Chirality and spin selectivity in electron transfer processes: from quantum detection to quantum enabled technologies

Project Information

CASTLE

Grant agreement ID: 101071533

DOI

10.3030/101071533

EC signature date 22 November 2022

Start date 1 January 2023

End date 31 December 2028

Funded under

• European Research Council (ERC)

Total cost

€ 8 976 957,00

EU contribution

€ 8 976 957,00

Coordinated by

UNIVERSITA DEGLI STUDI DI FIRENZE
Italy

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (23)

Chirality Versus Symmetry: Electron's Spin Selectivity in Nonpolar Chiral Lead–Bromide Perovskites

Author(s): A. Abhervé, N. Mercier, A. Kumar, T. K. Das, J. Even, C. Katan and M. Kepenekian
Published in: Advanced Materials, 2023, ISSN 0935-9648
Publisher: John Wiley & Sons, Ltd
DOI: 10.1002/adma.202305784

Journal of the American Chemical Society

Author(s): H. J. Eckvahl, G. Copley, R. M. Young, M. D. Krzyaniak and M. R. Wasielewski
Published in: Journal of the American Chemical Society, 2024, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.4c08706

Metalloporphyrins as Building Blocks for Quantum Information Science

Author(s): Fabio Santanni; Alberto Privitera
Published in: Advanced Optical Materials, 2024, ISSN 2195-1071
Publisher: Wiley
DOI: 10.1002/adom.202303036

Spin polarized current in chiral organic radical monolayers

Author(s): Giaconi, Niccolò; Lupi, Michela; Das, Tapan Kumar; Kumar, Anil; Poggini, Lorenzo; Viglianisi, Caterina; Sorace, Lorenzo; Menichetti, Stefano; Naaman, Ron; Sessoli, Roberta; Mannini, Matteo
Published in: Journal of Material Chemistry C, Issue 12, 2024, ISSN 2050-7526
Publisher: Royal Society of Chemistry , UK
DOI: 10.1039/D4TC00944D

Ab initio parametrization of a generalized Hubbard model in a molecule displaying chirality-induced spin selectivity

Author(s): D. K. Andrea Phan Huu, Arianna Cantarella, Pietro Bonfà, Lorenzo Savi, Alessandro Chiesa, Anna Painelli, Stefano Carretta
Published in: Communications Materials, Issue 6, 2025, ISSN 2662-4443
Publisher: Springer Science and Business Media LLC
DOI: 10.1038/S43246-025-00821-3

Chirality-Induced Spin Selectivity: A Minimal Model

Author(s): Lorenzo Savi, Leonardo Celada, D.K. Andrea Phan Huu, Alessandro Chiesa, Stefano Carretta, Anna Painelli
Published in: The Journal of Physical Chemistry Letters, Issue 16, 2025, ISSN 1948-7185
Publisher: American Chemical Society (ACS)
DOI: 10.1021/ACS.JPCLETT.5C01813

Dual structure of a vanadyl-based molecular qubit containing a bis(beta-diketonato) ligand

Author(s): Manuel Imperato, Alessio Nicolini, Matteo Boniburini, Daniele Sartini, Enrico Benassi, Mario Chiesa, Lara Gigli, Yu-Kai Liao, Arsen Raza, Enrico Salvadori, Lorenzo Sorace, Andrea Cornia
Published in: Inorganic Chemistry, 2024, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.5281/zenodo.13362609

Chirality-Induced Spin Selectivity at the Molecular Level: A Different Perspective to Understand and Exploit the Phenomenon

Author(s): Alessandro Chiesa, Alberto Privitera, Elena Garlatti, Giuseppe Allodi, Robert Bittl, Michael R. Wasielewski, Roberta Sessoli, Stefano Carretta
Published in: The Journal of Physical Chemistry Letters, Issue 16, 2025, ISSN 1948-7185
Publisher: American Chemical Society (ACS)
DOI: 10.1021/ACS.JPCLETT.5C00755

Chiral-induced spin selectivity in photo-induced electron transfer: Investigating charge and spin dynamics in a master equation framework

Author(s): Emilio Macaluso; Alessandro Chiesa; Paolo Santini; Robert Bittl; Stefano Carretta
Published in: The Journal of Chemical Physics, 2023, ISSN 1089-7690
Publisher: American Institute of Physics
DOI: 10.17169/refubium-40304

Oxovanadium(IV) Thiocarboxylate Paddlewheels Containing Ancillary Group 10 Metals: A Comparative Study on Pd and Pt Derivatives

Author(s): Olga Mironova, Giacomo Bellini, Alessio Nicolini, Manuel Imperato, Antonio Ranieri, Marco Borsari, Matteo Briganti, Rodolphe Clérac, Mathieu Rouzières, Enrico Salvadori, Maria Chiara Pagliero, Mario Chiesa, Andrea Cornia
Published in: Inorganic Chemistry, Issue 65, 2025, ISSN 0020-1669
Publisher: American Chemical Society (ACS)
DOI: 10.5281/ZENODO.17865582

Molecular nanomagnets: a viable path toward quantum information processing?

Author(s): A. Chiesa, P. Santini, E. Garlatti, F. Luis, S. Carretta
Published in: Reports on Progress in Physics, 2024, ISSN 1361-6633
Publisher: IOP Publishing
DOI: 10.1088/1361-6633/ad1f81

A Lewis Base Hydrogen Bond Donor (LB/HBD) Organocatalytic Approach to Dithiabridged Triarylamine Hetero[4]helicenes

Author(s): M. Lupi, O. Salmi, C. Viglianisi and S. Menichetti
Published in: Advanced Synthesis & Catalysis, 2023, ISSN 1615-4150
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/adsc.202300238

Chirality‐Induced Spin Selectivity: An Enabling Technology for Quantum Applications

Author(s): Chiesa, Alessandro; Privitera, Alberto; Macaluso, Emilio; Mannini, Matteo; Bittl, Robert; Naaman, Ron; Wasielewski, Michael R.; Sessoli, Roberta; Carretta, Stefano
Published in: Advanced Materials, 2023, ISSN 1521-4095
Publisher: Wiley, Wiley-VCH
DOI: 10.17169/refubium-40306

Many-Body Models for Chirality-Induced Spin Selectivity in Electron Transfer

Author(s): A. Chiesa, E. Garlatti, M. Mezzadri, L. Celada, R. Sessoli, M. R. Wasielewski, R. Bittl, P. Santini, S. Carretta
Published in: Nano Letters, 2024, ISSN 1530-6984
Publisher: American Chemical Society
DOI: 10.48550/arXiv.2406.15135

Journal of the American Chemical Society

Author(s): Alberto Privitera; Alessandro Chiesa; Fabio Santanni; Angelo Carella; Davide Ranieri; Andrea Caneschi; Matthew D. Krzyaniak; Ryan M. Young; Michael R. Wasielewski; Stefano Carretta; Roberta Sessoli
Published in: Journal of the American Chemical Society, 2025, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/JACS.4C10632

Efficient Spin-Selective Electron Transport at Low Voltages of Thia-Bridged Triarylamine Hetero[4]helicenes Chemisorbed Monolayer

Author(s): N. Giaconi, L. Poggini, M. Lupi, M. Briganti, A. Kumar, T. K. Das, A. L. Sorrentino, C. Viglianisi, S. Menichetti, R. Naaman, R. Sessoli and M. Mannini
Published in: ACS Nano, 2023, ISSN 1936-0851
Publisher: American Chemical Society
DOI: 10.1021/acsnano.3c04878

Direct observation of chirality-induced spin selectivity in electron donor–acceptor molecules

Author(s): Hannah J. Eckvahl; Nikolai A. Tcyrulnikov; Alessandro Chiesa; Jillian M. Bradley; Ryan M. Young; Stefano Carretta; Matthew D. Krzyaniak; Michael R. Wasielewski
Published in: Science, 2023, ISSN 1095-9203
Publisher: merican Association for the Advancement of Science
DOI: 10.48550/arxiv.2311.03599

Multiple Dimerization Modes in Thiocarboxylate Paddlewheel Complexes: A Comprehensive View of Energy Landscapes from DFT Calculations and Statistics

Author(s): Olga Mironova, Giacomo Bellini, Alessio Nicolini, Andrea Cornia
Published in: Chemistry – A European Journal, 2025, ISSN 0947-6539
Publisher: Wiley
DOI: 10.5281/ZENODO.17793316

Organic and Biomolecular Chemistry

Author(s): M. Lupi, M. Fabbri, G. Mazzeo, G. Longhi, S. Abbate, C. Viglianisi and S. Menichetti
Published in: Organic & Biomolecular Chemistry, 2024, ISSN 1477-0520
Publisher: Royal Society of Chemistry
DOI: 10.1039/D4OB00979G

Detecting chirality-induced spin selectivity in chromophore-linked DNA hairpins using photogenerated radical pairs

Author(s): Elisabeth I. Latawiec, Alessandro Chiesa, Yunfan Qiu, Nikolai A. Tcyrulnikov, Ryan M. Young, Stefano Carretta, Matthew D. Krzyaniak, Michael R. Wasielewski
Published in: Proceedings of the National Academy of Sciences, Issue 122, 2025, ISSN 0027-8424
Publisher: Proceedings of the National Academy of Sciences
DOI: 10.1073/PNAS.2515120122

Quantum spin coherence and electron spin distribution channels in vanadyl-containing lantern complexes

Author(s): Manuel Imperato, Alessio Nicolini, Marco Borsari, Matteo Briganti, Mario Chiesa, Yu-Kai Liao, Antonio Ranieri, Arsen Raza, Enrico Salvadori, Lorenzo Sorace, Andrea Cornia
Published in: Inorganic Chemistry Frontiers, 2023, ISSN 2052-1545
Publisher: Royal Sociaty of Chemistry
DOI: 10.1039/d3qi01806g

Challenges in the Direct Detection of Chirality‐induced Spin Selectivity: Investigation of Foldamer‐based Donor‐acceptor Dyads

Author(s): Privitera, Alberto; Faccio, Davide; Giuri, Demetra; Latawiec, Elisabeth I.; Genovese, Damiano; Tassinari, Francesco; Mummolo, Liviana; Chiesa, Mario; FONTANESI, Claudio; Salvadori, Enrico; Cornia, Andrea; Wasielewski, Michael; Claudia, Tomasini; Sessoli, Roberta
Published in: Chemistry- A European Journal, 2023, ISSN 1521-3765
Publisher: Wiley, Wiley-VCH
DOI: 10.1002/chem.202301005

Weak Exchange Interactions in Multispin Systems: EPR Studies of Metalloporphyrins Decorated with {Cr7Ni} Rings

Author(s): F. Santanni, E. Little, S. J. Lockyer, G. F. S. Whitehead, E. J. L. McInnes, G. A. Timco, A. M. Bowen, R. Sessoli and R. E. P. Winpenny
Published in: Inorganic Chemistry, 2024, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c01248