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Binuclear Iridium(III) Complexes for White-Emitting OLEDs

Project description

Developing energy-efficient lighting of the future

In the quest for more efficient lighting, the current best alternative to conventional light bulbs is the inorganic light-emitting diode (LED). White organic LEDs are being developed that use multiple luminescent substances called luminophores in a single device. This causes imbalanced white-light emission and colour instability. Efforts have been made to overcome these drawbacks but this involves complex synthetic procedures. The EU-funded Lefko-Phos project aims to introduce easy-to-synthesise compounds that display dual emission for white-light generation from a single molecular entity. Their strategy involves generating blue and orange emission at the same time. The project will open the way to more energy-efficient lighting in the future.

Objective

The European Union set the ambitious target of increasing energy efficiency by 27% within 2030. Since ≈ 20% of the EU electrical energy is used for lighting, more efficient lighting concepts need to be developed. At present, inorganic light emitting diodes (LEDs) stand out as the best alternative to conventional lighting devices. In future, organic LEDs (OLEDs) are predicted to become the ultimate solution, since they allow fabrication of large-area flat and flexible devices; consequently, white-emitting OLEDs (WOLEDs) are actively investigated. Current WOLEDs require the use of multiple luminophores in a single device, but this leads to imbalanced white-light emission and colour instability, due to the different stability over time of each single emitter. Moreover, the incorporation of multiple emitters increases manufacturing costs. To overcome these drawbacks, attempts have been made to generate white-emission from a single multifunctional material. However, strong limitations were faced due to the complex synthetic procedures and the inability to control the excited-state properties of the emitter and its internal energy-transfer processes. In this scenario, we propose a new strategy for easy-to-synthesize binuclear cyclometalated iridium(III) complexes, displaying dual-emission for white-light generation from a single molecular entity. The strategy involves simultaneous generation of blue and orange emission from two electronically uncoupled Ir(III) centres, linked together by a non-conjugated bridging unit. This ambitious goal can be achieved due to the mutual interaction between the Experienced Researcher (ER) and the Host Institution (HI). While the ER has a strong background in the synthesis of luminescent complexes, the HI has a consolidated expertise in organic synthesis, theoretical and experimental photophysics, and in fabrication and testing of OLED devices. This combination of competencies will guarantee the successful implementation of this project.

Fields of science (EuroSciVoc)

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Programme(s)

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Topic(s)

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Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

MSCA-IF-EF-ST - Standard EF

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) H2020-MSCA-IF-2018

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Coordinator

CONSIGLIO NAZIONALE DELLE RICERCHE
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 171 473,28
Address
PIAZZALE ALDO MORO 7
00185 Roma
Italy

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Region
Centro (IT) Lazio Roma
Activity type
Research Organisations
Links
Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 171 473,28
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