The investigations focused on the experimental characterization, buffer gas cooling and quantum chemistry. We could numerically show that the system could become twice as cold by careful optimization of the ion trap parameters and thus probe deeper into the quantum regime. Furthermore, we created a bath of Feshbach dimers and measured the molecular ion formation that followed when combing the bath with the ion. This demonstrated the sensing capabilities of a trapped ion in probing as little as 50 dimers in a bath of 20 000 atoms. These results were published in four peer-reviewed publications: Hirzler et al., Phys. Rev. A 102, 033109 (2020), Hirzler et al., Phys. Rev. Res. 2, 033232 (2020), Trimby et al., New J. Phys. 24, 035004 (2022) and Hirzler et al., Phys. Rev. Lett. 128, 103401 (2022). Furthermore, the knowledge obtained on ultracold ion-atom systems was reviewed and summarized as a chapter in Advances In Atomic, Molecular, and Optical Physics (Lous and Gerritsma, AAMOP 71, 65-133 (2022)).