Objetivo The main goal of the project is the design of novel homogeneous catalysts on the basis of tailor-made hybrid phosphine ligands.In the course of the project a number of functional hybrid phosphines will be obtained from a wide range of primary phosphines, based on the reactions of primary phosphines with functionalised halides or aldehydes in the presence of functionalised amines, especially amino acids. The two mutually connected aspects of functional hybrid phosphines, namely, water-solubility and binucleating ability towards hard and soft transition metals, due to the hydrophilic properties and reactivity of the functional groups, will be investigated, with the major goal of designing highly effective and stereoselective catalysts for mono- and biphasic reactions, such as olefin metathesis, polymerisation of e-caprolactone, ethylene carbonate, and glycolide; and co-polymerisation of e-caprolactone, ethylene carbonate, or olefins with carbon monoxide; and chiral polymerisation of L-(-)-lactide, leading towards biodegradable polymers.Therefore a sophisticated investigation of the properties of the desired novel phosphines is proposed, uniting the efforts of organoelement, organometallic, structural, and catalytic teams. This approach provides the possibility of solving a number of fundamental problems, such as reactivity of hybrid phosphines, structure and behaviour of their transition metal complexes in solution, mechanism and structure of intermediates of the catalytic processes, as well as a number of applied problems of precatalyst design, the most effective conditions for the catalytic reactions, as well as utilisation of the results in industry. Programa(s) IC-INTAS - International Association for the promotion of cooperation with scientists from the independent states of the former Soviet Union (INTAS), 1993- Tema(s) 3 - Chemistry OPEN - OPEN Call Convocatoria de propuestas Data not available Régimen de financiación Data not available Coordinador Universität Leipzig Aportación de la UE Sin datos Dirección Johannisallee 29 04103 Leipzig Alemania Ver en el mapa Coste total Sin datos Participantes (5) Ordenar alfabéticamente Ordenar por aportación de la UE Ampliar todo Contraer todo A. E. Arbusov Institute of Organic and Physical Chemistry Rusia Aportación de la UE Sin datos Dirección Arbusov str. 8 420088 Kazan Ver en el mapa Coste total Sin datos Russian Academy of Sciences Rusia Aportación de la UE Sin datos Dirección Tropinina ultica, 49 603600 Nizhny Novgorod Ver en el mapa Coste total Sin datos Russian Academy of Sciences Rusia Aportación de la UE Sin datos Dirección Institutsky Prospect 142432 Chernogolovka, Moscow district Ver en el mapa Coste total Sin datos TECHNION - ISRAEL INSTITUTE OF TECHNOLOGY Israel Aportación de la UE Sin datos Dirección Technion City HAIFA Ver en el mapa Coste total Sin datos University of Wales, Bangor Reino Unido Aportación de la UE Sin datos Dirección Deniol Road LL57 2UW Bangor Ver en el mapa Coste total Sin datos