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Diamond and Metal Photo-Electrocatalysts for Hydrogen Evolution and Carbon Dioxide Reduction

Descripción del proyecto

Producción de combustible y compuestos químicos valiosos a partir del diamante

Mitigar el cambio climático y reducir las emisiones de gases de efecto invernadero son los principales retos del siglo XXI. En el centro de estos retos está satisfacer la creciente demanda energética y usar la energía de manera eficiente al tiempo que se reduce la dependencia de los combustibles fósiles. El programa Horizonte 2020 de la Unión Europea desempeña un papel crucial en la transición hacia fuentes de energía renovable. El proyecto financiado con fondos europeos DIMPEL CAT empleará cristales de diamante para imitar el proceso natural de la fotosíntesis y transformar CO2 en combustible y compuestos químicos valiosos. Hasta el momento, intentos parecidos han necesitado emplear materiales escasos y caros como el platino. Emplear diamantes sintéticos constituye un gran avance en el campo: los diamantes emiten electrones con un alto potencial de reducción, lo que significa que pueden reducir moléculas inertes como el CO2.

Objetivo

Climate change, increased energy demand, and greenhouse gases have major impacts on the environment. Following the recent International Climate Change conference in Paris, many nations have initiated measures to fulfill their agreements to reduce carbon emissions and promote renewable energy. In addition, EU Horizon 2020 has the major priority to invest funds in development of secure, clean and efficient energy methods. Currently, the most efficient way to produce the clean energy source H2 requires platinum. However, this metal is highly scarce and expensive. Carbon Dioxide conversion to synthetic fuels such as CO, formaldehyde is likewise mainly performed by expensive metals, and at high temperatures which are unsustainable. Therefore, there is a strong incentive to develop alternative, sustainable catalysts based on cheap, earth-abundant materials.
In this project, we are going to use the diamonds as nano materials which can release electrons into solution upon illumination; the electrons can be used by the transition metal complexes for the production of hydrogen and to convert CO2 into valuable chemicals such as CO, formic acid. The inspiration comes here from the natures photosynthesis where the sunlight is harvested by plants to fix CO2 to valuable chemicals such as carbohydrates. Diamond is unique in its ability to produce solvated electrons directly into solution upon irradiation; these electrons are highly reducing and have capacity to activate CO2. This projects aims to improve the selectivity and efficiency of the reduction process by coupling the reducing electrons from diamond with the most effective transition metal catalysts from literature. Furthermore, this project will provide a new set of skills required for becoming an independent researcher in the highly important sustainable energy field.

Ámbito científico (EuroSciVoc)

CORDIS clasifica los proyectos con EuroSciVoc, una taxonomía plurilingüe de ámbitos científicos, mediante un proceso semiautomático basado en técnicas de procesamiento del lenguaje natural.

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Coordinador

UNIVERSITY COLLEGE LONDON
Aportación neta de la UEn
€ 224 933,76
Dirección
GOWER STREET
WC1E 6BT London
Reino Unido

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Región
London Inner London — West Camden and City of London
Tipo de actividad
Higher or Secondary Education Establishments
Enlaces
Coste total
€ 224 933,76