Objective
The objectives of the project involve an experimental and theoretical study of influence of the structural factors on the tautomeric equilibrium, kinetics and mechanism of the sigma-tropic tautomerism (including superfast) in mollar systems with oxygen cation-accepting centers. The work plan comprises the synthesis of a series of stituted benzoylacetones, 4-nitrosophenols, 3- fluoroindophenols, 3-fluorobenzaurins and their organometallic derivatives in the laboratory of Prof. D.N.Kravtsov at A.N.Nesmeyanov Institute of Organo- Element Compounds, Moscow, Russia where expertise allready is available.
After synthesis and characterization, the aroylacetones and their organometallic derivatives will be studied in detail in the NMR group at the Institute of Bioorganic Chemistry, Minsk, Belarus using temperature dependent 2D-NMR spectroscopy by 200 MHz NMR spectrometer. stituted 4-nitrosophenols, 3- fluoroindophenols, 3-fluorobenzaurins and their organometallic derivatives will be investigated at the laboratory of Prof. A.S.Peregudov using 400 MHz NMR spectrometer adapted for a registration of the heavy metal NMR spectra. Here in particular dynamic NMR spectroscopy methods are widely used to study of dynamic processes in molles. The sensitivity problems will be overcome by studies of NMR spectra in the laboratory of Prof. P.E. Hansen at Department of Life Sciences and Chemistry, Roskilde University, Roskilde, Denmark. The calculation of a wide range of mollar properties of the compounds and studies of diffusion and spectral editing will be made in the laboratory of Prof. J.C. Lindon, Department of Chemistry, Birkbeck College, University of London, London, England. The expertise for all stages of this project exists in the laboratories in Roskilde, London, Moscow and Minsk.
The results of the joint investigation will be discussed in terms of the tautomeric preference and mechanism of tautomerism for organic and organometallic compounds to improve understanding of underlying reasons of the structural features of the compounds and the pliarities of tautomeric mechanisms which may be of benefit in future studies in pharmacology, environment protection and salvage.
Fields of science (EuroSciVoc)
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
CORDIS classifies projects with EuroSciVoc, a multilingual taxonomy of fields of science, through a semi-automatic process based on NLP techniques. See: The European Science Vocabulary.
This project has not yet been classified with EuroSciVoc.
Be the first one to suggest relevant scientific fields and help us improve our classification service
You need to log in or register to use this function
Programme(s)
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Multi-annual funding programmes that define the EU’s priorities for research and innovation.
Topic(s)
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Data not available
Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.
Call for proposal
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Data not available
Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.
Funding Scheme
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.
Data not available
Coordinator
4000 Roskilde
Denmark
The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.