Cement-based materials, properties, evolution, barrier functions

Deliverables

Manuscript for peer-reviewed publication on results generated within WP3
Detailed WP1 description of scientific work: compilation of partner descriptions with update of Appendix_B
Draft of the 4th and final project workshop proceedings

Draft of the 4th and final project Workshop proceedings

Planning on interaction with socio-political stakeholders
Report (with update) on basis for application to Safety Case

Report (with update) on Basis for application to Safety Case. This Report will be updated in Project month 36 and 48

Report on WP1 established experimental boundary conditions, experimental methods
State-of-art report related to WP2 topics (updated)
Planned dissemination of final results
Detailed WP3 description of scientific work: compilation of partner descriptions with update of Appendix_B
Final results and interpretation of the modelling by incorporating results from WP1&WP2 experiments

Final results and interpretation of the modelling by incorporating results from WP&WP2 experiments

Report on interaction with non-scientific stakeholder
Manuscript for peer-reviewed publication on results generated in WP1
Manuscript for peer-reviewed publication on results generated within WP2
State-of-art report related to WP2 topics (initial)
Draft of the 3rd Annual Project Workshop Proceedings
List of mobility measures and summary of the works undertaken
Report/Documentation of exchange of data between experimental and modelling WPs (with updating)

This deliverable will be updated in month 26, 38 and 48

State-of-art report related to WP1 topics (updated)
Consolidated plan for Upscaling Modelling Task
Agreement and documentation of systems to be studied (WP1)

Agreement and documentation of systems to be studied

Periodic management and activity reports

Periodic Management and activity Report. This deliverable will be updated in Project month 36 and 48

Draft of the 2nd Annual Project Workshop Proceedings
Preliminary results and interpretation of the modelling by incorporating results from WP1&WP2 experiments
Agreement and documentation of systems to be studied (WP2)

Agreement and documentation of systems to be studied

State-of-art report related to WP1 topics (initial)
Draft of the 1st Annual project Workshop Proceedings

Draft of the 1st Annual Workshop Proceedings

Review and definition of modelling approach to be followed in the project: scale of analysis, physico-chemical processes, software, HPC resources
Report on the Upscaling Modelling Task
Report on new data (sorption, speciation, solubility) for radionuclide retention generated in WP2 (with updating)

Report on new data (sorption, speciation, solubility) for radionuclide Retention generated in WP2 (with updating)

Report on the relevance of the outcome of Cebama for the Safety Case (Manuscript for peer-reviewed publication)
Detailed WP2 description of scientific work: compilation of partner descriptions with update of Appendix B
Minutes from 2nd Annual Workshop
Report on WP1 selected experimental materials to be used, including both new laboratory and aged in-situ samples
Communication Action Plan
Description of and results from the modelling of external lab and/or field experiments and industrial analogues

Description of and results from the modelling of external lab and/or field experiments and industrial analogues.

Final project reporting, dissemination, communication, training & education, ethical/socio-political/broader stakeholder involvement

Final project reporting, dissemination, communication, Training & education, ethical/socio-political/broader stakeholder involvement

Final Report (EUR)

Final Report (EUR). Lead beneficiaries for this deliverable are KIT and AMPHOS21

Preparation of a generic poster presenting the project
Press release
Set up project webpage and blog

Publications

Sorpce radia na vybrané cementové materiály/ Sorption of radium on cementitious materials (in Czech)

Author(s): Jana Kittnerová
Published in: 2017
Publisher: CTU in Prague, Faculty of Nuclear Sciences and Physical Engineering, Department of Nuclear Chemistry

Kinetics of low-pH cementitious materials in deep underground repository

Author(s): Schmidt, Luisa
Published in: Master’s Thesis at the Technical University of Munich, Department of Civil, Geo, and Environmental Engineering, Chair of Material Science and Testing, Issue 1st of May, 2018, 2018
Publisher: Technical University of Munich

Coupled thermo-hydro-chemical-mechanical models of the bentonite barrier in a HLW repository

Author(s): Mon A.
Published in: Issue September 2017, 2017
Publisher: UDC

Chemical behaviour of bentonite in the near field of the KBS-3V concept

Author(s): Itälä Aku
Published in: Issue 2018-11-20, 2018, ISBN 978-951-38-8670-7
Publisher: VTT Technical Research Centre of Finland

Comparison of experimental and modelled pore solutions of low-pH Ordinary Portland Cement based mix designs

Author(s): Vehmas, T, Leivo, M & Holt, Erika
Published in: XXIII Nordic Concrete Research Symposium,, Issue 21 - 23 August 2017, Aalborg, Denmark, 2017, Page(s) 11-14
Publisher: Nordic Concrete Federation

Cementitious leachates interaction with MX-80 bentonite in geological nuclear waste repository environment

Author(s): Vehmas T., Itälä, A., Heikola, T., Leivo, M., Holt E., Vuorio, M
Published in: 7th International conference on clays in natural and engineered barriers for radioactive waste confinement, Issue 24th-27th of September 2017, 2017
Publisher: Congrex Switzerland Ltd

Reactive Transport Modeling and Changes in Porosity at Reactive Interfaces in a HLW repository in Clay

Author(s): J. Samper, A Mon, L Montenegro, A Naves & J Fernández
Published in: Book of Abstracts - Eos Trans. American Geophysical Union GU, Fall Meeting, 2016
Publisher: American Geophysical Union

Coupled THCM numerical models of heating and hydration tests to study the interactions of OPC concrete with compacted FEBEX bentonite

Author(s): J. Samper, A. Mon, L. Montenegro, A. Naves, J Fernández, J. Cuevas, R. Fernández, M.J. Turrero, E. Torres
Published in: Book of Abstracts - VII International Conference on Clays in Natural and Engineered Barriers for Radioactive Waste Confinement, Issue 24-27 September 2017, 2017, Page(s) 17-19
Publisher: Clay Conference 2017

Long-term non-isothermal geochemical evolution of compacted bentonite, concrete and corrosion products in a HLW repository in clay

Author(s): A. Mon, J. Samper, L. Montenegro, A. Naves, J Fernández
Published in: Book of Abstracts - VII International Conference on Clays in Natural and Engineered Barriers for Radioactive Waste Confinement, Issue 24-27 September 2017, 2017
Publisher: Clay Conference 2017

Formation of magnesium sheet silicates as a consequence of the alkaline perturbation of a bentonite barrier

Author(s): Fernández, R., González-Santamaría, D.1, Angulo, M., Torres, E.2, Ruiz, A.I., Turrero, M.J. and Cuevas, J.
Published in: The 7th International Conference on Clays in Natural and Engineered Barriers for radioactive waste confinement, Issue 24-27 September 2017, 2017
Publisher: Book of abstracts

Concrete-bentonite interaction: comparing long-term laboratory tests (HB) and in situ experiments (FEBEX-DP)

Author(s): E. Torres, J. Cuevas, R. Fernández, A.I. Ruiz, A. Ortega, M. Angulo, M.C. Alonso, J.L. García-Calvo, M.J. Turrero
Published in: The 7th International Conference on Clays in Natural and Engineered Barriers for radioactive waste confinement, 2017
Publisher: Book of abstracts

Stable isotopes applied to the study of the concrete/bentonite interaction in the FEBEX in situ Test

Author(s): E. Torres, M.J. Turrero, A. Garralón, J. Cuevas, R. Fernández, A. Ortega, A.I. Ruiz
Published in: The 7th International Conference on Clays in Natural and Engineered Barriers for radioactive waste confinement., 2017
Publisher: Book of abstracts

SurfacE Reactivity Interface Experiments studying microscale concrete-bentonite interaction

Author(s): Daniel González-Santamaría, Raúl Fernández, Ana Isabel Ruiz, María Angulo, Almudena Ortega, Enrique Rodríguez, Jaime Cuevas
Published in: 16th INTERNATIONAL CLAY CONFERENCE, clay from the oceans to the space, Issue 17-21 July 2017, 2017
Publisher: Book of abstracts

An extended membrane polarization model for spectral induced polarization of low-pH cement and concrete

Author(s): A. Hördt, M. Bücker, P. Leroy, S. Huisman, E. Zimmermann, S. Gaboreau, F. Claret, H. Stebner
Published in: European Geosciences Union General Assembly 2018, 2018
Publisher: Book of abstracts

EVOLUTION OF MINERALOGY AND RADIONUCLIDE DIFFUSION ON PORTLANDTYPE CEMENTITIOUS MATERIALS DUE GEOCHEMICAL AND THERMAL EFFECTS

Author(s): Tomáš ROSENDORF, Radek ČERVINKA, Dušan VOPÁLKA, Petr VEČERNÍK
Published in: RadChem - 18th Radiochemical Conference, 2018
Publisher: Book of abstracts

Taking profit from molecular sensitivity on the macro scale: Application of PET for investigating transport processes in barrier material

Author(s): Johannes Kulenkampff
Published in: European Geosciences Union General Assembly 2018, Issue 8- 13 April 2018, 2018
Publisher: Proceedings

Experiments on a cement-clay interface and the impact on physical properties: The Dutch context

Author(s): D. Bykov, A. Sabău, Y. Yigittop, J. L. Kloosterman, R. J. M. Konings, J. C. L. Meeussen
Published in: Book of abstracts - 4th International Workshop on Mechanisms and Modelling of Waste/Cement Interactions, 2016, Page(s) 31
Publisher: PSI-EMPA-UBERN

Kinetic parameters for assessing the pH –evolution of low pH concrete

Author(s): Vehmas T., Leivo M., Holt E.
Published in: Book of abstracts - 4th International Workshop on Mechanisms and Modelling of Waste/Cement Interactions, 2016, Page(s) 27
Publisher: PSI-EMPA-UBERN

Impact of temperature on microstructure and transport properties of OPC paste / argilite interface

Author(s): P. Lalan, A. Dauzères, L. De Windt, D. Bartier, J. Sammaljärvi, I. Techer, V. Detilleux
Published in: Book of abstracts - 4th International Workshop on Mechanisms and Modelling of Waste/Cement Interactions, 2016, Page(s) 37
Publisher: PSI-EMPA-UBERN

Cemtex project: Understand the physico-chemical evolution of cementitious material in clayey environment at 70°C

Author(s): P. Lalan, A. Dauzères, L. De Windt, D. Bartier, J. Sammaljärvi, I. Techer
Published in: Book of abstracts - 4th International Workshop on Mechanisms and Modelling of Waste/Cement Interactions, 2016, Page(s) 38
Publisher: PSI-EMPA-UBERN

Changes in diffusion properties of cement paste induced by leaching and carbonation accounting for the effects of limestone fillers and water/powder ratio

Author(s): Phung, Q. T., Maes, N., Jacops, E., Jacques, D., De Schutter, G.
Published in: Book of abstracts - 4th International Workshop on Mechanisms and Modelling of Waste/Cement Interactions, 2016, Page(s) 98
Publisher: PSI-EMPA-UBERN

Interaction processes at the concrete-bentonite interface after 13 years exposure of febex-plug. Part I Concrete alteration

Author(s): MC Alonso, J.L. García-Calvo, J. Cuevas, M.J. Turrero, R. Fernández,E. Torres, A.I. Ruiz
Published in: Book of abstracts - 4th International Workshop on Mechanisms and Modelling of Waste/Cement Interactions, 2016, Page(s) 29
Publisher: PSI-EMPA-UBERN

Interaction processes at the concrete-bentonite interface after 13 years of FEBEX-Plug operation. Part II: Bentonite contact

Author(s): Cuevas, J., Ruiz, A.I. Fernández, R.Torres, E., Alonso, M.C., García-Calvo, J.L. Aparicio, A., Turrero, M.J.
Published in: Book of abstracts - 4th International Workshop on Mechanisms and Modelling of Waste/Cement Interactions, 2016, Page(s) 32
Publisher: PSI-EMPA-UBERN

Uptake and retention of safety relevant radionuclides in cementitious systems.

Author(s): Lange, S., Deissmann, G., Bosbach, D.
Published in: Book of abstracts - 4th International Workshop on Mechanisms and Modelling of Waste/Cement Interactions, 2016, Page(s) 68
Publisher: PSI-EMPA-UBERN

Solubility, hydrolysis and sorption of beryllium in cementitious systems

Author(s): GAONA, X., BÖTTLE, M., RABUNG, Th., ALTMAIER, M.
Published in: Book of abstracts - 4th International Workshop on Mechanisms and Modelling of Waste/Cement Interactions, 2016, Page(s) 57
Publisher: PSI-EMPA-UBERN

Predicting long term interactions between concrete and boom clay with a reactive transport model

Author(s): Meeussen, J. C. L., Koenen, M., Griffioen, J.
Published in: Book of abstracts - 4th International Workshop on Mechanisms and Modelling of Waste/Cement Interactions, 2016, Page(s) 41
Publisher: PSI-EMPA-UBERN

Coupling thermodynamic modelling of cement hydration with moisture transfer. Application to low-pH cement systems.

Author(s): A. Idiart, M. Laviña, J. Olmeda
Published in: International Symposium On Concrete Modelling, CONMOD2018, Issue August 2018, 2018
Publisher: RILEM

Reactive transport modelling of cement hydration and degradation. Application to USFD experiments

Author(s): M. Laviña, J. Olmeda, A. Idiart
Published in: Book of abstracts - 5th International Workshop on Mechanisms and Modelling of Waste / Cement Interactions, CEM2019, Issue March 2019, 2019
Publisher: KIT

Molybdenum adsorption onto cement pure phases. The role of C-S-H and AFm phases

Author(s): M. López-García, J. Olmeda, M. Grivé, P. Henoqc
Published in: Book of Abstracts - 5th International Workshop on Mechanisms and Modelling of Waste / Cement Interactions, Issue 25-27 March 2019, 2019
Publisher: KIT

Molybdenum retention onto cement pastes and cement hydrate pure phases 1

Author(s): M. López-García, M. Grivé, J. Olmeda, P. Henocq
Published in: 6th International Conference on the Chemistry and Migration Behaviour of Actinides and Fission Products in the Geosphere, Issue 10-15 September 2017, 2017
Publisher: Amphos 21

Benchmark of reactive transport models within CEBAMA: application to a concrete / clay interface

Author(s): A Idiart, M Laviña, V Montoya, G Kosakowski, B Cochepin, I Munier, J Samper, A Mon, L Montenegro, J Meeussen, G Deissmann, S Rohmen, J Poonoosamy
Published in: 9th European Commission Conference EURATOM Res. Training Radioactive Waste Management, EURADWASTE 2019, Issue June 2019, 2019
Publisher: EURADWASTE

Pore-scale reactive transport modeling of degradation processes in cementitious systems: Concept development based on the Lattice-Boltzmann approach

Author(s): S. Rohmen, A. Idiart, G. Deissmann, D. Bosbach
Published in: 9th International Conference on Porous Media & Annual Meeting, Interpore 2017, Issue May 2017, 2017
Publisher: Interpore

Reactive transport processes at a low-pH concrete / clay interface: a benchmark modelling study

Author(s): A Idiart, M Laviña, E Coene, V Montoya, G Kosakowski, B Cochepin, I Munier, J Samper, A Mon, J Meeussen, G Deissmann, S Rohmen, J Poonoosamy, D Vopálka
Published in: International Symposium On Cement-based Materials for Nuclear Wastes, NUWCEM 2018, Issue 24-26 October 2018, 2018
Publisher: SFEN

Coupled thermo-hydro-chemical-mechanical model of shotcrete-bentonite interaction in FEBEX in situ test

Author(s): Samper J., Mon A., Montenegro L.
Published in: Book of abstracts - 5th International Workshop on Mechanisms and Modelling of Waste / Cement Interactions, CEM2019, Issue March 2019, 2019
Publisher: KIT

Coupled themo-hyodro-chemical-mechanical model of laboratory mortar-bentonite interaction tests

Author(s): Samper, J., Mon A., Montenegro L.
Published in: Book of abstracts - 5th International Workshop on Mechanisms and Modelling of Waste / Cement Interactions, CEM2019, Issue March 2019, 2019
Publisher: KIT

Reactive transport numerical predictions of the interactions of the bentonite with the concrete plug of the FEBEX in situ test

Author(s): Samper, J., A. Mon, L. Montenegro
Published in: Book of Abstracts - VII International Conference on Clays in Natural and Engineered Barriers for Radioactive Waste Confinement, Issue 24-27 September 2017, 2017, Page(s) 514-515
Publisher: Clay Conference 2017

Non-isothermal reactive transport model of the geochemical interactions of compacted bentonite, concrete and corrosion products in a radioactive waste repository in clay

Author(s): Fernández, J., J. Samper, A. Mon, L. Montenegro
Published in: 45th IAH Congress. Groundwater and life, Issue 9-14 September 2018, 2018
Publisher: IAH Congress

Non-isothermal benchmark of interactions of concrete, bentonite and clay

Author(s): Mon A., Kosakowski G., Samper J., Montenegro L.
Published in: Book of Abstracts. International Workshop Subsurface Environmental Simulation Benchmarking Workshop V, A Coruña,, Issue October 2016, 2016, Page(s) 66-68, ISBN 978-84-617-5468-7
Publisher: Tórculo

Ground wáter composition in the interaction with low-pH OPC-SF based concretes

Author(s): M.C. Alonso, A. Fernandez and J.L. Garcia-Calvo
Published in: 3rd International Symposium on cement-based materials for nuclear wastes, Issue 2 years, 2019, Page(s) 48
Publisher: CEA and SFEN

Thermodynamic and crystallographic model for anion uptake by hydrated calcium aluminate (AFm): an example of molybdenum

Author(s): Nicolas C. M. Marty, Sylvain Grangeon, Erik Elkaïm, Christophe Tournassat, Clémence Fauchet, Francis Claret
Published in: Scientific Reports, Issue 8/1, 2018, ISSN 2045-2322
Publisher: Nature Publishing Group
DOI: 10.1038/s41598-018-26211-z

Deciphering mineralogical changes and carbonation development during hydration and ageing of a consolidated ternary blended cement paste

Author(s): Francis Claret, Sylvain Grangeon, Annick Loschetter, Christophe Tournassat, Wout De Nolf, Nicholas Harker, Faiza Boulahya, Stéphane Gaboreau, Yannick Linard, Xavier Bourbon, Alejandro Fernandez-Martinez, Jonathan Wright
Published in: IUCrJ, Issue 5/2, 2018, Page(s) 150-157, ISSN 2052-2525
Publisher: International Union of Crystallography (IUCr)
DOI: 10.1107/s205225251701836x

Exploring the electrical potential inside cylinders beyond the Debye-Hückel approximation: a computer code to solve the Poisson-Boltzmann equation for multivalent electrolytes

Author(s): Philippe Leroy, Alexis Maineult
Published in: Geophysical Journal International, 2018, ISSN 0956-540X
Publisher: Geological Society by Blackwell Scientific
DOI: 10.1093/gji/ggy124

Modeling the evolution of complex conductivity during calcite precipitation on glass beads

Author(s): Philippe Leroy, Shuai Li, Damien Jougnot, André Revil, Yuxin Wu
Published in: Geophysical Journal International, 2017, Page(s) ggx001, ISSN 0956-540X
Publisher: Geological Society by Blackwell Scientific
DOI: 10.1093/gji/ggx001

Long-term non-isothermal reactive transport model of compacted bentonite, concrete and corrosion products in a HLW repository in clay

Author(s): Alba Mon, Javier Samper, Luis Montenegro, Acacia Naves, Jesús Fernández
Published in: Journal of Contaminant Hydrology, Issue 197, 2017, Page(s) 1-16, ISSN 0169-7722
Publisher: Elsevier BV
DOI: 10.1016/j.jconhyd.2016.12.006

Low-pH cement mortar-bentonite perturbations in a small-scale pilot laboratory experiment

Author(s): D.E. González-Santamaría, M. Angulo, A.I. Ruiz, R. Fernández, A. Ortega, J. Cuevas
Published in: Clay Minerals, Issue 53/02, 2018, Page(s) 237-254, ISSN 0009-8558
Publisher: Mineralogical Society
DOI: 10.1180/clm.2018.16

Characterisation of a high pH cement backfill for the geological disposal of nuclear waste: The Nirex Reference Vault Backfill

Author(s): Vasconcelos, R.G.W.; Beaudoin, N.; Hamilton, A.; Hyatt, N.C.; Provis, J.L.; Corkhill, C.L.
Published in: Applied Geochemistry, 2018, ISSN 0883-2927
Publisher: Pergamon Press Ltd.

PREPUBLICATION: Dissolution kinetics of hydrated calcium aluminates (AFm-Cl) as a function of pH and at room temperature

Author(s): Marty, Nicolas C.M.1; Grangeon, Sylvain1; Lerouge, Catherine1; Warmont, Fabienne2; Rozenbaum, Olivier3; Conte, Thibaud1; Claret, Francis1
Published in: Mineralogical Magazine, 2016
Publisher: Mineralogical Society
DOI: 10.1180/minmag.2016.080.161

Coupled THCM model of a heating and hydration concrete-bentonite column test

Author(s): J. Samper, A. Mon, L. Montenegro, J. Cuevas, M.J. Turrero, A. Naves, R. Fernández, E. Torres
Published in: Applied Geochemistry, Issue 94, 2018, Page(s) 67-81, ISSN 0883-2927
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.apgeochem.2018.05.007

Uptake of 226Ra in cementitious systems: A complementary solution chemistry and atomistic simulation study

Author(s): Steve Lange, Piotr M. Kowalski, Milan Pšenička, Martina Klinkenberg, Stephan Rohmen, Dirk Bosbach, Guido Deissmann
Published in: Applied Geochemistry, Issue 96, 2018, Page(s) 204-216, ISSN 0883-2927
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.apgeochem.2018.06.015

Authigenic Clay Minerals from Interface Reactions of Concrete-Clay Engineered Barriers: A New Perspective on Mg-Clays Formation in Alkaline Environments

Author(s): Jaime Cuevas, Ana Ruiz, Raúl Fernández, Daniel González-Santamaría, María Angulo, Almudena Ortega, Elena Torres, María Turrero
Published in: Minerals, Issue 8/9, 2018, Page(s) 362, ISSN 2075-163X
Publisher: MDPI
DOI: 10.3390/min8090362

Stable isotopes applied to the study of the concrete/bentonite interaction in the FEBEX in situ test

Author(s): E. Torres, M.J. Turrero, A. Garralón, J. Cuevas, R. Fernández, A. Ortega, A.I. Ruíz
Published in: Applied Geochemistry, Issue 100, 2019, Page(s) 432-443, ISSN 0883-2927
Publisher: Pergamon Press Ltd.
DOI: 10.1016/j.apgeochem.2018.12.017

Investigating the Potential Barrier Function of Nanostructured Materials Formed in Engineered Barrier Systems (EBS) Designed for Nuclear Waste Isolation

Author(s): Jaime Cuevas, Ana Isabel Ruiz, Raúl Fernández
Published in: The Chemical Record, Issue 18/7-8, 2018, Page(s) 1065-1075
Publisher: UAM-biblioteca peer rev unformatted
DOI: 10.1002/tcr.201700094

Geochemical conditions for the formation of Mg silicates phases in bentonite and implications for radioactive waste disposal

Author(s): Fernández, Raúl; González-Santamaría, Daniel; Angulo, María; Torres, Elena; Ruiz, Ana Isabel; Turrero, María Jesús; Cuevas, Jaime
Published in: UAM_Biblioteca, 2018
Publisher: UAM-biblioteca peer rev unformatted

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