Light assisted solar fuel production by artificial CO2 Reduction and water Oxidation

Informations projet

LICROX

N° de convention de subvention: 951843

DOI 10.3030/951843

Projet clôturé

Date de signature de la CE 29 Juin 2020

Date de début 1 Septembre 2020

Date de fin 31 Août 2023

Financé au titre de

• EXCELLENT SCIENCE - Future and Emerging Technologies (FET)

Coût total € 3 199 602,50

Contribution de l’UE € 3 199 602,50

Coordonné par

FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA
Spain

Livrables

Open Research Data Pilot (2)

D7.3. DMP

A detailed data management plan will be prepared, including storage, oversight, quality assurance, back-ups, anonymization, definitions and other aspects

7.4 Update DMP

Update of the DMP midterm of project

Documents, reports (14)

D2.1 Nanocatalysts for CO2R

Report on CuNCs with different sizes and shapes as well as different capping ligands for selective CO to ethylene and ethanol conversion

D3.1 Optimized BiVO4 photoanodes with coupled WOC

Report evaluating the performance and stability of optimized BiVO4 photoanodes

D5.2 Photoanode/OPV/dark cathode half-cell

Report on the fabrication and test performance of the PEC with the configuration photoanodeOPVdark cathode

D4.2 Light absorption in the PEC

Report on the optimal PEC fabricated structure that will be designed to enhance absorption and balance the current among the different light absorption materials in the cell

D6.4 Societal acceptability

The findings of the four citizens workshops will be joint in an assessment report on societal acceptability

D2.3 Tandem catalytic system for CO2R

Report on dark cathodes based on a tandem catalytic system containing Cu NCs and molCAT with current densities j 2030 mAcm2 and onset potentials of E 025 to 05 V vs RHE

D3.3 Optimized Fe2TiO5 photoanodes

Report evaluating the performance and stability of optimized NP Fe2TiO5 photoanodes

D3.2 Optimized CuFeO2 photocathodes

Report evaluating the performance and stability of optimized CuFeO2 photocathodes

D4.1 Summary of computational approaches & models

Report on the methodology and codes used to improve light trapping in the tandem PECs

2.4 Anodes for WOC

Report on dark anodes based on iron or copper molecular water oxidation catalysts with current densities of j 2030 mAcm2 and working potential E 15 to 17 V vs RHE

D5.3 Full photoelectrochemical cells

Report on the performance and comparison of the three Full PECs fabricated within Task 54 with configuration photoanodeOPVphotocathode

D5.1 Photocathode/OPV/dark anode half-cell

Report on the fabrication and test performance of the PEC with the configuration photocathodeOPVdark anode

CO2R molecular catalysts

Report on iron and cobalt molecular catalysts active for the CO2R from CO2 to CO molCAT

D6.3 Environmental, societal and ethical consequences of the LICROX technology

The stakeholder workshop and the LCA report will be joint in an assessment report of environmental societal and ethical consequences of the LICROX technology

Websites, patent fillings, videos etc. (1)

D6.2 Project website

Project website live

Publications

Peer reviewed articles (4)

Tandem electrocatalytic CO₂ reduction with Fe-porphyrins and Cu nanocubes enhances ethylene production

Auteurs: Min Wang; Vasilis Nikolaou; Anna Loiudice; Ian D. Sharp; Antoni Llobet; Raffaella Buonsanti
Publié dans: Chemical Science, Numéro 11, 2022, ISSN 2041-6539
Éditeur: Royal Society of Chemistry
DOI: 10.1039/d2sc04794b

Crystal-Phase Control of Ternary Metal Oxides by Solid-State Synthesis with Nanocrystals

Auteurs: Anna Loiudice; Bastien P.G. Niau; Raffaella Buonsanti
Publié dans: ACS Nanoscience Au, Numéro 2, 2022, ISSN 1936-0851
Éditeur: American Chemical Society
DOI: 10.1021/acsnanoscienceau.1c00049

Consecutive Ligand-Based Electron Transfer in New Molecular Copper-Based Water Oxidation Catalysts

Auteurs: Marcos Gil-Sepulcre, Pablo Garrido-Barros, Jan Oldengott, Ignacio Funes-Ardoiz, Roger Bofill, Xavier Sala, Jordi Benet-Buchholz, Antoni Llobet
Publié dans: Angewandte Chemie International Edition, Numéro 60, 34, 2021, Page(s) 18639-18644, ISSN 1521-3773
Éditeur: Wiley-VCH
DOI: 10.1002/anie.202104020

The spatial distribution of cobalt phthalocyanine and copper nanocubes controls the selectivity towards C2 products in tandem electrocatalytic CO2 reduction

Auteurs: Min Wang, Anna Loiudice, Valery Okatenko, Ian D. Sharp and Raffaella Buonsanti
Publié dans: Chemical Science, Numéro 14, 2023, Page(s) 1097-1104, ISSN 2041-6539
Éditeur: Royal Society of Chemistry
DOI: 10.1039/d2sc06359j