SYNergistic SORBents

Project Information

SYNSORB

Grant agreement ID: 885695

DOI

10.3030/885695

EC signature date 12 May 2020

Start date 1 September 2020

End date 31 August 2026

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 2 497 298,00

EU contribution

€ 2 497 298,00

Coordinated by

UNIVERSITY OF LIMERICK
Ireland

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Deliverables

Open Research Data Pilot (1)

Data Management Plan

Data Management plan

Publications

Peer reviewed articles (35)

Pillar Modularity in <b>fsc</b> Topology Hybrid Ultramicroporous Materials Based upon Tetra(4-pyridyl)benzene

Author(s): Debobroto Sensharma; Benjamin H. Wilson; Naveen Kumar; Daniel J. O’Hearn; Michael J. Zaworotko
Published in: Crystal Growth and Design, 2022, ISSN 1528-7483
Publisher: American Chemical Society
DOI: 10.1021/acs.cgd.2c00561

Highly Productive C₃H₄/C₃H₆ Trace Separation by a Packing Polymorph of a Layered Hybrid Ultramicroporous Material

Author(s): Mei-Yan Gao, Andrey A. Bezrukov, Bai-Qiao Song, Meng He, Sousa Javan Nikkhah, Shi-Qiang Wang, Naveen Kumar, Shaza Darwish, Debobroto Sensharma, Chenghua Deng, Jiangnan Li, Lunjie Liu, Rajamani Krishna, Matthias Vandichel, Sihai Yang, Michael J. Zaworotko
Published in: Journal of the American Chemical Society, 2023, Page(s) 11837–11845, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c03505

Reversible Phase Transformations in a Double-Walled Diamondoid Coordination Network with a Stepped Isotherm for Methane

Author(s): Xia Li, Debobroto Sensharma, Leigh Loots, Shubo Geng, Sousa Javan Nikkhah, En Lin, Volodymyr Bon, Wansheng Liu, Zhifang Wang, Tao He, Soumya Mukherjee, Matthias Vandichel, Stefan Kaskel, Leonard J. Barbour, Zhenjie Zhang, Michael J. Zaworotko
Published in: Journal of the American Chemical Society, Issue 146, 2024, Page(s) 18387-18395, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c03555

Crystal Engineering of a New Hexafluorogermanate Pillared Hybrid Ultramicroporous Material Delivers Enhanced Acetylene Selectivity

Author(s): Nathan C. Harvey-Reid, Debobroto Sensharma, Soumya Mukherjee, Komal M. Patil, Naveen Kumar, Sousa Javan Nikkhah, Matthias Vandichel, Michael J. Zaworotko, Paul E. Kruger
Published in: ACS Applied Materials &amp; Interfaces, Issue 16, 2024, Page(s) 4803-4810, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.3c16634

Amino-Functionalised Hybrid Ultramicroporous Materials that Enable Single-Step Ethylene Purification from a Ternary Mixture

Author(s): Soumya Mukherjee; Naveen Kumar; Andrey A. Bezrukov; Kui Tan; Tony Pham; Katherine A. Forrest; Kolade A. Oyekan; Omid T. Qazvini; David G. Madden; Brian Space; Brian Space; Michael J. Zaworotko
Published in: Angewandte Chemie (International Ed. in English), 2021, Page(s) 10902-10909, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202100240

Flexible Coordination Network Exhibiting Water Vapor–Induced Reversible Switching between Closed and Open Phases

Author(s): Mohana Shivanna; Andrey A. Bezrukov; Victoria Gascón-Pérez; Ken-ichi Otake; Suresh Sanda; Daniel J. O’Hearn; Qing-Yuan Yang; Susumu Kitagawa; Michael J. Zaworotko
Published in: ACS Applied Materials and Interfaces, 2022, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.2c10002

Control over Phase Transformations in a Family of Flexible Double Diamondoid Coordination Networks through Linker Ligand Substitution

Author(s): Kyriaki Koupepidou, Varvara I. Nikolayenko, Debobroto Sensharma, Andrey A. Bezrukov, Mohana Shivanna, Dominic C. Castell, Shi-Qiang Wang, Naveen Kumar, Ken-ichi Otake, Susumu Kitagawa, Michael J. Zaworotko
Published in: Chemistry of Materials, Issue 35, 2023, Page(s) 3660-3670, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.3c00334

Green Synthesis of a New Schiff Base Linker and Its Use to Prepare Coordination Polymers

Author(s): Maria T. Hayes, Aizhamal Subanbekova, Yassin H. Andaloussi, Alan C. Eaby, Michael J. Zaworotko
Published in: Crystal Growth &amp; Design, Issue 25, 2025, Page(s) 444-451, ISSN 1528-7483
Publisher: American Chemical Society
DOI: 10.1021/acs.cgd.4c01606

Reversible single-crystal to single-crystal phase transformation between a new Werner clathrate and its apohost.

Author(s): Catiúcia R. M. O. Matos; Catiúcia R. M. O. Matos; Rana Sanii; Shi-Qiang Wang; Célia M. Ronconi; Michael J. Zaworotko
Published in: Dalton Transactions (Cambridge, England : 2003), 2021, Page(s) 12923-12930, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d1dt01839f

Efficient Capture of Trace Acetylene by an Ultramicroporous Metal-Organic Framework with Purine Binding Sites

Author(s): Shivani Sharma; Soumya Mukherjee; Soumya Mukherjee; Aamod V. Desai; Matthias Vandichel; Gourab K. Dam; Ashwini Jadhav; Gabriele Kociok-Köhn; Michael J. Zaworotko; Sujit K. Ghosh
Published in: Chemistry of Materials, 2021, Page(s) 5800-5808, ISSN 0897-4756
Publisher: American Chemical Society
DOI: 10.1021/acs.chemmater.1c01723

A new type of C₂H₂ binding site in a <i>cis</i>-bridging hexafluorosilicate ultramicroporous material that offers trace C₂H₂ capture

Author(s): Bai-Qiao Song, Mei-Yan Gao, Lisa Mercene van Wyk, Cheng-Hua Deng, Alan C. Eaby, Shi-Qiang Wang, Shaza Darwish, Dan Li, Shao-Jie Qin, Yun-Lei Peng, Qing-Yuan Yang, Leonard J. Barbour, Michael J. Zaworotko
Published in: Chemical Science, Issue 16, 2025, Page(s) 9010-9019, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d5sc00697j

One-step ethylene production from a four-component gas mixture by a single physisorbent

Author(s): Jian-Wei Cao, Soumya Mukherjee, Tony Pham, Yu Wang, Teng Wang, Tao Zhang, Xue Jiang, Hui-Juan Tang, Katherine A. Forrest, Brian Space, Michael J. Zaworotko, Kai-Jie Chen
Published in: Nature Communications, 2021, Page(s) 6507, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-021-26473-8

CO ₂ Capture by Hybrid Ultramicroporous TIFSIX‐3‐Ni under Humid Conditions Using Non‐Equilibrium Cycling

Author(s): Saif Ullah; Kui Tan; Debobroto Sensharma; Naveen Kumar; Soumya Mukherjee; Andrey A. Bezrukov; Jing Li; Michael J. Zaworotko; Timo Thonhauser
Published in: Angewandte Chemie (International Ed. in English), 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202206613

One Step Further: A Flexible Metal–Organic Framework that Functions as a Dual-Purpose Water Vapor Sorbent

Author(s): Samuel M. Shabangu, Andrey A. Bezrukov, Alan C. Eaby, Sousa Javan Nikkhah, Shaza Darwish, Varvara I. Nikolayenko, Debobroto Sensharma, Shi-Qiang Wang, Matthias Vandichel, Michael J. Zaworotko
Published in: ACS Materials Letters, Issue 7, 2025, Page(s) 433-441, ISSN 2639-4979
Publisher: American Chemical Society (ACS)
DOI: 10.1021/acsmaterialslett.4c02019

Crystal Engineering of a Chiral Crystalline Sponge That Enables Absolute Structure Determination and Enantiomeric Separation

Author(s): Chenghua Deng, Bai-Qiao Song, Matteo Lusi, Andrey A. Bezrukov, Molly M. Haskins, Mei-Yan Gao, Yun-Lei Peng, Jian-Gong Ma, Peng Cheng, Soumya Mukherjee, Michael J. Zaworotko
Published in: Crystal Growth &amp; Design, Issue 23, 2023, Page(s) 5211-5220, ISSN 1528-7483
Publisher: American Chemical Society
DOI: 10.1021/acs.cgd.3c00446

Trace removal of benzene vapour using double-walled metal–dipyrazolate frameworks

Author(s): Tao He, Xiang-Jing Kong, Zhen-Xing Bian, Yong-Zheng Zhang, Guang-Rui Si, Lin-Hua Xie, Xue-Qian Wu, Hongliang Huang, Ze Chang, Xian-He Bu, Michael J. Zaworotko, Zuo-Ren Nie, Jian-Rong Li
Published in: Nature Materials, 2022, ISSN 1476-1122
Publisher: Nature Publishing Group
DOI: 10.1038/s41563-022-01237-x

Crystal engineering of a new platform of hybrid ultramicroporous materials and their C₂H₂/CO₂ separation properties

Author(s): Daniel J. O'Hearn, Debobroto Sensharma, Asif Raza, Andrey A. Bezrukov, Matthias Vandichel, Soumya Mukherjee, Michael J. Zaworotko
Published in: Chemical Science, Issue 15, 2024, Page(s) 17937-17943, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4sc03029j

Functional flexible adsorbents and their potential utility

Author(s): Kyriaki Koupepidou, Aizhamal Subanbekova, Michael J. Zaworotko
Published in: Chemical Communications, Issue 61, 2025, Page(s) 3109-3126, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4cc05393a

Effect of Extra-Framework Anion Substitution on the Properties of a Chiral Crystalline Sponge

Author(s): Chenghua Deng, Bai-Qiao Song, Debobroto Sensharma, Mei-Yan Gao, Andrey A. Bezrukov, Varvara I. Nikolayenko, Matteo Lusi, Soumya Mukherjee, Michael J. Zaworotko
Published in: Crystal Growth &amp; Design, Issue 23, 2023, Page(s) 8139-8146, ISSN 1528-7483
Publisher: American Chemical Society
DOI: 10.1021/acs.cgd.3c00857

Ultramicroporous Lonsdaleite Topology MOF with High Propane Uptake and Propane/Methane Selectivity for Propane Capture from Simulated Natural Gas

Author(s): Chenghua Deng, Li Zhao, Mei-Yan Gao, Shaza Darwish, Bai-Qiao Song, Debobroto Sensharma, Matteo Lusi, Yun-Lei Peng, Soumya Mukherjee, Michael J. Zaworotko
Published in: ACS Materials Letters, Issue 6, 2024, Page(s) 56-65, ISSN 2639-4979
Publisher: American Chemical Society (ACS)
DOI: 10.1021/acsmaterialslett.3c01157

Reversible Co(II)–Co(III) Transformation in a Family of Metal–Dipyrazolate Frameworks

Author(s): Xiang-Jing Kong, Tao He, Andrey A. Bezrukov, Shaza Darwish, Guang-Rui Si, Yong-Zheng Zhang, Wei Wu, Yingjie Wang, Xia Li, Naveen Kumar, Jian-Rong Li, Michael J. Zaworotko
Published in: Journal of the American Chemical Society, 2024, Page(s) 34402–34408, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c09173

The Effect of Pendent Groups upon Flexibility in Coordination Networks with Square Lattice Topology

Author(s): Xia Li, Debobroto Sensharma, Kyriaki Koupepidou, Xiang-Jing Kong, Michael J. Zaworotko
Published in: ACS Materials Letters, Issue 5, 2023, Page(s) 2567-2575, ISSN 2639-4979
Publisher: American Chemical Society (ACS)
DOI: 10.1021/acsmaterialslett.3c00565

Effect of Polymorphism on the Sorption Properties of a Flexible Square-Lattice Topology Coordination Network

Author(s): Aizhamal Subanbekova, Andrey A. Bezrukov, Volodymyr Bon, Varvara I. Nikolayenko, Kyriaki Koupepidou, Debobroto Sensharma, Sousa Javan Nikkhah, Shi-Qiang Wang, Stefan Kaskel, Matthias Vandichel, Michael J. Zaworotko
Published in: ACS Applied Materials &amp; Interfaces, 2024, Page(s) 24132–24140, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.4c03777

Dinuclear Copper Sulfate-Based Square Lattice Topology Network with High Alkyne Selectivity

Author(s): Yassin H. Andaloussi, Debobroto Sensharma, Andrey A. Bezrukov, Dominic C. Castell, Tao He, Shaza Darwish, Michael J. Zaworotko
Published in: Crystal Growth &amp; Design, Issue 24, 2024, Page(s) 2573-2579, ISSN 1528-7483
Publisher: American Chemical Society
DOI: 10.1021/acs.cgd.4c00094

Breaking the trade-off between selectivity and adsorption capacity for gas separation

Author(s): Naveen Kumar, Soumya Mukherjee, Nathan C.Harvey-Reid, Andrey A. Bezrukov, Kui Tan, Vinicius Martins, Matthias Vandichel, Tony Pham, Lisa M. van Wyk, Kolade Oyekan, Amrit Kumar, Katherine A. Forrest, Komal M. Patil, Leonard J. Barbour, Brian Space, Yining Huang, Paul E. Kruger, Michael J. Zaworotko
Published in: Chem, 2021, Page(s) 3085-3098, ISSN 2451-9294
Publisher: Elsevier BV
DOI: 10.1016/j.chempr.2021.07.007

Crystal engineering of porous coordination networks for C3 hydrocarbon separation

Author(s): Mei-Yan Gao; Bai-Qiao Song; Debobroto Sensharma; Michael J. Zaworotko
Published in: SmartMat, 2020, Page(s) 38-55, ISSN 2688-819X
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/smm2.1016

One Atom Can Make All the Difference: Gas-Induced Phase Transformations in Bisimidazole-Linked Diamondoid Coordination Networks

Author(s): Kyriaki Koupepidou, Varvara I. Nikolayenko, Debobroto Sensharma, Andrey A. Bezrukov, Matthias Vandichel, Sousa Javan Nikkhah, Dominic C. Castell, Kolade A. Oyekan, Naveen Kumar, Aizhamal Subanbekova, William G. Vandenberghe, Kui Tan, Leonard J. Barbour, and Michael J. Zaworotko
Published in: Journal of American Chemical Society, 2023, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c01113

Water vapour and gas induced phase transformations in an 8-fold interpenetrated diamondoid metal–organic framework

Author(s): Aizhamal Subanbekova, Varvara I. Nikolayenko,Andrey A. Bezrukov, Debobroto Sensharma, Naveen Kumar, Daniel J. O'Hearn, Volodymyr Bon, Shi-Qiang Wang, Kyriaki Koupepidou, Shaza Darwish, Stefan Kaskel, Michael J. Zaworotko
Published in: Journal of Materials Chemistry A, 2023, ISSN 2050-7488
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3ta01574b

A pcu topology metal–organic framework, Ni(1,4-bib)(inca)₂, that exhibits high CO₂/N₂ selectivity and low water vapour affinity

Author(s): Samuel M. Shabangu, Alan C. Eaby, Sousa Javan Nikkhah, Lilia Croitor, Tao He, Andrey A. Bezrukov, Matthias Vandichel, Michael J. Zaworotko
Published in: Journal of Materials Chemistry A, 2025, ISSN 2050-7488
Publisher: Royal Society of Chemistry
DOI: 10.1039/d5ta01995h

Gate-opening Induced by C8 Aromatics in a Double Diamondoid Coordination Network

Author(s): Kyriaki Koupepidou, Shi-Qiang Wang, Varvara I. Nikolayenko, Dominic C. Castell, Catiúcia R. M. O. Matos, Matthias Vandichel, Michael J. Zaworotko
Published in: ACS Materials Letters, Issue 6, 2024, Page(s) 2197-2204, ISSN 2639-4979
Publisher: American Chemical Society (ACS)
DOI: 10.1021/acsmaterialslett.4c00511

Reversible transformations between the non-porous phases of a flexible coordination network enabled by transient porosity

Author(s): Varvara I. Nikolayenko, Dominic C. Castell, Debobroto Sensharma, Mohana Shivanna, Leigh Loots, Katherine A. Forrest, Carlos J. Solanilla-Salinas, Ken-ichi Otake, Susumu Kitagawa, Leonard J. Barbour, Brian Space, Michael J. Zaworotko
Published in: Nature Chemistry, 2023, ISSN 1755-4330
Publisher: Nature Publishing Group
DOI: 10.1038/s41557-022-01128-3

Modulation of Water Vapor Sorption by Pore Engineering in Isostructural Square Lattice Topology Coordination Networks

Author(s): Xia Li, Andrey A. Bezrukov, Wells Graham, Debobroto Sensharma, Xiang-Jing Kong, Timo Thonhauser, Michael J. Zaworotko
Published in: ACS Applied Materials &amp; Interfaces, Issue 16, 2024, Page(s) 34402-34408, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.4c06412

The First Sulfate-Pillared Hybrid Ultramicroporous Material, SOFOUR-1-Zn, and Its Acetylene Capture Properties

Author(s): Debobroto Sensharma, Daniel J. O'Hearn, Amin Koochaki, Andrey A. Bezrukov, Naveen Kumar, Benjamin H. Wilson, Matthias Vandichel, Michael J. Zaworotko
Published in: Angewandte Chemie International Edition, 2021, Page(s) e202116145, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ange.202116145

Crystal Engineering of Two Light and Pressure Responsive Physisorbents

Author(s): Dominic C. Castell; Varvara I. Nikolayenko; Debobroto Sensharma; Kyriaki Koupepidou; Katherine A. Forrest; Carlos J. Solanilla‐Salinas; Brian Space; Leonard J. Barbour; Michael J. Zaworotko
Published in: Angewandte Chemie (International Ed. in English), 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202219039

A Needle in a Haystack: Transient Porosity in a Closed Pore Square Lattice Coordination Network

Author(s): Kyriaki Koupepidou, Alan C. Eaby, Debobroto Sensharma, Sousa Javan Nikkhah, Tao He, Matteo Lusi, Matthias Vandichel, Leonard J. Barbour, Soumya Mukherjee, Michael J. Zaworotko
Published in: Angewandte Chemie, Issue 137, 2025, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/ange.202423521