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In Situ Probing of transition metal-oxide heteroInterfaces for high-peRformance solid-state Energy devices

Project description

New spectroscopy methods could lead to the design of better fuel cell interfaces

Solid oxide fuel cells have garnered significant attention for their ability to offer a clean and sustainable way of generating electricity. Compared with single-phase interfaces, transition metal oxide heterointerfaces exhibit orders of magnitude faster ion exchange/diffusion kinetics in solid oxide cells. However, due to the limited resolution of spectroscopy instruments compared to the nanometre length scales of heterointerfaces, the underlying electrokinetic mechanisms remain poorly understood. To address this issue, the INSPIRE project, funded under the Marie Skłodowska-Curie Actions programme, will conduct an in-situ study of a range of heterointerfaces using low-energy ion scattering spectroscopy and high-resolution plasma-focused ion beam secondary ion mass spectroscopy. The project will also design strain-engineered vertically aligned composite nanostructures of transition metal oxide heterostructures using pulsed laser deposition.

Objective

Improving energy efficiency, reducing emissions and increasing the share of renewables are among the primary targets of the EU. To achieve these goals, solid-state energy devices, including solid oxide cells (SOCs), have gathered significant attention. In recent years, advances in material design have opened up unprecedented opportunities for development. For example, compared with either single phase, heterointerfaces of transition metal oxides (TMOs) exhibit orders of magnitude faster ion exchange/diffusion kinetics in SOCs. However, there is continuous debate regarding the origin of these enhancements, mainly due to limited instrumental resolutions compared to the nanometre length scale of heterointerfaces. The underlying electrokinetic mechanisms must be understood and quantitatively determined so that we can rationally design interfaces with superior properties. This will open up new avenues in the low-temperature SOC (LT-SOC) applications. To this end, we propose an in-situ study of a range of heterointerfaces using both Low Energy Ion Scattering Spectroscopy and recently installed, one-of-a-kind and high-resolution Plasma Focused Ion Beam Secondary Ion Mass Spectroscopy. We will design strain-engineered vertically aligned composite nanostructures (VAN) of TMO heterostructures using Pulsed Laser Deposition. VAN design allows for strain tuning in electrodes with thicknesses reaching micrometre length scales, thus paving the way for potential commercialisation. The performance of these heterostructures will be investigated for LT-SOC applications, targeting higher outputs at lower operating temperatures (300-500°C). This project combines the candidate’s expertise in SOCs with the host institute’s unique surface characterisation capabilities. This work is expected to form a cornerstone in the researcher's academic career while significantly contributing to boosting European excellence by studying a highly topical research question.

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Topic(s)

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Funding Scheme

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MSCA-IF-EF-ST - Standard EF

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Call for proposal

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(opens in new window) H2020-MSCA-IF-2018

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Coordinator

IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 212 933,76
Address
SOUTH KENSINGTON CAMPUS EXHIBITION ROAD
SW7 2AZ LONDON
United Kingdom

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Region
London Inner London — West Westminster
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 212 933,76
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