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Liquid-Assisted Grinding - from Fundaments to Applications

Project description

Moving liquid-assisted grinding to the commercial stage

Mechanochemistry using manual grinding or ball mill equipment is an attractive and sustainable alternative to traditional solution methods for synthesising composite solids. Using small volumes of water, liquid-assisted grinding can accelerate the kinetics reactions between different solids. The EU-funded GrindCore project aims to provide further insight into the reaction mechanisms that take place on a molecular level during liquid-assisted grinding. Researchers plan to monitor the real-time kinetic reactions of an organic compound called methylcyclohexane through advanced X-ray diffraction and Raman spectroscopy techniques. The project's results could help take this technology faster to the commercial stage. Liquid-assisted grinding produces novel solids with bespoke physical and chemical properties that can be used by the pharmaceutical industry to screen for new drugs.

Objective

Liquid-assisted grinding (LAG) is a mechanochemical process in which a catalytic amount of added liquid tremendously accelerate the reaction kinetics, and often significantly alter reaction outcome. Due to high applicability potential of LAG and still a huge amount of ambiguities, it has become essential to improve understanding of reaction mechanisms at molecular level. Establishing a correspondence between solution and solid-state reaction mechanisms would enable utilisation of huge body of knowledge in the currently barely grazed mechanistic framework of solid-state milling reactions, which is a prerequisite for their systematic use and utilisation in Green Chemistry synthetic alternatives, which would be a critical requirement for any industrial application of LAG. This project should contribute implementation of MCh for a cleaner chemical laboratory and a sustainable, low-waste and low-emissions chemical and pharmaceutical industry. It is unacceptable that further development of such an important methodology depends on a mere trial and error or, at best, on the experimenter's experience and instincts.
Here, recently developed techniques for in situ real-time monitoring of MCh reactions by X-ray diffraction and Raman spectroscopy will be employed to enable insight into uninterrupted reactions and thus resolution of mechanistic pathways and kinetics of the selected representative simple reactions. The obtained data will be interpreted with respect of properties of liquids added to LAG systems. It is expected that in this way the catalytic action of liquids in LAG reactions will be put to a firmer ground.
The accumulated fundamental understanding of LAG reactions will be then applied to develop or improve Green Chemistry procedures for selected environmentally relevant processes and materials. This should consequently lead to optimisation of these processes, setting them ready for scale-up to ecologically friendlier, sustainable industrial processes.

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Topic(s)

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MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF)

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Call for proposal

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(opens in new window) H2020-MSCA-IF-2019

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Coordinator

RUDER BOSKOVIC INSTITUTE
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 243 763,20
Address
Bijenicka cesta 54
10000 Zagreb
Croatia

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Region
Hrvatska Grad Zagreb Grad Zagreb
Activity type
Research Organisations
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 243 763,20

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