European Magnesium Interactive Battery Community

Project Information

E-MAGIC

Grant agreement ID: 824066

DOI 10.3030/824066

Project closed

EC signature date 23 October 2018

Start date 1 January 2019

End date 30 June 2023

Funded under

• EXCELLENT SCIENCE - Future and Emerging Technologies (FET)

Total cost € 6 731 937,50

EU contribution € 6 731 937,50

Coordinated by

FUNDACION CIDETEC
Spain

Deliverables

Documents, reports (15)

LCA of Mg-based batteries - Literature review
Comprehensive report on the development of composite ceramic-polymer solid-state Mg- electrolytes for Mg-batteries

Report on the Mg ion cathode modelling. Proposal of new materials

Report on the Mg ion cathode modelling Proposal of new materials

Organic insertion materials. A comprehensive report

Organic insertion materials A comprehensive report

Review of relevant forms of Mg foils for batteries, incl. Mg-alloys foils
Anode modelling: Proposal of alloyed Mg anodes
Report on conversion cathode modelling. Proposal of new materials

Report on conversion cathode modelling Proposal of new materials

Role of the positive electrode-electrolyte interface in Mg-S batteries

Role of the positive electrodeelectrolyte interface in MgS batteries

Electrolyte modelling: Proposal of new electrolyte solutions

Electrolyte modelling Proposal of new electrolyte solutions

Report on basic electrolyte based on glymes, MgCl2, MgTFSI2
Inorganic insertion materials. A comprehensive report

Inorganic insertion materials A comprehensive report

High capacity conversion materials. A comprehensive report

High capacity conversion materials A comprehensive report

Alternative electrolytes with wide potential windows
Report on transport models for promising novel electrolytes
Optimizing selected Mg-alloys with suitable electrolyte solutions

Optimizing selected Mgalloys with suitable electrolyte solutions

Open Research Data Pilot (2)

Final Data Management Plan
Preliminary Data Management Plan

Websites, patent fillings, videos etc. (3)

Final report on International Workshops
First report on International Workshops
Project Website

Publications

Peer reviewed articles (36)

Development of Magnesium Borate Electrolytes: Explaining the Success of Mg[B(hfip)4]2 Salt

Author(s): Piotr Jankowski, Zhenyou Li, Zhirong Zhao-Karger, Thomas Diemant, Maximilian Fichtner, Tejs Vegge, Juan Maria Garcia Lastra
Published in: Energy Storage Materials, 2021, ISSN 2405-8297
Publisher: Elsevier
DOI: 10.1016/j.ensm.2021.11.012

Thermodynamic investigation of phase transformation in Sn anode for magnesium batteries

Author(s): Smobin Vincent, David Kleiven, Juan Maria Garcia Lastra, and Jin Hyun Chang
Published in: APL Materials, 2022, ISSN 2166-532X
Publisher: American Institute of Physics
DOI: 10.1063/5.0087046

Operando UV/vis Spectroscopy Providing Insights into the Sulfur and Polysulfide Dissolution in Magnesium–Sulfur Batteries

Author(s): Joachim Häcker, Duc Hien Nguyen, Tobias Rommel, Zhirong Zhao-Karger, Norbert Wagner, and K. Andreas Friedrich
Published in: ACS Energy Letters, 2022, ISSN 2380-8195
Publisher: American Chemical Society
DOI: 10.1021/acsenergylett.1c02152

Modeling of Electron‐Transfer Kinetics in Magnesium Electrolytes: Influence of the Solvent on the Battery Performance

Author(s): Janina Drews, Piotr Jankowski, Joachim Häcker, Zhenyou Li, Timo Danner, Juan Maria García Lastra, Tejs Vegge, Norbert Wagner, K. Andreas Friedrich, Zhirong Zhao-Karger, Maximilian Fichtner, Arnulf Latz
Published in: ChemSusChem, 2021, ISSN 1864-5631
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.202101498

Rationally Designed Vanadium Pentoxide as High Capacity Insertion Material for Mg‐Ion

Author(s): Ayan Mukherjee, Sarah Taragin, Hagit Aviv, Ilana Perelshtein, Malachi Noked
Published in: Advanced Functional Materials, 2020, Page(s) 2003518, ISSN 1616-301X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/adfm.202003518

Establishing a Stable Anode–Electrolyte Interface in Mg Batteries by Electrolyte Additive

Author(s): Zhenyou Li, Thomas Diemant, Zhen Meng, Yanlei Xiu, Adam Reupert, Liping Wang, Maximilian Fichtner, Zhirong Zhao-Karger
Published in: ACS Applied Materials & Interfaces, Issue 13/28, 2021, Page(s) 33123-33132, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.1c08476

Changes in the interfacial charge-transfer resistance of Mg metal electrodes, measured by dynamic electrochemical impedance spectroscopy

Author(s): Ran Attias, Ben Dlugatch, Munseok S. Chae, Yosef Goffer, Doron Aurbach
Published in: Electrochemistry Communications, Issue 124, 2021, Page(s) 106952, ISSN 1388-2481
Publisher: Elsevier BV
DOI: 10.1016/j.elecom.2021.106952

Particle atomic layer deposition as an effective way to enhance Li-S battery energy density

Author(s): E. Azaceta, S. García, O. Leonet, M. Beltrán, I. Gómez, A. Chuvilin A.R. Mainar, J.A. Blazquez, M.Knez
Published in: Materials Today Energy, 2020, ISSN 2468-6069
Publisher: Elsevier
DOI: 10.1016/j.mtener.2020.100567

Continuum Modelling As Tool for Optimizing the Cell Design of Magnesium Batteries

Author(s): Drews, Janina; Maça, Rudi Ruben; Wang, Liping; Wiedemann, Johannes; Blázquez, J. Alberto; Zhao-Karger, Zhirong; Fichtner, Maximilian; Danner, Timo; Latz, Arnulf
Published in: ECS Meeting Abstracts, 2022, ISSN 2151-2043
Publisher: Electrochemical society
DOI: 10.1149/ma2022-024461mtgabs

Stability of Current Collectors Against Corrosion in APC Electrolyte for Rechargeable Mg Battery

Author(s): Sankalpita Chakrabarty, J. Alberto Blázquez, Tali Sharabani, Ananya Maddegalla, Olatz Leonet, Idoia Urdampilleta, Daniel Sharon, Malachi Noked, Ayan Mukherjee
Published in: Journal of The Electrochemical Society, Issue 168/8, 2021, Page(s) 080526, ISSN 0013-4651
Publisher: Electrochemical Society, Inc.
DOI: 10.1149/1945-7111/ac1cc8

Computational Design of Ductile Magnesium Alloy Anodes for Magnesium Batteries

Author(s): Smobin Vincent, Jin Hyun Chang, Juan Maria Garcia Lastra
Published in: Batteries & Supercaps, Issue 4/3, 2021, Page(s) 522-528, ISSN 2566-6223
Publisher: Wiley
DOI: 10.1002/batt.202000240

Insights into the Degradation Mechanism of the Magnesium Anode in Magnesium–Chalcogen Batteries: Revealing Principles for Anode Design with a 3D-Structured Magnesium Anode

Author(s): Liping Wang; Thomas Diemant; Zhenyou Li; Bosubabu Dasari; Zhirong Zhao-Karger
Published in: ACS Applied Energy Materials, Issue 1, 2023, ISSN 2574-0962
Publisher: American Chemical Society
DOI: 10.1021/acsaem.2c03516

Cathode Materials and Chemistries for Magnesium Batteries: Challenges and Opportunities

Author(s): Zhenyou Li, Joachim Häcker, Maximilian Fichtner, Zhirong Zhao-Karger
Published in: Advanced Energy Materials, 2023, ISSN 1614-6840
Publisher: Wiley
DOI: 10.1002/aenm.202300682

Dual Role of Mo6S8in Polysulfide Conversion and Shuttlefor Mg–S Batteries

Author(s): Liping Wang, Piotr Jankowski, Christian Njel, Werner Bauer, Zhenyou Li, Zhen Meng,Bosubabu Dasari, Tejs Vegge, Juan Maria García Lastra, Zhirong Zhao-Karger,and Maximilian Fichtner
Published in: Advance Science, 2022, ISSN 2198-3844
Publisher: Wiley
DOI: 10.1002/advs.202104605

Investigationof the Anode-ElectrolyteInterfacein aMagnesiumFull-CellwithFluorinatedAlkoxyborate-BasedElectrolyte

Author(s): Ananyo Roy,Vinayan Bhagavathi Parambath, ThomasDiemant, GregorNeusser, ChristineKranz, R. Jürgen Behm, Zhenyou Li,Zhirong Zhao-Karger,[aximilian Fichtner
Published in: Batteries & Supercaps, 2021, ISSN 2566-6223
Publisher: Wiley
DOI: 10.1002/batt.202100305

MgSc2Se4 Solid Electrolyte for Rechargeable Mg Batteries: An Electric Field-Assisted All-Solid-State Synthesis

Author(s): Sumana Kundu, Nickolay Solomatin, Alexander Kraytsberg, Yair Ein-Eli
Published in: Energy Technology, 2022, ISSN 2194-4288
Publisher: Wiley
DOI: 10.1002/ente.202200896

Revealing and excluding the root cause of the electronic conductivity in Mg-ion MgSc2Se4 solid electrolyte

Author(s): Sumana Kundu, Nickolay Solomatin, Yaron Kauffmann, Alexander Kraytsberg, Yair Ein-Eli
Published in: Applied Materials Today, Issue 23, 2021, Page(s) 100998, ISSN 2352-9407
Publisher: Elsevier
DOI: 10.1016/j.apmt.2021.100998

A review on current anode materials for rechargeable Mg batteries

Author(s): Dajian Li; Yuan Yuan; Jiawei Liu; Maximilian Fichtner; Fusheng Pan
Published in: ISSN: 2213-9567, Issue 2, 2020, ISSN 2213-9567
Publisher: Journal of Magnesium and alloys
DOI: 10.5445/ir/1000126647

Modulation, Characterization, and Engineering of Advanced Materials for Electrochemical Energy Storage Applications: MoO 3 /V 2 O 5 Bilayer Model System

Author(s): Ran Attias, Michael Salama, Reeta Pant, Yossef Gofer, Doron Aurbach
Published in: The Journal of Physical Chemistry C, Issue 123/27, 2019, Page(s) 16577-16587, ISSN 1932-7447
Publisher: American Chemical Society
DOI: 10.1021/acs.jpcc.9b04371

Rechargeable Calcium–Sulfur Batteries Enabled by an Efficient Borate‐Based Electrolyte

Author(s): Zhenyou Li, Bhaghavathi Parambath Vinayan, Thomas Diemant, Rolf Jürgen Behm, Maximilian Fichtner, Zhirong Zhao‐Karger
Published in: Small, 2020, ISSN 1613-6810
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/smll.202001806

Autonomous Discovery of Materials for Intercalation Electrodes

Author(s): Felix T. Bölle, Nicolai R. Mathiesen, Alexander J. Nielsen, Tejs Vegge, Juan Maria Garcia‐Lastra, Ivano E. Castelli
Published in: Batteries & Supercaps, Issue 3/6, 2020, Page(s) 488-498, ISSN 2566-6223
Publisher: WILEY-VCH Verlag GmbH
DOI: 10.1002/batt.201900152

Towards stable and efficient electrolytes for room-temperature rechargeable calcium batteries

Author(s): Zhenyou Li, Olaf Fuhr, Maximilian Fichtner, Zhirong Zhao-Karger
Published in: Energy & Environmental Science, Issue 12/12, 2019, Page(s) 3496-3501, ISSN 1754-5692
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9ee01699f

Insights into the electrochemical processes of rechargeable magnesium–sulfur batteries with a new cathode design

Author(s): Bhaghavathi P. Vinayan, Holger Euchner, Zhirong Zhao-Karger, Musa Ali Cambaz, Zhenyou Li, Thomas Diemant, R. Jürgen Behm, Axel Gross, Maximilian Fichtner
Published in: Journal of Materials Chemistry A, Issue 7/44, 2019, Page(s) 25490-25502, ISSN 2050-7488
Publisher: Royal Society of Chemistry
DOI: 10.1039/c9ta09155f

Multi‐Electron Reactions Enabled by Anion‐Based Redox Chemistry for High‐Energy Multivalent Rechargeable Batteries

Author(s): Zhenyou Li, Bhaghavathi P. Vinayan, Piotr Jankowski, Christian Njel, Ananyo Roy, Tejs Vegge, Julia Maibach, Juan Maria García Lastra, Maximilian Fichtner, Zhirong Zhao‐Karger
Published in: Angewandte Chemie International Edition, Issue 59/28, 2020, Page(s) 11483-11490, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202002560

Mechanisms of Electronic and Ionic Transport during Mg Intercalation in Mg–S Cathode Materials and Their Decomposition Products

Author(s): Smobin Vincent, Jin Hyun Chang, Pieremanuele Canepa, and Juan Maria García-Lastra*
Published in: ACS Publications, 2023, ISSN 2639-4979
Publisher: American Chemistry Society
DOI: 10.1021/acs.chemmater.2c03784

AZ31 Magnesium Alloy foils as thin Anodes for Rechargeable Magnesium Batteries

Author(s): Ananya Maddegalla, Ayan Mukherjee, J. Alberto Blázquez, Eneko Azaceta, Olatz Leonet, Aroa R. Mainar, Aleksey Kovalevsky, Daniel Sharon, Jean-Frédéric Martin, Dane Sotta, Yair Ein-Eli, Doron Aurbach, Malachi Noked
Published in: ChemSusChem, 2021, ISSN 1864-5631
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.202101323

β-V₂O₅ as Magnesium Intercalation Cathode

Author(s): Rafael Trócoli; Prakash Parajuli; Carlos Frontera; Ashley P. Black; Grant C. B. Alexander; Indrani Roy; M. Elena Arroyo-de Dompablo; Robert F. Klie; Jordi Cabana; M. Rosa Palacín
Published in: instname:, Issue 1, 2022, ISSN 2574-0962
Publisher: ACS Publications
DOI: 10.1021/acsaem.2c02371

How solution chemistry affects the electrochemical behavior of cathodes for Mg batteries, a classical electroanalytical study

Author(s): Ran Attias, Shaul Bublil, Michael Salama, Yosef Goffer, Doron Aurbach
Published in: Electrochimica Acta, Issue 334, 2020, Page(s) 135614, ISSN 0013-4686
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.electacta.2020.135614

Evaluation of Mg[B(HFIP)4]2‑Based Electrolyte Solutions forRechargeable Mg Batteries

Author(s): Ben Dlugatch, Meera Mohankumar, Ran Attias, Balasubramoniam Murali Krishna, Yuval Elias, Yosef Gofer, David Zitoun, and Doron Aurbach*
Published in: Applied Materials & Interfaces, 2021, ISSN 1944-8252
Publisher: American Chemical Society
DOI: 10.1021/acsami.1c13419

Modeling of Ion Agglomeration in Magnesium Electrolytes and its Impacts on Battery Performance

Author(s): Janina Drews, Timo Danner, Piotr Jankowski, Tejs Vegge, Juan Maria García Lastra, Runyu Liu, Zhirong Zhao‐Karger, Maximilian Fichtner, Arnulf Latz
Published in: ChemSusChem, Issue 13/14, 2020, Page(s) 3599-3604, ISSN 1864-5631
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/cssc.202001034

Synthesis and Characterization of Magnesium Vanadates as potential Mg-ion Cathode Materials through an Ab Initio Guided Carbothermal Reduction Approach

Author(s): Lee, J., Dey, S., Dutton, S., & Grey, C.
Published in: Angewandte Chemie, 2021, ISSN 1521-3773
Publisher: Wiley
DOI: 10.1002/ange.202112688

Structure of Magnesium Chloride Complexes in Ethereal Systems: Computational Comparison of THF and Glymes as Solvents for Magnesium Battery Electrolytes

Author(s): Piotr Jankowski, Juan Maria García Lastra, Tejs Vegge
Published in: Batteries & Supercaps, 2020, ISSN 2566-6223
Publisher: WILEY-VCH Verlag GmbH
DOI: 10.1002/batt.202000168

Automatic Migration Path Exploration for Multivalent Battery Cathodes using Geometrical Descriptors

Author(s): Felix T. Bölle, Arghya Bhowmik, Tejs Vegge, Juan Maria García Lastra, Ivano E. Castelli
Published in: Batteries & Supercaps, 2021, ISSN 2566-6223
Publisher: Batteries and Supercaps
DOI: 10.1002/batt.202100086

Investigation on the formation of Mg metal anode/electrolyte interfaces in Mg/S batteries with electrolyte additives

Author(s): Vinayan Bhaghavathi Parambath, Zhirong Zhao-Karger, Thomas Diemant, Markus Jäckle, Zhenyou Li, Torsten Scherer, Axel Gross, R. Jürgen Behm, Maximilian Fichtner
Published in: Journal of Materials Chemistry A, Issue 8/43, 2020, Page(s) 22998-23010, ISSN 2050-7488
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0ta05762b

Combining Quinone‐Based Cathode with an Efficient Borate Electrolyte for High‐Performance Magnesium Batteries

Author(s): Yanlei Xiu, Zhenyou Li, Vinayan Bhaghavathi Parambath, Ziming Ding, Liping Wang, Adam Reupert, Maximilian Fichtner, Zhirong Zhao‐Karger
Published in: Batteries & Supercaps, 2021, ISSN 2566-6223
Publisher: Wiley
DOI: 10.1002/batt.202100163

The Role of Surface Adsorbed Cl – Complexes in Rechargeable Magnesium Batteries

Author(s): Ran Attias, Munseok S. Chae, Ben Dlugatch, Matan Oliel, Yosef Goffer, Doron Aurbach
Published in: ACS Catalysis, Issue 10/14, 2020, Page(s) 7773-7784, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.0c01956