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Potential-dependent Second-Harmonic Generation in Optical Antennas measured Time-resolved

Project description

Enhancing second-harmonic generation in nanoantennas

Second-harmonic generation is a nonlinear optical process with promising applications in spectroscopy, ultrafast optical switching and optical information processing. Antennas formed by metallic nanostructures enable second-harmonic generation at the nanometre scale, but with low efficiency. Funded by the Marie Skłodowska-Curie Actions programme, the PoSHGOAT project aims to optimise second-harmonic generation in these optical antennas. The project will fabricate electrically contacted nanoantennas with ultra-fine tips and ultra-narrow gaps and will apply an external potential to modulate surface charges in metallic nanoparticles. Furthermore, it will apply time-resolved pump-probe spectroscopy and develop numerical models to optimise nanoparticle geometries, therefore maximising second-harmonic generation.

Objective

Second-harmonic generation (SHG) is a nonlinear optical effect, with promising applications in background-free spectroscopy, ultrafast optical switching, and optical information processing. What is missing is the integration of these effects at the nanoscale, to be sensitive down to the singe molecule level and competitive in size with silicon electronics.

Metallic nanoparticles, called optical antennas (OAs), show resonances in the infrared and optical wavelength regime. They exhibit plasmons, coupled states of photons and electron density waves, which allow concentrating light much better than conventional optics, down to 10 nm³. OAs enable SHG in nanometer-sized volumes, but until now only with low efficiency. This is due to the complex task of: (i) a resonance to receive light with wavelength A, (ii) routing the energy to the OA surface (efficient SHG due to symmetry breaking), (iii) exploiting a second antenna resonance which can gather the SHG at wavelength B=A/2, and finally (iv) emitting the wavelength B to the far field.

In the proposed project PoSHGOAT I will control and optimize SHG in OAs. To this aim, I will introduce four novelties to SHG research:

(1) Fabrication of electrically-contacted nanoantennas with ultra-fine tips (r = 3 nm) and ultra-narrow gaps (g = 3 nm) by a subsequent Ga-ion and He-ion milling procedure.
(2) Modulation of the surface charges in metallic nanoparticles by applying an external potential.
(3) Time-resolved pump-probe spectroscopy of SHG with an applied voltage, eventually even with induced tunnelling of electrons in a highly asymmetric antenna gap. This will establish ultrafast control over the OA surface charge density and, thus, SHG.
(4) Numerical modelling of SHG and evolutionary optimization of nanoparticle geometries to maximize SHG in optical antennas.

All these efforts together will increase our understanding of nonlinear processes in plasmonic resonators, towards novel design rules for nonlinear plasmonic devices.

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MSCA-IF-EF-ST - Standard EF

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Call for proposal

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(opens in new window) H2020-MSCA-IF-2018

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Coordinator

POLITECNICO DI MILANO
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 137 604,96
Address
PIAZZA LEONARDO DA VINCI 32
20133 Milano
Italy

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Region
Nord-Ovest Lombardia Milano
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 137 604,96
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