The RTD performers (Delft University of Technology of Delft, the Netherlands and Inescop of Elda, Spain) have consorted with the industrial partners in a project to investigate the industrial potential of UV/Ozone pre-treatment of plastic and rubber parts for adhesive applications in the footwear, printing, coating and metallization industries. A main objective was, to replace pre-treatments of such surfaces with hazardous and poisonous chemicals, which are presently used for these purposes, but which are detrimental for workers' health and for the environment.The technology window for the application of UV/Ozone pre-treatment of polymer surfaces as an industrial technology was established. It was found that:
- -Short wavelength UV (172nm, 185nm) must be used in this process.
- -Ozone (O3) molecules or other oxidants must be present at the treated surface, rather than being formed bij the UV-radiation in the ambient atmosphere.
- A low pressure, low intensity mercury UV-source can be used, but it must have a special quartz envelope which transmits the 185nm wavelength UV.
- With these low pressure UV-sources the recommended pre-treatment time for polymer and rubber surfaces is of the order of minutes.
- For large series of parts to be treated this calls for moving belt, chain or band operations through a stationary and continuously operating UV-irradiation cabinet.
- Surfaces of polyethylene, polypropylene, polyvinylchloride were pre-treated with UV/Ozone and order of magnitude (tenfold) increases were obtained in the adhesion strength of coatings, glues and printing inks.
- Industrial parts and surfaces of engineering plastics or rubbers (ABS, EPDM, SBS, SBR, TR) and of leather were successfully pre-treated with UV/ozone and industrial specifications for specific adhesive technologies were met.
- Prototype equipment for UV/ozone pre-treatment has been built and equipment manufacturers among the partners in the consortium have obtained the first commercial orders for apparatus of this kind.
- With high intensity, low wavelength (172nm) UV excimer sources the irradiation time for successful pre-treatment of polymer surfaces is reduced to seconds.
The conclusion now is, that existing pre-treatments for coatings and adhesive technologies in several industrial applications can successfully be replaced by UV/Ozone pre-treatment. This gives advantages for workers' health and in the industrial impact on the environment. Introduction of UV/Ozone pre-treatment can lead to competitive industrial advantage, through modernisation of the manufacturing technology, improved process control and a more reproducible quality of the manufactured products.