DRop-on demand flexible Optoelectronics & Photovoltaics by means of Lead-Free halide perovskITes

Project Information

DROP-IT

Grant agreement ID: 862656

DOI

10.3030/862656

Project closed

EC signature date 30 August 2019

Start date 1 November 2019

End date 30 April 2023

Funded under

• EXCELLENT SCIENCE - Future and Emerging Technologies (FET)

Total cost

€ 3 461 345,00

EU contribution

€ 3 461 344,00

Coordinated by

UNIVERSITAT DE VALENCIA
Spain

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Deliverables

Websites, patent fillings, videos etc. (1)

Project Website

A project Website will be created and hosted in the servers of the coordinator organization and continuous update by uploading news for different publics (general, scientific, industrial).

Documents, reports (19)

Theoretical analysis of several G-LFP families

A first set of compounds will be analyzed theoretically during this initial period, as the double perovskite family, also as the basis for optimizing the theoretical material’s screening process.

First Report on Dissemination Activities

Dissemination activities for different public and scientifictechnical levels will be summarized according to the conceived plan

Inkjet-printed films of B-LFPs from precursors on a flexible substrate

Production of inkjet-printed polycristalline films of B-LFPs from precursors on a flexible substrate.

Photodetectors and integrated photonic chips based on B-LFPs

Study of photoconductive detectors based on optimized BLFP material deposited by inkjet printing on flexible substrates and integration with waveguide amplifierslasers

Laser structures (waveguides, vertical cavities) based on inkjet-printed B-LFPs

Demonstration of lasing in optimized BLFP material integrated with optical resonators as Distributed Feedback structures waveguide geometry or Distributed Bragg Reflector cavities vertical geometry

Final Report on Dissemination Activities

Dissemination activities for different public and scientifictechnical levels will be summarized for the whole project duration according to the conceived plan

B-LFP compatible charge transport layers for inkjet printing

The compatibility with BLFP films of polymeric and inorganic nZnO nSnO2 pNiO transport layers will be evaluated for different device architectures work packages 34

Obtaining B-LFP nanocrystals and properties

BLFP Snbased Nanocrystals will be synthesized and their main optical and structural properties will be analyzed A suitable surface passivation will be developed for achieving longterm stability of optoelectronicphotonic devices

ASE in inkjet-printed B-LFP-based waveguides on flexible substrates

Amplification of the Spontaneous Emission ASE in inkjetprinted active waveguides based on optimized BLFPs nanoparticulated and polycrystalline films for comparison of figures of merit integrated on flexible substrates

Inkjet printing of B-LFP materials: best suited flexible substrate

The most suitable substrate will be elucidated on the basis of structural, optical and electrical properties of inkjet printed B-LFP films using optimized inks of nanocrystals.

Interfacing of B-LFPs with charge transport layers

Experimental and theoretical study of the most appropriate charge transport layers on interfacing with BLFPs Snbased from those most used in literature

Exploitation Plan

An exploitation plan will be prepared by taking into account the nature of results achieved along the project at the level of chemical synthesis of new perovskite-like materials, surface functionalization, ink formulations and thin film preparation by inkjet printing, and optoelectronic/photonic devices.

Homogeneous thin films of B-LFP nanocrystals and properties

The optical and electro-optical properties of homogeneous thin films based on B-LFP nanocrystals by using low demanding deposition techniques will be studied and analyzed.

Inkjet-printed RGB LED arrays based on B-LFPs

Fabrication of a small matrix 10x10 pixels with RGBsubpixels as a raw display whose pixels emit white light LED These arrays will be based on BLFPs by inkjet printing as optimized in this work package for singlecolor LEDs

Solar cells with PCE>12% based on inkjet-printed B-LFPs (areas 0.04-1 cm2)

Solar cells with different active areas 0041 cm2 based on inkjetprinted BLFP benchmark material will be optimized to obtain efficiencies higher than 12

Inkjet-printed RGB LEDs based on B-LFP (benchmark) with EQE>14% for green

Fabrication and optimization of singlecolor LEDs pin configuration based on BLFPs Sncation with appropriate content of ClBrI anion to define the color deposited by inkjet printing on flexible substrates in order to obtain EQE14 for green

Polycrystalline thin films of B-LFP from molecular precursors and properties

Polycrystalline thin films of B-LFP (Sn-based) with improved stability will prepared from molecular and their optical and electro-optical properties will be analyzed.

Patent Portfolio and Report on Exploitation Activities

At the end of DROPIT a patent portfolio and exploitation activities developed along the project will be summarized

Inkjet-printed B-LFP solar modules with an active area over 25 cm2.

Solar minimodules 25 cm2 configurations using BLFP material will be fabricated by means of industrial printheads and the relevant printing parameters will be optimized to reach the highest performance

Open Research Data Pilot (1)

Data Management and Dissemination Plans

Data Management and Dissemination Plans the open research data pilot plan will be activated for DROPIT after month 6 and the dissemination activities along the project will be planned with the agreement of all partners

Publications

Peer reviewed articles (18)

Silver–Bismuth Halide Double Salts for Lead-Free Photovoltaics: Insights from Symmetry-Based Modeling

Author(s): B. Cucco, L. Pedesseau, C. Katan, J. Even, M. Kepenekian, and G. Volonakis
Published in: Solar RRL, Issue 6, 2022, Page(s) 2200718 (1-8), ISSN 2367-198X
Publisher: Wiley-VCH Verlag
DOI: 10.1002/solr.202200718

Ecofriendly Perovskites with Giant Self-Defocusing Optical Response

Author(s): I. Suárez, J. P. Martínez-Pastor, M. F. Oszajca, N. A. Lüchinger, B. Graves, S. Agouram, C. Millán, A. Ferrando
Published in: Advanced Optical Materials, Issue 10, 2022, Page(s) 2202120 (1-10), ISSN 2195-1071
Publisher: wiley publisher
DOI: 10.1002/adom.202202120

Recycled Photons Traveling Several Millimeters in Waveguides Based on CsPbBr3 Perovskite Nanocrystals

Author(s): Juan Navarro-Arenas, Isaac Suárez, Andrés F. Gualdrón-Reyes, Iván Mora-Seró, Juan Bisquert, Juan P. Martínez-Pastor
Published in: Advanced Optical Materials, Issue 2100807, 2021, ISSN 2195-1071
Publisher: Wiley
DOI: 10.1002/adom.202100807

Directional and polarized lasing action on Pb-free FASnI3 integrated in flexible optical waveguides

Author(s): I. Suárez, V. S. Chirvony, J. Sánchez-Díaz, R. S. Sánchez, I. Mora-Seró and J. P. Martínez-Pastor
Published in: Advanced Optical Materials, Issue 10, 2022, Page(s) 2200458 (1-11), ISSN 2195-1071
Publisher: wiley publisher
DOI: 10.1002/adom.202200458

Negative Thermal Quenching in FASnI 3 Perovskite Single Crystals and Thin Films

Author(s): Simon Kahmann, Olga Nazarenko, Shuyan Shao, Oleh Hordiichuk, Mikaël Kepenekian, Jacky Even, Maksym V. Kovalenko, Graeme R. Blake, Maria A. Loi
Published in: ACS Energy Letters, Issue 5/8, 2020, Page(s) 2512-2519, ISSN 2380-8195
Publisher: American Chemical Society
DOI: 10.1021/acsenergylett.0c01166

Continuous-Flow Synthesis of Orange Emitting Sn(II)-Doped CsBr Materials

Author(s): Samrat Das Adhikari, Sofia Masi, Carlos Echeverría-Arrondo, Sara Miralles-Comins, Rafael S. Sánchez, Jesum Alves Fernandes, Vladimir Chirvony, Juan P. Martínez-Pastor, Victor Sans, Iván Mora-Seró
Published in: Advanced Optical Materials, Issue 2101024, 2021, ISSN 2195-1071
Publisher: Wiley
DOI: 10.1002/adom.202101024

Fine Structure of Excitons in Vacancy-Ordered Halide Double Perovskites

Author(s): B. Cucco, C. Katan, J. Even, M. Kepenekian, and Volonakis
Published in: ACS Materials Letters, Issue 5, 2023, Page(s) 52-59, ISSN 2639-4979
Publisher: ACS Publications
DOI: 10.1021/acsmaterialslett.2c01010

Unusual Spectrally Reproducible and High Q-Factor Random Lasing in Polycrystalline Tin Perovskite Films

Author(s): V. S. Chirvony, I. Suárez, Jesus Sanchez-Diaz, R. S. Sánchez, J. Rodríguez-Romero, I. Mora-Seró, and J. P. Martínez-Pastor
Published in: Advanced Materials, Issue 35, 2023, Page(s) 2208293 (1-10), ISSN 1521-4095
Publisher: Wiley Publisher
DOI: 10.1002/adma.202208293

Pb-free halide perovskites for solar cells, light-emitting diodes, and photocatalysts

Author(s): P. Jiang, D. Acharya, G. Volonakis, M. Zacharias, M. Kepenekian, L. Pedesseau, C. Katan, J. Even
Published in: APL Materials, Issue 10, 2022, Page(s) 060902 (1-19), ISSN 2166-532X
Publisher: AIP Publishing LLC
DOI: 10.1063/5.0095515

Inkjet-Printed p-NiO/n-ZnO Heterojunction Diodes for Photodetection Applications

Author(s): S. González, G. Vescio, J. L. Frieiro, A. Hauser, F. Linardi, J. López‐Vidrier, M. Oszajca, S. Hernández, A. Cirera, and B. Garrido
Published in: Advanced Materials Interfaces, Issue 10, 2022, Page(s) 2300035 (1-8), ISSN 2196-7350
Publisher: Wiley publisher
DOI: 10.1002/admi.202300035

2D PEA2SnI4 Inkjet-Printed Halide Perovskite LEDs on Rigid and Flexible Substrates

Author(s): J. Sanchez-Diaz, J.L. Frieiro, R. S. Sánchez, S. Hernández, A. Cirera, I.Mora-Seró, and B. Garrido
Published in: ACS Energy Letters, Issue 7, 2022, Page(s) 3653–3655, ISSN 2380-8195
Publisher: ACS Publications
DOI: 10.1021/acsenergylett.2c01773

Sr-Doping Engineering for Enabling Long-Term Stable FAPb1 xSrxI3 Quantum Dots with 100% Photoluminescence Quantum Yield

Author(s): Andrés. F. Gualdrón-Reyes, David F. Macias-Pinilla, Sofía Masi, Carlos Echeverría-Arrondo, Said Agouram, Vicente Muñoz-Sanjosé, Jhonatan Rodríguez-Pereira, Jan M. Macak, and Iván Mora-Seró
Published in: J. Mat. Chem. C, Issue 9, 2021, Page(s) 1555-1566, ISSN 2050-7534
Publisher: Royal Society of Chemistry
DOI: 10.1039/d0tc04625f

White Light Emission from Lead-Free Mixed-Cation Doped Cs2SnCl6 Nanocrystals

Author(s): S. Das Adhikari, C. Echeverría-Arrondo, R. S. Sánchez, V. S. Chirvony, J. P. Martínez-Pastor, S. Agouram, V. Muñoz-Sanjosé, I. Mora-Seró
Published in: Nanoscale, Issue 14, 2022, Page(s) 1468-1479, ISSN 2040-3372
Publisher: RSC
DOI: 10.1039/d1nr06255g

Intrinsic formamidinium tin iodide nanocrystals by suppressing the Sn(IV) impurities

Author(s): D. N. Dirin, A. Vivani, M. Zacharias, T. Sekh, I. Cherniukh, S. Yakunin, F. Bertolotti, M. Aebli, R. D. Schaller, A. Wieczorek, S. Siol, C. Cancellieri, L. P. H. Jeurgens, N. Masciocchi, A. Guagliardi, L. Pedesseau, J. Even, M. V. Kovalenko, and M. I. Bodnarchuk
Published in: Nano Letters, Issue 23, 2023, Page(s) 1914-1923, ISSN 1530-6984
Publisher: American Chemical Society
DOI: 10.1021/acs.nanolett.2c04927

High Quality Inkjet Printed-Emissive Nanocrystalline Perovskite CsPbBr3 Layers for Color Conversion Layer and LEDs Applications

Author(s): G. Vescio, J. L. Frieiro, A. F. Gualdrón-Reyes, S. Hernández, I. Mora-Seró, B. Garrido, A. Cirera
Published in: Advanced Materials Technologies, Issue 7, 2022, Page(s) 2101525 (1-11), ISSN 2365-709X
Publisher: wiley publisher
DOI: 10.1002/admt.202101525

Electronic structure and stability of Cs2TiX6 and Cs2ZrX6 (X = Br, I) vacancy ordered double perovskites

Author(s): B. Cucco, G. Bouder, L. Pedesseau, C. Katan, J. Even, M. Kepenekian, G. Volonakis
Published in: Applied Physics Letters, Issue 119, 2021, Page(s) 181903, ISSN 0003-6951
Publisher: American Institute of Physics
DOI: 10.1063/5.0070104

From Zero- to One-Dimensional, Opportunities and Caveats of Hybrid Iodobismuthates for Optoelectronic Applications

Author(s): A. Skorokhod, N. Mercier, M. Allain, M. Manceau, C. Katan, and M. Kepenekian
Published in: Inorganic Chemistry, Issue 60, 2021, Page(s) 17123-17131, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.1c02384

Tin perovskite solar cells with >1300 hours of operational stability in N2 through a synergistic chemical engineering approach

Author(s): J. Sanchez-Diaz, R. S. Sánchez, S. Masi, M. Kreĉmarová, A. O. Alvarez, E. M. Barea, J. Rodriguez-Romero, V. S. Chirvony, J. F. Sánchez-Royo, J. P. Martinez-Pastor and I. Mora-Seró
Published in: Joule, Issue 6, 2022, Page(s) 861-883, ISSN 2542-4351
Publisher: Cell Press
DOI: 10.1016/j.joule.2022.02.014

Other (1)

H2020 European FET-Open project DROP-IT

Author(s): Pedesseau, Laurent; Kepenekian, Mikaël; Katan, Claudine; Even, Jacky
Published in: 9è Journées Nationales du PhotoVoltaïque (JNPV 2019), Dec 2019, Dourdan, France, Issue 1, 2019, Page(s) Poster
Publisher: Fédération de Recherche Photovoltaïque - CNRS
DOI: 10.5281/zenodo.4306452