Bismuth Compounds in Radical Reactions: Fundamental Aspects and Synthetic Applications

Project Information

Bismuth Goes Radical

Grant agreement ID: 946184

DOI

10.3030/946184

EC signature date 30 October 2020

Start date 1 May 2021

End date 31 December 2026

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 470 753,00

EU contribution

€ 1 470 753,00

Coordinated by

PHILIPPS UNIVERSITAET MARBURG
Germany

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Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (18)

Between imide, imidyl and nitrene – an imido iron complex in two oxidation states

Author(s): Sascha Reith; Serhiy Demeshko; Beatrice Battistella; Alexander Reckziegel; Christian Schneider; Andreas Stoy; Crispin Lichtenberg; Franc Meyer; Dominik Munz; C. Gunnar Werncke
Published in: Chemical Science, Issue 1, 2023, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2sc01088g

Insertion of CO₂ and CS₂ into Bi–N bonds enables catalyzed CH-activation and light-induced bismuthinidene transfer

Author(s): Kai Oberdorf; Anna Hanft; Xiulan Xie; F. Matthias Bickelhaupt; Jordi Poater; Crispin Lichtenberg
Published in: Chemical Science, 2023, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3sc01635h

Charge Makes a Difference: Molecular Ionic Bismuth Compounds

Author(s): Johanna Heine, Benjamin Peerless, Stefanie Dehnen, Crispin Lichtenberg
Published in: Angewandte Chemie, 2023, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/anie.202218771

A Dibismuthane with Olefin Functional Groups: Towards Tridentate Hybrid Chalcogen/Olefin Ligands

Author(s): Felix Geist, Sebastián Martínez, Jacqueline Ramler, Kai Oberdorf, Lisa Brändler, Sascha Reith, Crispin Lichtenberg
Published in: European Journal of Inorganic Chemistry, 2023, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202300415

Bonding in Low-Coordinated Organoarsenic and Organoantimony Compounds: A Threshold Photoelectron Spectroscopic Investigation

Author(s): Emil Karaev, Marius Gerlach, Lukas Faschingbauer, Jacqueline Ramler, Ivo Krummenacher, Crispin Lichtenberg, Patrick Hemberger, Ingo Fischer
Published in: Chemistry - A European Journal, 2023, ISSN 1521-3765
Publisher: Wiley VCH
DOI: 10.1002/chem.202300637

Bismut in der Dynamisch Kovalenten Chemie: Makrocyclen und Siebenkernige Komplexkationen mit Ungewöhnlichen Strukturen

Author(s): Andreas Stoy; Malte Jürgensen; Christina Millidoni; Chantsalmaa Berthold; Jacqueline Ramler; Sebastián Martínez; Magnus R. Buchner; Crispin Lichtenberg
Published in: Angewandte Chemie, 2023, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/ange.202308293

Charge Makes a Difference: Molecular Ionic Bismuth Compounds

Author(s): Johanna Heine; Benjamin Peerless; Stefanie Dehnen; Crispin Lichtenberg
Published in: Angewandte Chemie International Edition, Issue 1, 2023, ISSN 1521-3757
Publisher: Wiley VCH
DOI: 10.1002/ange.202218771

Cyclic Hydrocarbon Frameworks Containing Two Bismuth Atoms: Towards 9,10‐Dibismaanthracene

Author(s): Dennis Rottschäfer, Sascha Reith, Johannes Schwarzmann, Frank Tambornino, Crispin Lichtenberg
Published in: Chemistry – A European Journal, Issue 30, 2024, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202303363

Reductive Aromatization of 5,7,12,14‐Pentacenetetrone: Approach Towards Substituted Pentacenes?

Author(s): Olaf A. Kleykamp, Eugen Sharikow, Andreas Stoy, Xiulan Xie, Crispin Lichtenberg, Jörg Sundermeyer
Published in: Chemistry – A European Journal, Issue 31, 2025, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202403929

Two Faces of the Bi−O Bond: Photochemically and Thermally Induced Dehydrocoupling for Si−O Bond Formation

Author(s): Jacqueline Ramler, Johannes Schwarzmann, Andreas Stoy, Crispin Lichtenberg
Published in: European Journal of Inorganic Chemistry, 2022, ISSN 1099-0682
Publisher: Wiley
DOI: 10.1002/ejic.202100934

Bismuth in Dynamic Covalent Chemistry: Access to a Bowl‐Type Macrocycle and a Barrel‐Type Heptanuclear Complex Cation

Author(s): Andreas Stoy; Malte Jürgensen; Christina Millidoni; Chantsalmaa Berthold; Jacqueline Ramler; Sebastián Martínez; Magnus R. Buchner; Crispin Lichtenberg
Published in: Angewandte Chemie International Edition, 2023, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202308293

The Chlorido-Bismuth Dication: A Potent Lewis Acid Captured in a Hepta-Coordinate Species with a Stereochemically Active Lone Pair

Author(s): Ahmed Fetoh, Felipe Fantuzzi, Crispin Lichtenberg
Published in: Inorganic Chemistry, Issue 63, 2024, Page(s) 12089-12099, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c01076

Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical-Coupling Reactions (Pn=N, P, As)

Author(s): Kai Oberdorf, Anna Hanft, Jacqueline Ramler, Ivo Krummenacher, Matthias Bickelhaupt, Jordi Poater, Crispin Lichtenberg
Published in: Angewandte Chemie International Edition, 2021, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/anie.202015514

Transition Metal Mimetic π-Activation by Cationic Bismuth(III) Catalysts for Allylic C–H Functionalization of Olefins Using C═O and C═N Electrophiles

Author(s): Ruihan Wang, Sebastián Martínez, Johannes Schwarzmann, Christopher Z. Zhao, Jacqueline Ramler, Crispin Lichtenberg, Yi-Ming Wang
Published in: Journal of the American Chemical Society, Issue 146, 2024, Page(s) 22122-22128, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c06235

Bismutamide als einfache Vermittler hochselektiver Pn−Pn-Radikal-Kupplungsreaktionen (Pn=N, P, As)

Author(s): Kai Oberdorf, Anna Hanft, Jacqueline Ramler, Ivo Krummenacher, Matthias Bickelhaupt, Jordi Poater, Crispin Lichtenberg
Published in: Angewandte Chemie, 2021, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/ange.202015514

Bismuth Cations: Fluoride Ion Abstraction, Isocyanide Coordination, and Impact of Steric Bulk on Lewis Acidity

Author(s): Tobias Dunaj; Johannes Schwarzmann; Jacqueline Ramler; Andreas Stoy; Sascha Reith; Joel Nitzsche; Lena Völlinger; Carsten von Hänisch; Crispin Lichtenberg
Published in: Chemistry - A European Journal, Issue 1, 2023, ISSN 1521-3765
Publisher: Wiley VCH
DOI: 10.1002/chem.202204012

Bismuth as a Z‐Type Ligand: an Unsupported Pt−Bi Donor‐Acceptor Interaction and its Umpolung by Reaction with H₂

Author(s): Johannes Schwarzmann, Toni Eskelinen, Sascha Reith, Jacqueline Ramler, Antti J. Karttunen, Jordi Poater, Crispin Lichtenberg
Published in: Angewandte Chemie, Issue 136, 2024, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/ange.202410291

Bismuth Bound to Transition Metals: Visible‐Light‐Induced Olefin Coordination, Reductive Elimination, and Oxidative Addition

Author(s): Jacqueline Ramler, Felix Geist, Cornelius Mihm, Lukas Lubczyk, Sascha Reith, Christoph Herok, Felipe Fantuzzi, Crispin Lichtenberg
Published in: Chemistry – A European Journal, Issue 31, 2025, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202403253