Topological Explorations with a Clip: New Molecular Nanocarbons

Project Information

TOPOCLIP

Grant agreement ID: 949397

DOI

10.3030/949397

Project closed

EC signature date 15 October 2020

Start date 1 April 2021

End date 31 March 2026

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 499 625,00

EU contribution

€ 1 499 625,00

Coordinated by

UNIVERSITEIT VAN AMSTERDAM
Netherlands

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Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (13)

Effect of π‐Electron Conjugation on the Chiroptical Properties of Helicene Carbon Nanohoops

Author(s): Kovida Kovida, Juraj Malinčík, Tomáš Šolomek
Published in: Helvetica Chimica Acta, Issue 108, 2025, ISSN 0018-019X
Publisher: Verlag Helvetica Chimica Acta
DOI: 10.1002/hlca.202400166

π‐Radical Cascades to <i>Peri</i> ‐Fused Triangulene Dimers

Author(s): Paula L. Widmer, Leoš Valenta, Maximilian Mayländer, Jules Hutter, Francis J. Carta, Simon Jurt, Olivier Blacque, Laurent Bigler, Sabine Richert, Tomáš Šolomek, Michal Juríček
Published in: Angewandte Chemie International Edition, 2026, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.6610209

Giving the green light to photochemical uncaging of large biomolecules in high vacuum

Author(s): Yong Hua; Marcel Strauss; Sergey Fisher; Martin F. X. Mauser; Pierre Manchet; Martina Smacchia; Philipp Geyer; Armin Shayeghi; Michael Pfeffer; Tim Henri Eggenweiler; Steven Daly; Jan Commandeur; Marcel Mayor; Markus Arndt; Tomáš Šolomek; Valentin Köhler
Published in: JACS Au, Issue 1, 2023, ISSN 2691-3704
Publisher: Washington DC: American Chemical Society

How do Nanohoops Exercise Their Strain in [5]Helicene Racemization?

Author(s): Kovida Kovida, Juraj Malinčík, Thijs de Groot, Tomáš Šolomek
Published in: The Journal of Organic Chemistry, Issue 90, 2025, Page(s) 16607-16614, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.5c02280

Surfing the limits of cyanine photocages one step at a time

Author(s): Hana Janeková, Sergey Fisher, Tomáš Šolomek, Peter Štacko
Published in: Chemical Science, Issue 16, 2025, Page(s) 1677-1683, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4sc07165d

Role of exciton delocalization in chiroptical properties of benzothiadiazole carbon nanohoops

Author(s): Kovida Kovida, Juraj Malinčík, Carlos M. Cruz, Araceli G. Campaña, Tomáš Šolomek
Published in: Chemical Science, Issue 16, 2025, Page(s) 1405-1410, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4sc07333a

Exploring Silyl Protecting Groups for the Synthesis of Carbon Nanohoops

Author(s): Remigiusz B. Kręcijasz, Juraj Malinčík, Tomáš Šolomek
Published in: Synthesis, 2023, ISSN 0039-7881
Publisher: Georg Thieme Verlag
DOI: 10.1055/a-2008-9505

Circularly Polarized Luminescence in a Möbius Helicene Carbon Nanohoop

Author(s): Juraj Malinčík, Sudhakar Gaikwad, Juan P. Mora-Fuentes, Marc-Aurèle Boillat, Alessandro Prescimone, Daniel Häussinger, Araceli G. Campaña, Tomáš Šolomek
Published in: Angewandte Chemie International Edition, 2022, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202208591

Topological Bistability of the π-System in a Helicene Carbon Nanohoop

Author(s): Tomáš Šolomek, Juraj Malinčík
Published in: Synlett, 2024, ISSN 0936-5214
Publisher: Georg Thieme Verlag
DOI: 10.1055/a-2223-7245

Photoremovable Protecting Groups: Across the Light Spectrum to Near-Infrared Absorbing Photocages

Author(s): Peter Štacko, Tomáš Šolomek
Published in: CHIMIA, Issue 75, 2023, Page(s) 873, ISSN 0009-4293
Publisher: Schweizerische Chemische Gedellschaft
DOI: 10.2533/chimia.2021.873

Kinetic Trapping of Rylene Diimide Covalent Organic Cages

Author(s): Sergey Fisher, Hsin-Hua Huang, Luise Sokoliuk, Alessandro Prescimone, Olaf Fuhr, Tomáš Šolomek
Published in: The Journal of Organic Chemistry, Issue 90, 2025, Page(s) 4158-4166, ISSN 0022-3263
Publisher: American Chemical Society
DOI: 10.1021/acs.joc.4c02547

Leveraging Halogen Interactions for a Supramolecular Nanotube

Author(s): Sergey Fisher, Lorraine A. Malaspina, Cristian Gozálvez Martínez, Alessandro Prescimone, Yaser Balmohammadi, Simon Grabowsky, Tomáš Šolomek
Published in: Chemistry – A European Journal, Issue 30, 2025, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202400295

Strain-Induced Photochemical Opening of Ferrocene[6]cycloparaphenylene: Uncaging of Fe²⁺ with Green Light

Author(s): Remigiusz B. Kręcijasz, Juraj Malinčík, Simon Mathew, Peter Štacko, Tomáš Šolomek
Published in: Journal of the American Chemical Society, Issue 147, 2025, Page(s) 10231-10237, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c15818

Other (3)

π-System Bistability Determines the Circularly Polarized Luminescence in Helicene para-Phenylenes

Author(s): Juraj Malinčík; Carlos M. Cruz; Araceli G. Campaña; Tomáš Šolomek
Published in: ChemRxiv, 2024, ISSN 2573-2293
Publisher: American Chemical Society, Royal Societyof Chemistry, German Chemical Society, Chemical Society of Japan, Chinese Chemical Society
DOI: 10.26434/chemrxiv-2024-6pxt4

Decoding and Exploiting Kinetic Pathways in Dynamic Covalent Cage Formation via Isolated Macrocycle Precursors

Author(s): Sergey Fisher, Luise Sokoliuk, Robin Patrick Jos van Damme, Simon Meister, Noah Rychener, Tomáš Šolomek
Published in: ChemRxiv, 2026, ISSN 2573-2293
Publisher: American Chemical Society, Royal Societyof Chemistry, German Chemical Society, Chemical Society of Japan, Chinese Chemical Society
DOI: 10.26434/chemrxiv-2025-phz0c

Strain-Gated Photochemical Fe²⁺ Uncaging in Ferrocene-[n]Cycloparaphenylenes: A Photomechanophore Paradigm

Author(s): Remigiusz G. Kręcijasz, Simon Mathew, Tomáš Šolomek
Published in: ChemRxiv, 2026, ISSN 2573-2293
Publisher: American Chemical Society, Royal Societyof Chemistry, German Chemical Society, Chemical Society of Japan, Chinese Chemical Society
DOI: 10.26434/chemrxiv-2026-7g2pt