Charge Separation – A General Motif for the Activation and Catalytic Functionalization of Strong Bonds

Project Information

PUSH-IT

Grant agreement ID: 948185

DOI

10.3030/948185

EC signature date 11 September 2020

Start date 1 December 2020

End date 31 May 2026

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 499 658,00

EU contribution

€ 1 499 658,00

Coordinated by

UNIVERSITAT DES SAARLANDES
Germany

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Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (12)

(CAAC)Pd(py) Catalysts Disproportionate to Pd(CAAC)2

Author(s): Nicola Marigo, Bernd Morgenstern, Andrea Biffis, Dominik Munz
Published in: Organometallics, Issue 42, 2023, Page(s) 1567-1572, ISSN 1520-6041
Publisher: ACS
DOI: 10.22028/d291-40090

Über Carbenintermediate in der Al^I vermittelten Homologisierung von Isocyaniden

Author(s): Cuijuan Zhang; Fabian Dankert; Ziang Jiang; Baolu Wang; Dominik Munz; Jiaxiang Chu
Published in: Angew. Chem. Int. Ed., 2023, ISSN 1521-3757
Publisher: Wiley
DOI: 10.1002/ange.202307352

π‐Lewis Base Activation of Carbonyls and Hexafluorobenzene

Author(s): Aditesh Mondal, Kevin Breitwieser, Sergi Danés, Annette Grünwald, Frank W. Heinemann, Bernd Morgenstern, Frank Müller, Michael Haumann, Maximilian Schütze, Dustin Kass, Kallol Ray, Dominik Munz
Published in: Angewandte Chemie International Edition, Issue 64, 2025, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202418738

Iron-Catalyzed Intermolecular C−H Amination Assisted by an Isolated Iron-Imido Radical Intermediate

Author(s): Ethan Zars, Lisa Pick, Abinash Swain, Dr. Mrinal Bhunia, Dr. Patrick J. Carroll, Prof. Dr. Dominik Munz, Prof. Dr. Karsten Meyer, Prof. Dr. Daniel J. Mindiola
Published in: Angew. Chem. Int. Ed., 2024, ISSN 1521-3773
Publisher: Wiley
DOI: 10.1002/anie.202311749

Hexaphenyl-1,2-Diphosphonium Dication [Ph₃P–PPh₃]²⁺: Superacid, Superoxidant, or Super Reagent?

Author(s): Fabian Dankert, Simon P. Muhm, Chandan Nandi, Sergi Danés, Sneha Mullassery, Petra Herbeck-Engel, Bernd Morgenstern, Robert Weiss, Pedro Salvador, Dominik Munz
Published in: Journal of the American Chemical Society, Issue 147, 2025, Page(s) 15369-15376, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.5c01271

Swift C–C bond insertion by a 12-electron palladium(0) surrogate

Author(s): Kevin Breitwieser; Fabian Dankert; Annette Grünwald; Paula R. Mayer; Frank W. Heinemann; Dominik Munz
Published in: Chem. Commun., Issue 1, 2023, ISSN 1359-7345
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3cc03964a

A Lead(II) Substituted Triplet Carbene

Author(s): Fabian Dankert, Julian Messelberger, Abinash Swain, Ugo Authesserre, David Scheschkewitz, Bernd Morgenstern, Dominik Munz
Published in: J. Am. Chem. Soc., 2024, ISSN 1520-5126
Publisher: ACS
DOI: 10.26434/chemrxiv-2024-64knm

Gauging Radical Stabilization with Carbenes

Author(s): Kevin Breitwieser, Hilke Bahmann, Robert Weiss, Dominik Munz
Published in: Angew. Chem. Int. Ed., Issue e202206390, 2022, ISSN 1521-3757
Publisher: Wiley
DOI: 10.1002/anie.202206390

Between imide, imidyl and nitrene – an imido iron complex in two oxidation states

Author(s): Sascha Reith, Serhiy Demeshko, Beatrice Battistella, Alexander Reckziegel, Christian Schneider, Andreas Stoy, Crispin Lichtenberg, Franc Meyer, Dominik Munz, C. Gunnar Werncke
Published in: Chem. Sci., Issue 13, 2022, Page(s) 7907-7913, ISSN 2041-6539
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2sc01088g

Evidence for Carbene Intermediates in Isocyanide Homologation by Aluminium(I)

Author(s): Cuijuan Zhang, Fabian Dankert, Ziang Jiang, Baolu Wang, Dominik Munz, Jiaxiang Chu
Published in: Angew. Chem. Int. Ed., Issue e202307352, 2023, Page(s) e202307352, ISSN 1521-3757
Publisher: Wiley VCH
DOI: 10.1002/anie.202307352

Pd₈(PDip)₆: Cubic, Unsaturated, Zerovalent

Author(s): Kevin Breitwieser, Matteo Bevilacqua, Sneha Mullassery, Fabian Dankert, Bernd Morgenstern, Samuel Grandthyll, Frank Müller, Andrea Biffis, Christian Hering‐Junghans, Dominik Munz
Published in: Advanced Science, Issue 11, 2024, ISSN 2198-3844
Publisher: Wiley VCH
DOI: 10.1002/advs.202400699

Circularly Polarized Luminescence from Cyclic (Alkyl)(Amino) Carbene Derived Propellers

Author(s): Jan Lorkowski, Dylan Bouetard, Patrick Yorkgitis, Milan Gembicky, Thierry Roisnel, Nicolas Vanthuyne, Dominik Munz, Ludovic Favereau, Guy Bertrand, Marc Mauduit, Rodolphe Jazzar
Published in: Angew. Chem. Int. Ed., Issue e202305404, 2023, Page(s) e202305404, ISSN 1521-3757
Publisher: Wiley VCH
DOI: 10.1002/anie.202305404

Non-peer reviewed articles (2)

Elucidation of Organometallic Reaction Mechanisms by a China–Germany Team

Author(s): Jiaxiang Chu, Dominik Munz
Published in: Angew. Chem. Int. Ed., 2023, ISSN 1521-3773
Publisher: Wiley
DOI: 10.1002/anie.202314198

Elucidation of Organometallic Reaction Mechanisms by a China–Germany Team

Author(s): Dominik Munz, Jiaxiang Chu
Published in: Angewandte Chemie, Issue 135, 2024, ISSN 0044-8249
Publisher: Wiley VCH
DOI: 10.1002/ange.202314198

Other (2)

The Hexaphenyl-1,2-Diphosphonium Dication [Ph3P–PPh3]2+

Author(s): Fabian Dankert, Simon P. Muhm, Chandan Nandi, Sergi Danés, Sneha Mullassery, Petra Herbeck-Engel, Bernd Morgenstern, Robert Weiss, Pedro Salvador Sedano, Dominik Munz
Published in: ChemRXiv, 2025
Publisher: German Chemical Society (GDCh)
DOI: 10.26434/chemrxiv-2025-xt8vg

Gold(I) Terminal Imides: CH Auration and Dehydrogenation

Author(s): Emiliano Martinez-Vollbert, Suseelan Sarala Anjana, Fabian Dankert, Bernd Morgenstern, Dominik Munz
Published in: ChemRXiv, 2025
Publisher: Gesellschaft Deutsch Chemiker (GDCh)
DOI: 10.26434/chemrxiv-2025-shkhb