Bismuth Compounds in Radical Reactions: Fundamental Aspects and Synthetic Applications

Project Information

Bismuth Goes Radical

Grant agreement ID: 946184

DOI 10.3030/946184

EC signature date 30 October 2020

Start date 1 May 2021

End date 30 April 2026

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost € 1 470 753,00

EU contribution € 1 470 753,00

Coordinated by

PHILIPPS UNIVERSITAET MARBURG
Germany

Publications

Peer reviewed articles (12)

Between imide, imidyl and nitrene – an imido iron complex in two oxidation states

Author(s): Sascha Reith; Serhiy Demeshko; Beatrice Battistella; Alexander Reckziegel; Christian Schneider; Andreas Stoy; Crispin Lichtenberg; Franc Meyer; Dominik Munz; C. Gunnar Werncke
Published in: Chemical Science, Issue 1, 2023, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2sc01088g

Insertion of CO₂ and CS₂ into Bi–N bonds enables catalyzed CH-activation and light-induced bismuthinidene transfer

Author(s): Kai Oberdorf; Anna Hanft; Xiulan Xie; F. Matthias Bickelhaupt; Jordi Poater; Crispin Lichtenberg
Published in: Chemical Science, 2023, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3sc01635h

Charge Makes a Difference: Molecular Ionic Bismuth Compounds

Author(s): Johanna Heine, Benjamin Peerless, Stefanie Dehnen, Crispin Lichtenberg
Published in: Angewandte Chemie, 2023, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/anie.202218771

A Dibismuthane with Olefin Functional Groups: Towards Tridentate Hybrid Chalcogen/Olefin Ligands

Author(s): Felix Geist, Sebastián Martínez, Jacqueline Ramler, Kai Oberdorf, Lisa Brändler, Sascha Reith, Crispin Lichtenberg
Published in: European Journal of Inorganic Chemistry, 2023, ISSN 1434-1948
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/ejic.202300415

Bonding in Low-Coordinated Organoarsenic and Organoantimony Compounds: A Threshold Photoelectron Spectroscopic Investigation

Author(s): Emil Karaev, Marius Gerlach, Lukas Faschingbauer, Jacqueline Ramler, Ivo Krummenacher, Crispin Lichtenberg, Patrick Hemberger, Ingo Fischer
Published in: Chemistry - A European Journal, 2023, ISSN 1521-3765
Publisher: Wiley VCH
DOI: 10.1002/chem.202300637

Bismut in der Dynamisch Kovalenten Chemie: Makrocyclen und Siebenkernige Komplexkationen mit Ungewöhnlichen Strukturen

Author(s): Andreas Stoy; Malte Jürgensen; Christina Millidoni; Chantsalmaa Berthold; Jacqueline Ramler; Sebastián Martínez; Magnus R. Buchner; Crispin Lichtenberg
Published in: Angewandte Chemie, 2023, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/ange.202308293

Charge Makes a Difference: Molecular Ionic Bismuth Compounds

Author(s): Johanna Heine; Benjamin Peerless; Stefanie Dehnen; Crispin Lichtenberg
Published in: Angewandte Chemie International Edition, Issue 1, 2023, ISSN 1521-3757
Publisher: Wiley VCH
DOI: 10.1002/ange.202218771

Two Faces of the Bi−O Bond: Photochemically and Thermally Induced Dehydrocoupling for Si−O Bond Formation

Author(s): Jacqueline Ramler, Johannes Schwarzmann, Andreas Stoy, Crispin Lichtenberg
Published in: European Journal of Inorganic Chemistry, 2022, ISSN 1099-0682
Publisher: Wiley
DOI: 10.1002/ejic.202100934

Bismuth in Dynamic Covalent Chemistry: Access to a Bowl‐Type Macrocycle and a Barrel‐Type Heptanuclear Complex Cation

Author(s): Andreas Stoy; Malte Jürgensen; Christina Millidoni; Chantsalmaa Berthold; Jacqueline Ramler; Sebastián Martínez; Magnus R. Buchner; Crispin Lichtenberg
Published in: Angewandte Chemie International Edition, 2023, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202308293

Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical-Coupling Reactions (Pn=N, P, As)

Author(s): Kai Oberdorf, Anna Hanft, Jacqueline Ramler, Ivo Krummenacher, Matthias Bickelhaupt, Jordi Poater, Crispin Lichtenberg
Published in: Angewandte Chemie International Edition, 2021, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/anie.202015514

Bismutamide als einfache Vermittler hochselektiver Pn−Pn-Radikal-Kupplungsreaktionen (Pn=N, P, As)

Author(s): Kai Oberdorf, Anna Hanft, Jacqueline Ramler, Ivo Krummenacher, Matthias Bickelhaupt, Jordi Poater, Crispin Lichtenberg
Published in: Angewandte Chemie, 2021, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/ange.202015514

Bismuth Cations: Fluoride Ion Abstraction, Isocyanide Coordination, and Impact of Steric Bulk on Lewis Acidity

Author(s): Tobias Dunaj; Johannes Schwarzmann; Jacqueline Ramler; Andreas Stoy; Sascha Reith; Joel Nitzsche; Lena Völlinger; Carsten von Hänisch; Crispin Lichtenberg
Published in: Chemistry - A European Journal, Issue 1, 2023, ISSN 1521-3765
Publisher: Wiley VCH
DOI: 10.1002/chem.202204012