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Content archived on 2024-05-15

Towards the control of molecular-level machines operation through encapsulation in zeolites and mesoporous aluminosilicates.

Objective

The main objective of the project deals with the encapsulation of supramolecular level devices and machines, such as rotaxanes and [2]-catenanes, within the rigid internal voids of zeolites and mesoporous aluminosilicates. The resulting materials comprising an encapsulated molecular device could serve as a basis for the future Nanotechnology: the development of mechanoelectrical and photochemical communication systems and devices capable of storing and processing information. One of the common actions of these molecular devices is based on the occurrence of an elementary step of charge or electron transfer. The problem for the operation of the device is that back electron transfer is very fast in solution, taking place in the picoseconds time scale, and being too short for any nuclear movement to occur. It is well known the potential of zeolites as a medium to stabilize short-lived transients and to compartmentalize the entrapped molecules within their rigid voids. It is the purpose of this project to show that encapsulation of molecular level machines can contribute positively to the operation of these supramolecular devices. This benefit would derive from the increase in the lifetime of charge-separated states.

Fields of science (EuroSciVoc)

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Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

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Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

RGI - Research grants (individual fellowships)

Coordinator

UNIVERSITY OF BOLOGNA
EU contribution
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Address
Via Francesco Selmi 2
40126 BOLOGNA
Italy

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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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