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Contenido archivado el 2024-05-07

Synthesis and structural investigation of mono,di- and trinuclear transitionmetal complexes containing highly delocalized systems

Objetivo



There is great interest in a new class of organometallic compounds, tho in which one or more metals are part of the Pi-system of a linear conjugated carbon chain Cn. The interest is due principally to the fact that they may present new material properties, as liquid crystals or as non linear opticals.
Complexes 1 and 2 have been prepared in Prof. Werner's Group: (drawing 1 and 2) 1 and 2 are excellent building blocks for the preparation of new rhodium complexes in which the metal is bonded to two different Cn chains, taking part of a highly delocalized Pi-system. The objective of the research work will be the preparation of:
a) Mononuclear complexes, linking 1 or 2 to a C_C-C_CPh unit.
b) Di- and trinuclear complexes, linking 1 or 2 to other metallic centers by C_C- C_C chains.
c) Di- and trinuclear complexes containing ligands with very different electronic properties at the two ends of the molecule; these compounds may exhibit non-linear optical properties. Compounds having this optical properties are of great interest because of the potential applications in the new materials industry.

Ámbito científico (EuroSciVoc)

Programa(s)

Tema(s)

Convocatoria de propuestas

Datos no disponibles

Régimen de financiación

RGI - Research grants (individual fellowships)

Coordinador

Bayerische Julius-Maximilians-Universität Würzburg
Aportación de la UE
Sin datos
Dirección
Am Hubland
97074 Würzburg
Alemania
Coste total
Sin datos

Participantes (1)