effect in the Corrosion Inhibition Properties of Coumarate Ionic Liquids and Acrylic UV-Coatings

Author(s): Esther Udabe, Anthony Sommers, Maria Forsyth, David Mecerreyes
Published in: Polymers, Issue 12/11, 2020, Page(s) 2611, ISSN 2073-4360
Publisher: MDPI
DOI: 10.3390/polym12112611

Natural Deep Eutectic Solvents Based on Choline Chloride and Phenolic Compounds as Efficient Bioadhesives and Corrosion Protectors

Author(s): Matías L. Picchio, Daniela Minudri, Daniele Mantione, Miryam Criado-Gonzalez, Gregorio Guzmán-González, Ruth Schmarsow, Alejandro J. Müller, Liliana C. Tomé, Roque J. Minari, and David Mecerreyes
Published in: ACS Sustainable Chemistry Engineering, Issue 10(25), 2022, Page(s) 8135-8142, ISSN 2168-0485
Publisher: American Chemical Society
DOI: 10.1021/acssuschemeng.2c01976

Additive Manufacturing of Conducting Polymers: Recent Advances, Challenges, and Opportunities

Author(s): Miryam Criado-Gonzalez; Miryam Criado-Gonzalez; Antonio Dominguez-Alfaro; Naroa Lopez-Larrea; Nuria Alegret; David Mecerreyes; David Mecerreyes
Published in: ACS Applied Polymer Materials, Issue 3(6), 2021, Page(s) 2865-2883, ISSN 2637-6105
Publisher: American Chemical Society
DOI: 10.1021/acsapm.1c00252

Polyphenol Iongel Patches with Antimicrobial, Antioxidant and Anti-Inflammatory Properties

Author(s): Gisela C. Luque; Melissa Moya; Matias L. Picchio; Vanessa Bagnarello; Idalia Valerio; José Bolaños; María Vethencourt; Sue-Hellen Gamboa; Liliana C. Tomé; Roque J. Minari; David Mecerreyes
Published in: Polymers, Issue 15(5), 2023, Page(s) 1076, ISSN 2073-4360
Publisher: MDPI
DOI: 10.3390/polym15051076

Hydrophobic Eutectogels as Electrodes for Underwater Electromyography Recording

Author(s): Jon López de Lacalle, Matias L. Picchio, Antonio Dominguez-Alfaro, Ruben Ruiz-Mateos Serrano, Bastien Marchiori, Isabel del Agua, Naroa Lopez-Larrea, Miryam Criado-Gonzalez, George G. Malliaras, and David Mecerreyes
Published in: ACS Materials Letters, Issue 5, 12,, 2023, Page(s) 3340–3346, ISSN 2639-4979
Publisher: American Chemical Society
DOI: 10.1021/acsmaterialslett.3c00938

3D Printable Conducting and Biocompatible PEDOT-graft-PLA Copolymers by Direct Ink Writing

Author(s): Antonio Dominguez‐Alfaro, Elena Gabirondo, Nuria Alegret, Claudia María De León‐Almazán, Robert Hernandez, Ainara Vallejo‐Illarramendi, Maurizio Prato, David Mecerreyes
Published in: Macromolecular Rapid Communications, Issue 42, 12, 2021, Page(s) 2100100, ISSN 1521-3927
Publisher: Wiley-VCH GmbH
DOI: 10.1002/marc.202100100

Reducing Passive Drug Diffusion from Electrophoretic Drug Delivery Devices through Co‐Ion Engineering

Author(s): Shao-Tuan Chen; Megan N. Renny; Liliana C. Tomé; Jorge L. Olmedo-Martínez; Esther Udabe; Elise P. W. Jenkins; David Mecerreyes; David Mecerreyes; George G. Malliaras; Robert R. McLeod; Christopher M. Proctor
Published in: Advanced Science, Issue 8(12), 2021, Page(s) 2003995, ISSN 2198-3844
Publisher: Wiley
DOI: 10.1002/advs.202003995

Catechol-Containing Acrylic Poly(ionic liquid) Hydrogels as Bioinspired Filters for Water Decontamination

Author(s): Antonela Gallastegui, Luca Porcarelli, Rodrigo E. Palacios, M. Lorena Gómez, David Mecerreyes
Published in: ACS Applied Polymer Materials, Issue 1/7, 2019, Page(s) 1887-1895, ISSN 2637-6105
Publisher: ACS Publications
DOI: 10.1021/acsapm.9b00443

Tuning Electronic and Ionic Conductivities in Composite Materials for Electrochemical Devices

Author(s): Nerea Casado, Sara Zendegi, Rafael del Olmo, Antonio Dominguez-Alfaro, and Maria Forsyth
Published in: ACS Applied Polymer Materials, Issue 3, 4,, 2021, Page(s) 1777–1784, ISSN 2637-6105
Publisher: American Chemical Society
DOI: 10.1021/acsapm.0c01315

Mixed Conductive, Injectable, and Fluorescent Supramolecular Eutectogel Composites

Author(s): Miryam Criado‐Gonzalez; Nuria Alegret; Alejandro M. Fracaroli; Daniele Mantione; Gregorio Guzmán‐González; Rafael Del Olmo; Kentaro Tashiro; Liliana C. Tomé; Matias L. Picchio; David Mecerreyes
Published in: Angewandte Chemie, Issue 62 (26), 2023, Page(s) e202301489, ISSN 1521-3773
Publisher: Wiley
DOI: 10.1002/anie.202301489

Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols

Author(s): Jon López de Lacalle, Antonela Gallastegui, Jorge L. Olmedo-Martínez, Melissa Moya, Naroa Lopez-Larrea, Matías L. Picchio, and David Mecerreyes
Published in: ACS Macro Letters, Issue 12 (2), 2023, Page(s) 125-132, ISSN 2161-1653
Publisher: American Chemical Society
DOI: 10.1021/acsmacrolett.2c00657

Injectable PEDOT:PSS/cholinium ionic liquid mixed conducting materials for electrocardiogram recordings

Author(s): Nerea Casado, Sara Zendegi, Liliana C. Tomé, Santiago Velasco-Bosom, Ana Aguzin, Matias Picchio, Miryam Criado-Gonzalez, George G. Malliaras, Maria Forsyth and David Mecerreyes
Published in: Journal of Materials Chemistry C, Issue 10, 2022, Page(s) 15186-15193, ISSN 2050-7534
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2tc03248a

Ionic Hydrogel for Accelerated Dopamine Delivery via Retrodialysis

Author(s): Christopher M. Proctor, Chung Yuen Chan, Luca Porcarelli, Esther Udabe, Ana Sanchez-Sanchez, Isabel del Agua, David Mecerreyes, George G. Malliaras
Published in: Chemistry of Materials, Issue 31/17, 2018, Page(s) 7080-7084, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.9b02135

Decoupled ion mobility in nano-confined ionic plastic crystal

Author(s): Haijin Zhu, Aleksandra Grzelak, Ruhamah Yunis, Jaime Martín, Maria Forsyth
Published in: Materials Advances, Issue 1/9, 2020, Page(s) 3398-3405, ISSN 2633-5409
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0ma00778a

Gelatin and tannic acid based iongels for muscle activity recording and stimulation electrodes

Author(s): Ana Aguzin, Gisela C. Luque, Ludmila I. Ronco, Isabel del Agua, Gregorio Guzmán-González, Bastien Marchiori, Agustina Gugliotta, Liliana C. Tomé, Luis M. Gugliotta, David Mecerreyes and Roque J. Minari
Published in: ACS Biomaterials Science & Engineering, Issue 8, 6, 2022, Page(s) 2598–2609, ISSN 2373-9878
Publisher: American Chemical Society
DOI: 10.1021/acsbiomaterials.2c00317

Flame Retardant Polyphosphoester Copolymers as Solid Polymer Electrolyte for Lithium Batteries

Author(s): Jorge L. Olmedo-Martínez, Leire Meabe, Raphaël Riva, Gregorio Guzmán-González, Luca Porcarelli, Maria Forsyth, Agurtzane Mugica, Itxaso Calafel, Alejando J. Müller, Philippe Lecomte, Christine Jérôme, David Mecerreyes
Published in: Polymer Chemistry, Issue 12, 2021, Page(s) 3441-3450, ISSN 1759-9962
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1py00344e

Mixed Ionic and Electronic Conducting Eutectogels for 3D-Printable Wearable Sensors and Bioelectrodes

Author(s): Matías L. Picchio, Antonela Gallastegui, Nerea Casado, Naroa Lopez-Larrea, Bastien Marchiori, Isabel del Agua, Miryam Criado-Gonzalez, Daniele Mantione, Roque J. Minari, David Mecerreyes
Published in: Advanced Materials Technologies, Issue 7(10), 2022, Page(s) 2101680, ISSN 2365-709X
Publisher: Wiley
DOI: 10.1002/admt.202101680

Metal-free coumarate based ionic liquids and poly(ionic liquid)s as corrosion inhibitors

Author(s): Esther Udabe, Maria Forsyth, Anthony Somers, David Mecerreyes
Published in: Materials Advances, Issue 1/4, 2020, Page(s) 584-589, ISSN 2633-5409
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0ma00243g

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