Bismuth Redox Catalysis for Sustainable Organic Synthesis

Project Information

Let-it-Bi

Grant agreement ID: 850496

DOI

10.3030/850496

Project closed

EC signature date 23 August 2019

Start date 1 February 2020

End date 31 July 2025

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 498 750,00

EU contribution

€ 1 498 750,00

Coordinated by

MAX PLANCK INSTITUT FUER KOHLENFORSCHUNG
Germany

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (34)

Synthesis, Isolation, and Characterization of Two Cationic Organobismuth(II) Pincer Complexes Relevant in Radical Redox Chemistry

Author(s): Xiuxiu Yang, Edward J. Reijerse, Nils Nöthling, Daniel J. SantaLucia, Markus Leutzsch, Alexander Schnegg, Josep Cornella
Published in: Journal of the American Chemical Society, Issue 145, 2023, Page(s) 5618-5623, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c12564

Isolation and Characterization of an Organobismuth Dihydride

Author(s): Satoshi Kurumada, Nils Nöthling, Yue Pang, Nijito Mukai, Markus Leutzsch, Richard Goddard, Josep Cornella
Published in: Journal of the American Chemical Society, Issue 147, 2025, Page(s) 29636-29641, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.5c09023

Bismuth in Radical Chemistry and Catalysis

Author(s): Mauro Mato, Josep Cornella
Published in: Angewandte Chemie, Issue 136, 2025, Page(s) 21, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/ange.202315046

Aryl Silicon Nucleophiles in Bismuth Catalysis

Author(s): Teresa Faber, Sophia Engelhardt, Josep Cornella
Published in: Angewandte Chemie International Edition, Issue 64, 2025, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202424698

Dihydrogen and Ethylene Activation by a Sterically Distorted Distibene

Author(s): Yue Pang, Markus Leutzsch, Nils Nöthling, Josep Cornella
Published in: Angewandte Chemie International Edition, Issue 62, 2023, Page(s) 62 (32), ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202302071

Activation and Catalytic Degradation of SF₆ and PhSF₅ at a Bismuth Center

Author(s): Vanessa A. Béland, Nils Nöthling, Markus Leutzsch, Josep Cornella
Published in: Journal of the American Chemical Society, Issue 146, 2024, Page(s) 25409-25415, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c07044

Activation and C−C Coupling of Aryl Iodides via Bismuth Photocatalysis

Author(s): Mauro Mato, Alexios Stamoulis, Paolo Cleto Bruzzese, Josep Cornella
Published in: Angewandte Chemie, Issue 137, 2025, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/ange.202418367

Synthesis and Characterization of Monomeric Triarylbismuthine Oxide

Author(s): Jennifer Kuziola, Hye Won Moon, Markus Leutzsch, Nils Nöthling, Vanessa A. Béland, Josep Cornella
Published in: Angewandte Chemie International Edition, Issue 64, 2025, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202415169

Bi-Catalyzed Trifluoromethylation of C(sp²)–H Bonds under Light

Author(s): Takuya Tsuruta, Davide Spinnato, Hye Won Moon, Markus Leutzsch, Josep Cornella
Published in: Journal of the American Chemical Society, Issue 145, 2023, Page(s) 25538-25544, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c10333

High-valent bismuth redox catalysis

Author(s): Planas, O., Cornella, J.
Published in: Nachrichten aus der Chemie, Issue 69 (10), 2021, Page(s) 79-83, ISSN 1439-9598
Publisher: Wiley - V C H Verlag GmbbH & Co.
DOI: 10.1002/nadc.20214116551

Synthesis and characterization of chlorotriarylbismuthonium salts

Author(s): Jennifer Kuziola, Nils Nöthling, Markus Leutzsch, Josep Cornella
Published in: Chemical Communications, Issue 60, 2024, Page(s) 10532-10535, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4cc03364g

Internal Atom Exchange in Oxazole Rings: A Blueprint for Azole Scaffold Evaluation

Author(s): Spinnato, D., Leutzsch, M., Wang, F., & Cornella, J.
Published in: Synlett, 2023, ISSN 0936-5214
Publisher: Georg Thieme Verlag
DOI: 10.1055/a-2201-9285

Catalytic Activation of N 2 O at a Low-Valent Bismuth Redox Platform

Author(s): Yue Pang, Markus Leutzsch, Nils Nöthling, Josep Cornella
Published in: Journal of the American Chemical Society, Issue 142/46, 2020, Page(s) 19473-19479, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c10092

Catalytic 1,2‐Migratory Insertion in a Bismuth Redox Platform: Reductive Arylation of Aldehydes

Author(s): Xiangrong Liu, Hye Won Moon, Davide Spinnato, Markus Leutzsch, Josep Cornella
Published in: Angewandte Chemie International Edition, 2025, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202510360

Synthesis and isolation of a triplet bismuthinidene with a quenched magnetic response

Author(s): Yue Pang, Nils Nöthling, Markus Leutzsch, Liqun Kang, Eckhard Bill, Maurice van Gastel, Edward Reijerse, Richard Goddard, Lucas Wagner, Daniel SantaLucia, Serena DeBeer, Frank Neese, Josep Cornella
Published in: Science, Issue 380, 2024, Page(s) 1043-1048, ISSN 0036-8075
Publisher: American Association for the Advancement of Science
DOI: 10.1126/science.adg2833

(Hetero)aryl‒S(VI) Fluorides: Synthetic Development and Opportunities

Author(s): Magre, M.; Ni, Shengyang, Cornella, J.
Published in: Angewandte Chemie International Edition, Issue 61 (23), 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202200904

Direct Determination of a Giant Zero-Field Splitting of 5422 cm^–1 in a Triplet Organobismuthinidene by Infrared Electron Paramagnetic Resonance

Author(s): Tarek Al Said, Davide Spinnato, Karsten Holldack, Frank Neese, Josep Cornella, Alexander Schnegg
Published in: Journal of the American Chemical Society, Issue 147, 2025, Page(s) 84-87, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c14795

Bismuth‐Catalyzed Amide Reduction

Author(s): Xiuxiu Yang, Jennifer Kuziola, Vanessa A. Béland, Julia Busch, Markus Leutzsch, Jordi Burés, Josep Cornella
Published in: Angewandte Chemie International Edition, Issue 62, 2023, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202306447

Synthesis and Structure of Mono-, Di-, and Trinuclear Fluorotriarylbismuthonium Cations

Author(s): Kuziola, J.; Magre, M.; Nöthling, N.; Cornella, J.
Published in: Organometallics, Issue 41 (14), 2022, Page(s) 1754 - 1762, ISSN 0276-7333
Publisher: American Chemical Society
DOI: 10.1021/acs.organomet.2c00135

Bismuth radical catalysis in the activation and coupling of redox-active electrophiles

Author(s): Mato. M.; Spinnato, D.; Leutzsch, M.; Moon, H.-W.; Reijerse, E.; Cornella, J.
Published in: Nature Chemistry, Issue 15 (8), 2023, Page(s) 1138 - 1145, ISSN 1755-4330
Publisher: Nature Publishing Group

Conjugate Aminocyclization Catalyzed by a Bismuthinidene

Author(s): Mauro Mato, Feng Wang, Josep Cornella
Published in: Advanced Synthesis & Catalysis, Issue 366, 2024, Page(s) 740-744, ISSN 1615-4150
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/adsc.202300857

Oxidative Addition of Aryl Electrophiles into a Red-Light-Active Bismuthinidene

Author(s): Mauro Mato, Paolo Cleto Bruzzese, Fumiya Takahashi, Markus Leutzsch, Edward J. Reijerse, Alexander Schnegg, Josep Cornella
Published in: Journal of the American Chemical Society, Issue 145, 2023, Page(s) 18742-18747, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c06651

Reductive Cyclopropanation through Bismuth Photocatalysis

Author(s): Shengyang Ni, Davide Spinnato, Josep Cornella
Published in: Journal of the American Chemical Society, Issue 146, 2024, Page(s) 22140-22144, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c07262

Radical Activation of Ammonia and Water at Bismuth(II)

Author(s): Yang, X.; Reijerse, E.; Bhattacharyya, K.; Leutzsch, M.; Kochius, M.; Nöthling, N.; Busch, J.; Schnegg, A.; Auer, A.; Cornella, J.
Published in: Journal of the American Chemical Society, Issue 144 (36), 2022, Page(s) 16535 - 16544, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c05882

Bismuth-Catalyzed Oxidative Coupling of Arylboronic Acids with Triflate and Nonaflate Salts

Author(s): Oriol Planas, Vytautas Peciukenas, Josep Cornella
Published in: Journal of the American Chemical Society, Issue 142/26, 2020, Page(s) 11382-11387, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.0c05343

Mechanism of the Aryl–F Bond-Forming Step from Bi(V) Fluorides

Author(s): Oriol Planas, Vytautas Peciukenas, Markus Leutzsch, Nils Nöthling, Dimitrios A. Pantazis, Josep Cornella
Published in: Journal of the American Chemical Society, Issue 144, 2023, Page(s) 14489-14504, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.2c01072

Characterization of Iminobismuthanes and Catalytic Reduction of Organic Azides via Bi(I)/Bi(III) Redox Cycling

Author(s): Hye Won Moon, Nils Nöthling, Markus Leutzsch, Jennifer Kuziola, Josep Cornella
Published in: Angewandte Chemie, Issue 137, 2025, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/ange.202417864

Catalytic Hydrodefluorination via Oxidative Addition, Ligand Metathesis, and Reductive Elimination at Bi(I)/Bi(III) Centers

Author(s): Yue Pang, Markus Leutzsch, Nils Nöthling, Felix Katzenburg, Josep Cornella
Published in: Journal of the American Chemical Society, 2021, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c06735

Bismuth Redox Catalysis: An Emerging Main-Group Platform for Organic Synthesis

Author(s): Moon, H. -W.; Cornella, J.
Published in: ACS Catalysis, Issue 12 (2), 2022, Page(s) 1382 - 1393, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.1c04897

Red-light Active N,C,N-Pincer Bismuthinidene: Excited State Dynamics and Mechanism of Oxidative Addition into Aryl Iodides

Author(s): Alexios Stamoulis, Mauro Mato, Paolo Cleto Bruzzese, Markus Leutzsch, Alejandro Cadranel, Marcos Gil-Sepulcre, Frank Neese, Josep Cornella
Published in: Journal of the American Chemical Society, Issue 147 (7), 2024, Page(s) 6037 - 6048, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.26434/chemrxiv-2024-x72vw

Mechanistic Studies on the Bismuth‐Catalyzed Transfer Hydrogenation of Azoarenes

Author(s): Hye Won Moon, Feng Wang, Kalishankar Bhattacharyya, Oriol Planas, Markus Leutzsch, Nils Nöthling, Alexander A. Auer, Josep Cornella
Published in: Angewandte Chemie, Issue 135, 2023, Page(s) 62 (49), ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202313578

Adición oxidante en complejos de bismuto

Author(s): Mauro Mato, Josep Cornellà
Published in: Anales de Química de la RSEQ, Issue 120, 2024, Page(s) 17, ISSN 2792-5250
Publisher: Real Sociedad Española de Química
DOI: 10.62534/rseq.aq.1955

Dibismuthanes in catalysis: from synthesis and characterization to redox behavior towards oxidative cleavage of 1,2-diols

Author(s): Marc Magre, Jennifer Kuziola, Nils Nöthling, Josep Cornella
Published in: Organic & Biomolecular Chemistry, Issue 19/22, 2021, Page(s) 4922-4929, ISSN 1477-0520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1ob00367d

Redox-Neutral Organometallic Elementary Steps at Bismuth: Catalytic Synthesis of Aryl Sulfonyl Fluorides

Author(s): Magre, M.; Cornella, J
Published in: Journal of the American Chemical Society, Issue 143 (51), 2022, Page(s) 21497 - 21502, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c11463

Book chapters (1)

Organometallic Compounds of Arsenic, Antimony and Bismuth

Author(s): Cornella Josep, Pang Yue
Published in: Comprehesive Oragnometallic Chemistry IV, 2022, Page(s) 478-522, ISBN 9780323913508
Publisher: Elsevier
DOI: 10.1016/b978-0-12-820206-7.00128-1

Other (1)

A trimetallic bismuth-based allyl cation

Author(s): Davide Spinnato; Nils Nöthling; Markus Leutzsch; Maurice van Gastel; Lucas Wagner; Frank Neese; Josep Cornella
Published in: ChemRxiv, Issue 3, 2024
Publisher: ChemRxiv
DOI: 10.26434/chemrxiv-2024-b8wzs