Selective Electrochemical Nucleophilic Fluorination

Project Information

SENF

Grant agreement ID: 949821

DOI

10.3030/949821

EC signature date 22 October 2020

Start date 1 August 2021

End date 31 January 2027

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 1 553 043,00

EU contribution

€ 1 553 043,00

Coordinated by

UNIVERSITY OF BRISTOL
United Kingdom

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Publications

Peer reviewed articles (13)

Palladium-catalysed regio- and stereo-controlled C-2 β-fluorovinylation of indoles

Author(s): Atul K. Chaturvedi, Alastair J. J. Lennox
Published in: Organic Chemistry Frontiers, Issue 12, 2025, Page(s) 4410-4416, ISSN 2052-4129
Publisher: Royal Society of Chemistry (RSC)
DOI: 10.1039/d5qo00521c

Pulsed electrolysis: enhancing primary benzylic C(sp³)–H nucleophilic fluorination

Author(s): Alexander P. Atkins; Atul K. Chaturvedi; Joseph A. Tate; Alastair J. J. Lennox
Published in: Organic Chemistry Frontiers, Issue 1, 2024, ISSN 2052-4129
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3qo01865b

Hypervalent iodine-mediated intramolecular alkene halocyclisation

Author(s): Charu Bansal, Oliver Ruggles, Albert C Rowett, Alastair J J Lennox
Published in: Beilstein Journal of Organic Chemistry, Issue 20, 2024, Page(s) 3113-3133, ISSN 1860-5397
Publisher: Beilstein-Institut
DOI: 10.3762/bjoc.20.258

Silver-Catalyzed (<i>Z</i>)-β-Fluoro-vinyl Iodonium Salts from Alkynes: Efficient and Selective Syntheses of <i>Z</i>-Monofluoroalkenes

Author(s): Alexi T. Sedikides, Alastair J. J. Lennox
Published in: Journal of the American Chemical Society, Issue 146, 2024, Page(s) 15672-15680, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c03826

Non-Aqueous Binary and Ternary <i>n</i>HF·Base Fluoride Reagents: Characterization of Structure, Properties, and Reactivity

Author(s): Stephen G. Sweeting, Alastair J. J. Lennox
Published in: Journal of the American Chemical Society, Issue 147, 2025, Page(s) 19329-19341, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.5c05472

Benzylic C(sp³)–H fluorination

Author(s): Alexander P Atkins, Alice C Dean, Alastair J J Lennox
Published in: Beilstein Journal of Organic Chemistry, Issue 20, 2024, Page(s) 1527-1547, ISSN 1860-5397
Publisher: Beilstein-Institut
DOI: 10.3762/bjoc.20.137

Electrochemical Synthesis of Isolated Fluoride Reagents from PFAS

Author(s): Florian Dorchies, Luke P. Ward, Isaac P. Richards, Mohamed Elsherbini, Alastair J. J. Lennox
Published in: Journal of the American Chemical Society, Issue 148, 2026, Page(s) 12255-12263, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.6c01373

200 Years of The Haloform Reaction: Methods and Applications

Author(s): Albert C. Rowett, David M. Heard, Priya Koria, Alice C. Dean, Stephen G. Sweeting, Alastair J. J. Lennox
Published in: Chemistry – A European Journal, Issue 30, 2025, ISSN 0947-6539
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202403045

Ultrafast Excited-State Dynamics of the Organic Photoredox Catalyst DDQ

Author(s): Deborin Ghosh, Vera Brieskorn, Charlotte A. Smith, Hallam J. M. Greene, Ria G. Binyahan, Federico J. Hernández, Alastair J. J. Lennox, Basile F. E. Curchod, Andrew J. Orr-Ewing
Published in: The Journal of Physical Chemistry Letters, Issue 16, 2025, Page(s) 9748-9752, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.5c02391

A Stoichiometric Haloform Coupling for Ester Synthesis with Secondary Alcohols

Author(s): Albert C. Rowett, Stephen G. Sweeting, David M. Heard, Alastair J. J. Lennox
Published in: Angewandte Chemie International Edition, Issue 63, 2024, ISSN 1433-7851
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/anie.202400570

Diastereodivergent nucleophile–nucleophile alkene chlorofluorination

Author(s): Sayad Doobary, Andrew J. D. Lacey, Stephen G. Sweeting, Sarah B. Coppock, Henry P. Caldora, Darren L. Poole, Alastair J. J. Lennox
Published in: Nature Chemistry, Issue 16, 2024, Page(s) 1647-1655, ISSN 1755-4330
Publisher: Nature Publishing Group
DOI: 10.1038/s41557-024-01561-6

Au(I)‐, Au(II)‐, Au(III)‐Fluoride Complexes: Synthesis and Applications in Organic Transformations

Author(s): Alexi T. Sedikides, Rhian C. Walters, Alice C. Dean, Alastair J. J. Lennox
Published in: Angewandte Chemie, Issue 137, 2026, ISSN 0044-8249
Publisher: Wiley
DOI: 10.1002/ange.202424656

Oxidative benzylic C(sp ³ )–H functionalisation of electron-poor substrates with photoexcited DDQ

Author(s): Alexander P. Atkins, Charlotte A. Smith, Deborin Ghosh, Hallam J. M. Greene, Ria G. Binyahan, Ciaran J. Greene, Joseph A. Tate, Andrew J. Orr-Ewing, Alastair J. J. Lennox
Published in: Chemical Science, Issue 16, 2025, Page(s) 19280-19287, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d5sc05561j