Versatile Ionomers for DIvalent CAlcium baTteries

Resultado final

Report regarding the capability of using the developed ionomers as binders in composite electrodes

Organization of an International Conference

Third report regarding advanced data analysis to elucidate the structure and interactions of the functional components

Second report regarding the electrical response of functional components. Correlation with thermoanalytical and structural investigations will be included.

Website

Design of a website that includes progresses results and ambitions to popularize VIDICAT towards a large audience

Final report on Ca metal electrode studies

Final report about results obtained from the electrochemical evaluation of Ca metal and the study of the CaCaNIONO and CaCaNIONONCC interfaces

Performances of SFPE-based on B1 & B2 and CaI2 selection of B1 or B2.

Report about the performance of Solvent-free Polymer Electrolytes based on two different backbones. The best will be provided to the partners involved in WP4.

Results of structural studies II

Second report regarding structural studies performed on functional components

Report on the results of thermoanalytical studies III

Third report regarding thermoanalytical studies of functional materials in the nano and mesoscale domain

Results of advanced data analysis II

Second report regarding advanced data analysis to elucidate the structure and interactions of the functional components.

Report on the results of thermoanalytical studies II

Second report regarding thermoanalytical studies of functional materials in the nano and mesoscale domain.

Results of morphological studies II

Second report regarding the study of morphology and surface of functional components

Determination of conduction mechanism III

Third report regarding numerical modelling performed to study the thermodynamic and kinetic properties and their influence on Ca2 transport

Results of morphological studies III

Third report regarding the study of morphology and surface of functional components

Determination of conduction mechanism II

Second report regarding numerical modelling performed to study the thermodynamic and kinetic properties and their influence on Ca2+ transport.

Results of electrical studies III

Third report regarding the electrical response of functional components Correlation with thermoanalytical and structural investigations will be included

First report on synthesis and characterization of novel cathodes

Report on first results regarding the synthesis and characterization of novel materials used as cathodes.

Results of structural studies III

Third report regarding structural studies performed on functional components

Selection of the best Ca-IONO/NCC and Ca-NIONO/NCC

Report regarding the effect of NCC on mechanical properties of the CaNIONO towards decreasing film thickness

Final report on Ca metal battery, including best cathodes

Final report on Ca metal battery including the best cathode materials with CaNIONONCC as binder and Ca metal

Thin-films: Gs+ to reach or exceed 60 mS/cm2 at r.t.

Report regarding success on increasing Gs up to 60 mScm at room temperature without sacrificing safety in the battery for CaNIONONCC

Report on model compounds for electrolyte testing

Report about the synthesis and characterization of model compounds to provide a Ca2+ host for electrolyte testing.

Upscaling of Ca-IONO at the 1 kg level

Production of up to 1 kg of the chosen Ca-NIONO by upscaling the synthesis process.

Data Management Plan

Description of the data management life cycle for the data to be collected, processed and/or generated by project.

Publicaciones

Water-in-eutectogel” electrolytes for quasi-solid-state aqueous Lithium-ion batteries

Autores: Xu Hou, Travis P Pollard, Xin He, Leilei Du, Xiaokang Ju, Wenguang Zhao, Meirong Li, Jun Wang, Elie Paillard, Hai Lin, Jingyu Sun, Kang Xu, Oleg Borodin, Martin Winter, Jie Li
Publicado en: Advanced Energy Materials, Edición 12, 2022, ISSN 1614-6832
Editor: Wiley-VCH Verlag
DOI: 10.1002/aenm.202200401

Effective Solid Electrolyte Interphase Formation on Lithium Metal Anodes by Mechanochemical Modification.

Autores: Julia Wellmann, Jan-Paul Brinkmann, Björn Wankmiller, Kerstin Neuhaus, Uta Rodehorst, Michael R. Hansen, Martin Winter, and Elie Paillard
Publicado en: ACS Appl. Mater. Interfaces, Edición 13/29, 2021, Página(s) 34227–34237, ISSN 1944-8244
Editor: American Chemical Society
DOI: 10.1021/acsami.1c07490

Cathode–Electrolyte Interphase in a LiTFSI/Tetraglyme Electrolyte Promoting the Cyclability of V2O5

Autores: Xu Liu, Maider Zarrabeitia, Bingsheng Qin, Giuseppe Antonio Elia, and Stefano Passerini
Publicado en: ACS Appl. Mater. Interfaces, Edición 12/49, 2020, Página(s) 54782–54790, ISSN 1944-8244
Editor: American Chemical Society
DOI: 10.1021/acsami.0c16727

Investigation of alkali and alkaline earth solvation structures in tetraglyme solvent

Autores: L. H. B. Nguyen, T. Picard, N. Sergent, C. Raynaud, J.-S. Filhol and M.-L. Doublet
Publicado en: Phys. Chem. Chem. Phys., Edición 14639076, 2021, ISSN 1463-9076
Editor: Royal Society of Chemistry
DOI: 10.1039/d1cp02939h

Simultaneous Formation of Interphases on both Positive and Negative Electrodes in High-Voltage Aqueous Lithium-Ion Batteries

Autores: Xu Hou, Travis P. Pollard, Wenguang Zhao, Xin He, Xiaokang Ju, Jun Wang, Leilei Du, Elie Paillard, Hai Lin, Kang Xu, Oleg Borodin, Martin Winter, Jie Li
Publicado en: Small, Edición 18/5, 2022, ISSN 1613-6829
Editor: Wiley
DOI: 10.1002/smll.202104986

Interplay between Conductivity, Matrix Relaxations and Composition of Ca‐Polyoxyethylene Polymer Electrolytes

Autores: Gioele Pagot, Keti Vezzù, Cynthia Susana Martinez‐Cisneros, Claire Antonelli, Belen Levenfeld, Alejandro Varez, Jean‐Yves Sanchez, Vito Di Noto
Publicado en: ChemElectroChem, Edición 8/13, 2021, Página(s) 2459-2466, ISSN 2196-0216
Editor: Wiley
DOI: 10.1002/celc.202100475

Failure mechanism of LiNi0.6Co0.2Mn0.2O2 cathodes in aqueous/non-aqueous hybrid electrolyte

Autores: Leilei Du, Xu Hou, Debbie Berghus, Lars Frankenstein, Richard Schmuch, Jun Wang, Elie Paillard, Martin Winter, Tobias Placke Jie Li
Publicado en: Journal of Materials Chemistry A, Edición 7, 2023, ISSN 2050-7496
Editor: Royal Society of Electrochemistry
DOI: 10.1039/d2ta08650f

First-principles theory of electrochemical capacitance

Autores: Tobias Binninger
Publicado en: Electrochimica Acta, Edición 444, 2023, ISSN 0013-4686
Editor: Pergamon Press Ltd.
DOI: 10.48550/arxiv.2302.04848

Nanostructured block copolymer single-ion conductors for low-temperature, high-voltage and fast charging lithium-metal batteries

Autores: Junli Shi, Huu-Dat Nguyen, Zhen Chen, Rui Wang, Dominik Steinle, Lester Barnsley, Jie Li, Henrich Frielinghaus, Dominic Bresser, Cristina Iojoiu, Elie Paillard
Publicado en: Energy Mater, Edición 3, 2023, ISSN 2770-5900
Editor: OAE Publishing Inc.
DOI: 10.20517/energymater.2023.27

Understanding of crucial factors for improving the energy density of lithium-sulfur pouch cells

Autores: Olatz Leonet, Álvaro Doñoro, Ana Fernández-Barquín, Andriy Kvasha, Idoia Urdampilleta, J. Alberto Blázquez
Publicado en: Front. Chem., Edición 10, 2022, Página(s) 1-10, ISSN 1662-5153
Editor: Frontiers Research Foundation
DOI: 10.3389/fchem.2022.888750

Investigating the abnormal conductivity behaviour of divalent cations in low dielectric constant tetraglyme-based electrolytes.

Autores: Long Hoang Bao Nguyen, Tanguy Picard, Cristina Iojoiu, Fannie Alloin, Nicolas Sergent, Marie-Liesse Doublet and Jean-Sebastien Filhol
Publicado en: Phys. Chem. Chem. Phys., Edición 14639076, 2022, ISSN 1463-9076
Editor: Royal Society of Chemistry
DOI: 10.1039/d2cp03200g

Evaluation of counter and reference electrodes for the investigation of Ca battery materials

Autores: Xu Liu, Giuseppe Antonio Elia, Stefano Passerini
Publicado en: Journal of Power Sources Advances, Edición 2, 2020, Página(s) 100008, ISSN 2666-2485
Editor: ELSEVIER SCIENCE BV
DOI: 10.1016/j.powera.2020.100008

Opening the door to liquid-free polymer electrolytes for calcium batteries

Autores: C.S. Martinez-Cisneros, A. Fernandez, C. Antonelli, B. Levenfeld, A. Varez, K. Vezzù, V. Di Noto, J-Y. Sanchez
Publicado en: Electrochimica Acta, 2020, ISSN 0013-4686
Editor: Pergamon Press Ltd.

Operando pH Measurements Decipher H+ /Zn2+ Intercalation Chemistry in High-Performance Aqueous Zn/δ-V2O5 Batteries

Autores: Xu Liu, Holger Euchner, Maider Zarrabeitia, Xinpei Gao, Giuseppe Antonio Elia, Axel Groß, and Stefano Passerini
Publicado en: ACS Energy Lett., Edición 5/9, 2020, Página(s) 2979–2986, ISSN 2380-8195
Editor: American Chemical Society
DOI: 10.1021/acsenergylett.0c01767

Single-ion conducting interlayers for improved lithium metal plating

Autores: Jiajia Wan, Xu Liu, Thomas Diemant, Mintao Wan, Stefano Passerini, Elie Paillard
Publicado en: Energy Storage Materials, Edición 63, 2023, ISSN 2405-8289
Editor: Elsevier
DOI: 10.1016/j.ensm.2023.103029

Dendrite-Free Zinc Deposition Induced by Zinc-Phytate Coating for Long-Life Aqueous Zinc Batteries

Autores: Leilei Du, Dr. Xu Hou, Xiaofei Yang, Dr. Vassilios Siozios, Dr. Bo Yan, Dr. Xiaokang Ju, Prof. Elie Paillard, Prof. Martin Winter, Dr. Tobias Placke, Prof. Jie Li
Publicado en: Batteries and Supercaps, Edición 5, 2022, ISSN 2566-6223
Editor: Wiley
DOI: 10.1002/batt.202100376

Alkoxy-functionalized ionic liquid electrolytes: understanding ionic coordination of calcium ion speciation for the rational design of calcium electrolytes

Autores: Xinpei Gao, Xu Liu, Alessandro Mariani, Giuseppe Antonio Elia, Manuel Lechner, Carsten Streb, Stefano Passerini
Publicado en: Energy & Environmental Science, Edición 13/8, 2020, Página(s) 2559-2569, ISSN 1754-5692
Editor: Royal Society of Chemistry
DOI: 10.1039/d0ee00831a

AMOEBA Polarizable Force Field for Molecular Dynamics Simulations of Glyme Solvents

Autores: Tobias Binninger, Defne Saraç, Liam Marsh, Tanguy Picard, Marie-Liesse Doublet, and Christophe Raynaud
Publicado en: J. Chem. Theory Comput., Edición 19, 2023, ISSN 1549-9618
Editor: American Chemical Society
DOI: 10.1021/acs.jctc.2c00926

Resultado final

Publicaciones

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