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NOTsoQUANTUM: Realistic simulations of polaritonic chemistry

Project description

Simplified quantum-like simulations shed light on novel hybrid light–matter states

When molecular transitions interact strongly with confined electromagnetic fields, optical excitations known as molecular polaritons are formed. These polaritonic states can benefit the light absorption and emission processes in materials (molecular photophysical processes), yet the ways in which this happens are largely unknown. With the support of the Marie Skłodowska-Curie Actions programme, the NOTsoQUANTUM project is developing the framework to realistically simulate molecular polaritons. The ‘semi-quantum’ approach will enable simulations inaccessible with a full quantum description of light and matter, enhancing insight required for greater control in applications.

Objective

Polaritonic chemistry is an emerging field aiming to manipulate chemical dynamics and reactivity as well as material properties through the formation of polaritons. These are hybrid light-matter states emerging from the interaction between molecular transitions and confined light modes, leading to unique properties in the so-called strong coupling (SC) regime. Recent investigations have demonstrated several examples where polaritonic states prove beneficial to a variety of distinct processes, including the modification of nonadiabatic dynamics and molecular photophysical processes. Despite all the efforts placed into understanding how polaritons affect these processes, many unanswered questions still remain in the field. At the present time, the only way to achieve a deeper understanding on how to control the effect of polaritons in chemistry and predict new phenomena is to have a physically sound, accurate and low-cost methodology capable of including all key ingredients responsible for the formation of polaritons, while describing the dynamics of the light and matter entities on an equal footing. Such a framework remains to be explored, and this proposal precisely aims at developing the necessary methodology and simulate a realistic setup of molecular polaritons. The outcomes of this proposal will provide insight on the manipulation of chemical dynamics in polaritonic chemistry and additionally predict plausible modifications of photophysical processes. This will be possible by extending the Ehrenfest+R approach, a promising method for the simulation of coupled photon-molecular dynamics, to SC situations. Taking advantage of its ability to recover quantum effects of light-matter interactions with semiclassical dynamics, we will follow a “NOTsoQUANTUM” approach that will allow for feasible simulations which would otherwise be prohibitive with a full quantum description of both light and matter.

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Programme(s)

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Topic(s)

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Funding Scheme

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MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF)

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Call for proposal

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(opens in new window) H2020-MSCA-IF-2020

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Coordinator

UNIVERSIDAD AUTONOMA DE MADRID
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 245 732,16
Address
CALLE EINSTEIN 3 CIUDAD UNIV CANTOBLANCO RECTORADO
28049 MADRID
Spain

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Region
Comunidad de Madrid Comunidad de Madrid Madrid
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 245 732,16

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