Objective
The main objective of this research project is to elucidate the nature and structure of the intermediates involved in selected oxidizing systems based on peroxides (hydrogen peroxide or alkyl hydroperoxides) and transition metal ions in their highest oxidation state (i.e. Ti(IV), V(V), Cr(VI), Mo(VI), W(VI)). The mechanism of some processes will also be investigated.
The reactivity of a given couple Metal/peroxide is a function of the nature of the metal and of the peroxide, as well as of the ligands. Variation of the reactivity can be detected as a function both of the co-ordination sphere and of the solvation sphere. Appropriate correlations among spectroscopic and structural parameters with kinetic data determined in model reactions will be searched in order to understand and possibly predict the reactivity of peroxo-metal complexes on the basis of their structure.
The oxidation of unreactive substrates could be then achieved by carefully designing the structure of peroxo-metal species.
Fields of science (EuroSciVoc)
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Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
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Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
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Coordinator
35131 Padova
Italy
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.