Project description
Lighting the way to tailored design of novel photocatalysts
Catalysts speed the rate of chemical reactions without being consumed by them, making otherwise inefficient reactions feasible commercially or enhancing the yield of already feasible reactions. Photocatalysis relies on a catalyst to accelerate photochemical reactions. In the drive toward more sustainable chemistry, eco-friendly and cost-effective photocatalysis has a leading role to play. With the support of the Marie Skłodowska-Curie Actions programme, the MMOF4PPS project will investigate and characterise members of a highly promising family of photocatalysts to foster the engineering and optimisation of innovative new photocatalysts for the green transition.
Objective
Research and development on high performance (in terms of stability and robustness) and conceptually innovative catalysts is essential to answer the increasing demand of sustainable chemicals and to achieve the European goal of energy consumption reduction, energy security improvement and competitiveness.
In this regard multi-molecular catalyst with efficient electronic conductivity is emerging as a prominent research area. Mixed-metal metal organic frameworks (MM-MOFs) indeed exhibit excellent ability to deliver superior photocatalytic activity with improved temperature stability and robustness in harsh conditions, compared to homometallic systems. However, the understanding of these materials is still in its infancy. It is thus crucial to couple the synthesis of tailor-made multi-material systems with high-resolution characterization techniques and reliable surface science models, to obtain a deep understanding of emergent chemical and physical phenomena that are otherwise inaccessible with a single material catalyst.
The main objectives and actions of MMOF4PPS will thus be to: (a) explore and optimize synthetic procedures for MM-MOFs, (b) decipher the ultrafast photo-processes inside MM-MOFs, (c) study the effect of varying ratio of metal clusters on the photocatalytic performance, (d) gain detailed knowledge of the effectiveness of MM-MOFs over single metal MOFs in photocatalysis and (e) develop structure–(photocatalytic) activity relationship.
Such information represents a steppingstone for the optimization and acceleration in the development of sustainable catalysis, and is thus expected to have significant industrial and socio-economic impacts.
In addition, both experienced researcher and host will benefit from establishing interdisciplinary research and deliver research excellence to academia and industry.
Fields of science
Programme(s)
Funding Scheme
MSCA-IF - Marie Skłodowska-Curie Individual Fellowships (IF)Coordinator
13071 Ciudad Real
Spain