Project description
A novel approach to the nitrogen fixation process
The Haber–Bosch artificial nitrogen fixation process is used to produce fertiliser at an immense scale, paving the way for industrial agriculture. As an energy-intensive chemical process, however, it emits millions of tonnes of CO2. Alternatives for delocalised fertiliser production have been sought, such as electrically powered plasma processes, but they fail to exceed Haber-Bosch efficiencies. The EU-funded PENFIX project will investigate a possible solution – the integration of pulsed power atmospheric microwave plasma for nitric oxide production using air. The project will focus on novel reactor designs and diagnostic and modelling activities.
Objective
Industrial scale nitrogen fixation (NF) via the Haber-Bosch process dominates artificial fertilizer production and at present, enables yield enhancements which nourish over 40 % of the world population. Owing to the exceptional stability of molecular nitrogen’s triple bond the Haber-Bosch process is an energy intensive chemical process which accounts for 1-2 % of the world's energy production, consumes 2-3 % of the global natural gas output and emits more than 300 million tonnes of CO2. In light of an increasing population (and fertilizer demand) coupled with an urgency to reduce CO2 emissions, efforts to find alternative technologies for NF that offer the potential of reduced energy usage while minimizing greenhouse gas emissions have accelerated. Electrically powered plasma processes are considered as a promising alternative for delocalized fertilizer production, based on renewable energy, and more specifically for NO production. To-date, however, plasma designs for NF have not exceeded Haber-Bosch efficiencies. Pulsed powered microwave (MW) generated plasma technology offers some promise in this regard. Pulsing of the discharge power enables strategies which direct energy to primarily heat electrons (’non-thermal’ conditions) providing a far more efficient pathway to molecular bond breakage (and resulting NO production) than thermal effects. Indeed, reports on pulsed powered MW discharges have indicated an opportunity to tune electron energies to maximize molecular vibrational excitation, identified as an optimal route for energy efficiency in NO production. In a novel advance, plasma efficient nitrogen fixation ’PENFIX', proposes to interrogate ’pulsed’ powered atmospheric microwave (MW) plasma for nitric oxide (NO) production using air. Novel reactor designs informed by validated modelling will be of particular focus. Diagnostic and modelling activities will elucidate the fundamental physics while addressing the challenges of future industrial scale deployment.
                                Fields of science (EuroSciVoc)
                                                                                                            
                                            
                                            
                                                CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See:   The European Science Vocabulary.
                                                
                                            
                                        
                                                                                                
                            CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
- engineering and technology environmental engineering energy and fuels renewable energy
- natural sciences physical sciences plasma physics
- engineering and technology environmental engineering energy and fuels fossil energy natural gas
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                  H2020-EU.1.3. - EXCELLENT SCIENCE - Marie Skłodowska-Curie Actions
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                  H2020-EU.1.3.2. - Nurturing excellence by means of cross-border and cross-sector mobility
                                    
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                  Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
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MSCA-IF-EF-ST - Standard EF
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(opens in new window) H2020-MSCA-IF-2018
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Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.
2000 Antwerpen
Belgium
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