Innovative photocatalysts integrated in flow photoreactor systems for direct CO2 and H2O conversion into solar fuels

Informations projet

NEFERTITI

N° de convention de subvention: 101022202

DOI

10.3030/101022202

Projet clôturé

Date de signature de la CE 9 Avril 2021

Date de début 1 Juillet 2021

Date de fin 31 Decembre 2025

Financé au titre de

• SOCIETAL CHALLENGES - Secure, clean and efficient energy

Coût total

€ 4 312 287,50

Contribution de l’UE

€ 3 844 427,50

Coordonné par

ACONDICIONAMIENTO TARRASENSE ASSOCIACION
Spain

CORDIS fournit des liens vers les livrables publics et les publications des projets HORIZON.

Les liens vers les livrables et les publications des projets du 7e PC, ainsi que les liens vers certains types de résultats spécifiques tels que les jeux de données et les logiciels, sont récupérés dynamiquement sur OpenAIRE .

Livrables

Documents, reports (16)

Training mechanisms to enhance international collaboration

Guidelines adapted to design training courses in NEFERTITI to enhance international collaboration.

Preliminary report on the photocatalyst candidates: Synthesis conditions and photocatalytic activity evaluation

Synthesis characterization and evaluation of the proposed photocatalysts for syngas conversion into alcohols

Theoretical analysis of the best photocatalyst candidate for alcohols generation from syngas

Report on the modelling work for proposed photocatalysts based on TiO2 or FexOy combined with FTS catalysts.Deliverable subject to addressing IP (sensitive information might be removed before publication).

Training assessment

This deliverable summarises the results of the training activities and the quality assessment of the trainings, its results and its impact.

Project website, standard templates and supporting documents.

Establish the project website and provide initial materials to support internal and external communication activities

Theoretical analysis of the best photocatalyst candidate for the simultaneous conversion of CO2 and H2O into syngas

Report on the modelling work for proposed photocatalysts based on 2-D COFs and Au NPs and RuO2 NPs among others.Deliverable subject to addressing IP (sensitive information might be removed before publication).

Final Dissemination workshop on NEFERTITI technologies

Report about the execution and outputs of the final dissemination event (workshop).

Dissemination Plan and Communication Toolbox

Comprehensive dissemination plan and a report on the first large set of communication tools

List of potential photocatalysts for the alcohols generation from syngas

Report on possible FTS catalysts and metal oxides to be used as photocatalysts for the syngas formation

Validation data for ethanol production

Validation report of the fully integrated NEFERTITI system to produce ethanol, with data on throughput and catalysts efficiency and stability.Deliverable subject to addressing IP (sensitive information might be removed before publication).

Safety recommendations on the selection of the components to develop the new photocatalysts

Preliminary assessment report of the potential hazards of those components selected as candidates to be part of the final products developed in NEFERTITI project

Report on conditioning and CO2 solubilization in water

Selection of the methodology that will be used to increase the solubilization ratio of CO2 in water

PCFR1 optimised for syngas generation

Comprehensive report containing optimal reaction conditions for the continuous syngas generation.Deliverable subject to addressing IP (sensitive information might be removed before publication).

Best candidate materials' sustainability assessment

Best candidate materials will be analysed from the environmental, economic and social perspective.

List of potential 2D porous materials for the simultaneous photocatalytic conversion of CO2 and H2O into syngas

Report on possible 2D COFs materials to be used as photocatalysts for syngas formation

PCFR2 optimised for alcohols generation

Comprehensive report containing optimal reaction conditions for the continuous alcohols generation.Deliverable subject to addressing IP (sensitive information might be removed before publication).

Publications

Peer reviewed articles (10)

Stacking Effects on the Optoelectronic Properties of 2D Perylene-Zn-Porphyrin-Based COFs

Auteurs: Valentin Diez-Cabanes, Sergio de-la-Huerta-Sainz, Elisabeth Escamilla, Pedro A. Marcos, Alfredo Bol-Arreba, Kathryn McCarthy, Roberto González-Gómez, Santiago Aparicio, Pau Farràs
Publié dans: The Journal of Physical Chemistry C, Numéro 130, 2026, Page(s) 4451-4465, ISSN 1932-7447
Éditeur: American Chemical Society
DOI: 10.1021/acs.jpcc.5c08341

Insights into the Interfacial Charge Transfer Dynamics in Semiconductor–Molecular Catalyst Assemblies for Photo–Induced CO₂ Reduction

Auteurs: Tamal Chatterjee, Beatriu Domingo‐Tafalla, Pablo Ballester, Emilio Palomares
Publié dans: ChemElectroChem, Numéro 11, 2024, Page(s) e202300620, ISSN 2196-0216
Éditeur: Wiley-VCH GmbH
DOI: 10.1002/celc.202300620

Manganese–rhodium nanoparticles: Adsorption on titanium oxide surfaces and catalyst for syngas reactions

Auteurs: P. A. Marcos, N. Aguilar, S. Rozas, S. Martel, A. Bol, S. Aparicio
Publié dans: The Journal of Chemical Physics, Numéro 161, 2024, ISSN 0021-9606
Éditeur: American Institute of Physics
DOI: 10.1063/5.0215450

Desulfurization of thiosemicarbazones: the role of metal ions and biological implications

Auteurs: Alondra Jiménez-Pérez, Sandra Fernández-Fariña, Rosa Pedrido, Javier García-Tojal
Publié dans: JBIC Journal of Biological Inorganic Chemistry, Numéro 29, 2024, Page(s) 3-31, ISSN 1432-1327
Éditeur: Springer Science and Business Media LLC
DOI: 10.1007/s00775-023-02037-7

Progress in development of photocatalytic processes for synthesis of fuels and organic compounds under outdoor solar light

Auteurs: Alexey Galushchinskiy; Roberto González-Gómez; Kathryn McCarthy; Pau Farràs; Aleksandr Savateev
Publié dans: Energy & Fuels, Numéro 1, 2022, ISSN 0887-0624
Éditeur: American Chemical Society
DOI: 10.1021/acs.energyfuels.2c00178

Enhanced Photostability and Photoactivity of Ruthenium Polypyridyl-Based Photocatalysts by Covalently Anchoring Onto Reduced Graphene Oxide

Auteurs: Seán Hennessey, Roberto González-Gómez, Kathryn McCarthy, Christopher S. Burke, Camille Le Houérou, Nirod Kumar Sarangi, Patrick McArdle, Tia E. Keyes, Fabio Cucinotta, Pau Farràs
Publié dans: ACS Omega, Numéro 9, 2024, Page(s) 13872-13882, ISSN 2470-1343
Éditeur: ACS
DOI: 10.1021/acsomega.3c08800

Unravelling the Atomic Structure of a Metal‐Covalent Organic Framework Assembled from Ruthenium Metalloligands

Auteurs: Seán Hennessey, Roberto González‐Gómez, Nicolás Arisnabarreta, Anna Ciotti, Jing Hou, Nadezda V. Tarakina, Andrey Bezrukov, Kunal S. Mali, Michael Zaworotko, Steven De Feyter, Max García‐Melchor, Pau Farràs
Publié dans: Advanced Materials, Numéro 37, 2026, ISSN 0935-9648
Éditeur: United Nations Industrial Developement Organization
DOI: 10.1002/adma.202502155

Morphological Modulation and Performance Tuning of Perylene-Porphyrin-Based Covalent Organic Frameworks

Auteurs: Kathryn McCarthy, Roberto González-Gómez, Owen Woodford, Elizabeth A. Gibson, Fabio Cucinotta, Pau Farràs
Publié dans: ACS Omega, Numéro 11, 2026, Page(s) 22533-22538, ISSN 2470-1343
Éditeur: American Chemical Society (ACS)
DOI: 10.1021/acsomega.5c08275

Recent advances in the rational designing of metalloporphyrinoid-based CO2 reduction catalysts: From molecular structural tuning to the application in catalysis

Auteurs: Beatriu Domingo-Tafalla, Tamal Chatterjee, Emilio Palomares
Publié dans: Journal of Porphyrins and Phthalocyanines, Numéro 27, 2023, Page(s) 23-46, ISSN 1088-4246
Éditeur: Society of Porphyrins and Phthalocyanines
DOI: 10.1142/s1088424623300033

Electro- and Photoinduced Interfacial Charge Transfers in Nanocrystalline Mesoporous TiO₂ and TiO₂/Iron Porphyrin Sensitized Films under CO₂ Reduction Catalysis

Auteurs: Beatriu Domingo-Tafalla, Tamal Chatterjee, Federico Franco, Javier Perez Hernandez, Eugenia Martinez-Ferrero, Pablo Ballester, Emilio Palomares
Publié dans: ACS Applied Materials & Interfaces, Numéro volume 11, issue 15, 2023, Page(s) 14304-14315, ISSN 1944-8244
Éditeur: American Chemical Society
DOI: 10.1021/acsami.2c22458