Skip to main content
Go to the home page of the European Commission (opens in new window)
English en
CORDIS - EU research results
CORDIS

Perovskite/GaAs hybrid structures: towards enhanced optoelectronic properties

Project description

Enhanced control over charge carriers could boost photodetection

Photodetectors are sensors that transform light into electrical signals. They are widely used and essential to applications in fields including optical communications, biomedical imaging and gas sensing. Hybrid halide perovskites have gotten tremendous attention for their application in solar cells and are now gaining momentum for use in other types of optoelectronics. With the support of the Marie Skłodowska-Curie Actions programme, the OPTOHYB project is characterising the photoluminescence and dynamic localisation of charge carriers in this new hybrid structure. This approach should lead to better control over the charge carriers’ localisation to enhance photodetection.

Objective

OPTOHYB focuses on studying the carrier localization (CL) in a new hybrid structure namely halide perovskites/GaAs for photodetection application. Understanding the CL phenomenon in this hybrid structure could provide insights towards enhancing/controlling the optoelectronic properties. The idea consists of detecting and controlling the CL in the hybrid heterojunction and orient it towards photodetection devices. The phenomenon can be generated, either, randomly by strain, composition, size, and diffusion fluctuations, or, controllably by doping. The CL affects the bandgap (creating band-tails states and optical transitions) which affects the carrier lifetime. The experimental treatment of the phenomenon will be performed optically by the mean of steady-state photoluminescence (PL) and the time-resolved photoluminescence (TRPL) to evaluate the CL signatures. The obtained results will be correlated with morphological and structural observations to qualitatively understand the luminescence mechanisms in the new hybrid structure. To realize OPTOHYB's goal, for the first time, a quantitative study by modeling the PL features and the decay time will be performed using the Localized State Ensemble model (LSE) and the generalized model for TRPL. The newly obtained parameters will allow the control of the CL's evolution versus the ex- and/or in-situ conditions. The successful execution of this proposal will create a new platform with controllable band-tail state formation and carriers dynamic related to the CL phenomenon. Therefore, slowing the charge carrier lifetime due to the carrier hopping between different states in the band-tail, which is beneficial for photodetection. Finally, the fabrication of a photodetector based on halide perovskites/GaAs heterostructure prototype will be performed. The efficiency of the prototype will be checked regarding the possible engineering of the CL and its effect on the prototype and the way on how we can exploit it.

Fields of science (EuroSciVoc)

Keywords

Programme(s)

Topic(s)

Funding Scheme

MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF)

See all projects funded under this funding scheme

Call for proposal

(opens in new window) H2020-MSCA-IF-2020

See all projects funded under this call

Coordinator

UNIVERSITA DEGLI STUDI DI PARMA
Net EU contribution
€ 107 170,80
Address
VIA UNIVERSITA 12
43121 PARMA
Italy
Region
Nord-Est Emilia-Romagna Parma
Activity type
Higher or Secondary Education Establishments
Links
Total cost
€ 107 170,80

Participants (1)