Chirality and spin selectivity in electron transfer processes: from quantum detection to quantum enabled technologies

Información del proyecto

CASTLE

Identificador del acuerdo de subvención: 101071533

DOI

10.3030/101071533

Fecha de la firma de la CE 22 Noviembre 2022

Fecha de inicio 1 Enero 2023

Fecha de finalización 31 Diciembre 2028

Financiado con arreglo a

• European Research Council (ERC)

Coste total

€ 8 976 957,00

Aportación de la UE

€ 8 976 957,00

Coordinado por

UNIVERSITA DEGLI STUDI DI FIRENZE
Italy

CORDIS proporciona enlaces a los documentos públicos y las publicaciones de los proyectos de los programas marco HORIZONTE.

Los enlaces a los documentos y las publicaciones de los proyectos del Séptimo Programa Marco, así como los enlaces a algunos tipos de resultados específicos, como conjuntos de datos y «software», se obtienen dinámicamente de OpenAIRE .

Publicaciones

Peer reviewed articles (32)

Chirality Versus Symmetry: Electron's Spin Selectivity in Nonpolar Chiral Lead–Bromide Perovskites

Autores: A. Abhervé, N. Mercier, A. Kumar, T. K. Das, J. Even, C. Katan and M. Kepenekian
Publicado en: Advanced Materials, 2023, ISSN 0935-9648
Editor: John Wiley & Sons, Ltd
DOI: 10.1002/adma.202305784

Journal of the American Chemical Society

Autores: H. J. Eckvahl, G. Copley, R. M. Young, M. D. Krzyaniak and M. R. Wasielewski
Publicado en: Journal of the American Chemical Society, 2024, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/jacs.4c08706

Metalloporphyrins as Building Blocks for Quantum Information Science

Autores: Fabio Santanni; Alberto Privitera
Publicado en: Advanced Optical Materials, 2024, ISSN 2195-1071
Editor: Wiley
DOI: 10.1002/adom.202303036

Spin polarized current in chiral organic radical monolayers

Autores: Giaconi, Niccolò; Lupi, Michela; Das, Tapan Kumar; Kumar, Anil; Poggini, Lorenzo; Viglianisi, Caterina; Sorace, Lorenzo; Menichetti, Stefano; Naaman, Ron; Sessoli, Roberta; Mannini, Matteo
Publicado en: Journal of Material Chemistry C, Edición 12, 2024, ISSN 2050-7526
Editor: Royal Society of Chemistry , UK
DOI: 10.1039/D4TC00944D

Ab initio parametrization of a generalized Hubbard model in a molecule displaying chirality-induced spin selectivity

Autores: D. K. Andrea Phan Huu, Arianna Cantarella, Pietro Bonfà, Lorenzo Savi, Alessandro Chiesa, Anna Painelli, Stefano Carretta
Publicado en: Communications Materials, Edición 6, 2025, ISSN 2662-4443
Editor: Springer Science and Business Media LLC
DOI: 10.1038/S43246-025-00821-3

Chirality-Induced Spin Selectivity: A Minimal Model

Autores: Lorenzo Savi, Leonardo Celada, D.K. Andrea Phan Huu, Alessandro Chiesa, Stefano Carretta, Anna Painelli
Publicado en: The Journal of Physical Chemistry Letters, Edición 16, 2025, ISSN 1948-7185
Editor: American Chemical Society (ACS)
DOI: 10.1021/ACS.JPCLETT.5C01813

Dual structure of a vanadyl-based molecular qubit containing a bis(beta-diketonato) ligand

Autores: Manuel Imperato, Alessio Nicolini, Matteo Boniburini, Daniele Sartini, Enrico Benassi, Mario Chiesa, Lara Gigli, Yu-Kai Liao, Arsen Raza, Enrico Salvadori, Lorenzo Sorace, Andrea Cornia
Publicado en: Inorganic Chemistry, 2024, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.5281/zenodo.13362609

Detecting Chirality-Induced Spin Selectivity in Randomly Oriented Radical Pairs Photogenerated by Hole Transfer

Autores: Hannah J. Eckvahl, Graeme Copley, Ryan M. Young, Matthew D. Krzyaniak, Michael R. Wasielewski
Publicado en: Journal of the American Chemical Society, Edición 146, 2024, ISSN 0002-7863
Editor: American Chemical Society (ACS)
DOI: 10.1021/JACS.4C08706

Light-Activated Qubit Coupling in a Vanadyl Porphyrin Trimer

Autores: Alberto Privitera, Alessandro Chiesa, Fabio Santanni, Davide Ranieri, Prem P. Sahu, Matthew D. Krzyaniak, Andrea Caneschi, Ryan M. Young, Mathias O. Senge, Federico Totti, Michael R. Wasielewski, Stefano Carretta, Roberta Sessoli
Publicado en: Journal of the American Chemical Society, Edición 148, 2026, ISSN 0002-7863
Editor: American Chemical Society (ACS)
DOI: 10.1021/JACS.5C17205

Chirality-Induced Spin Selectivity at the Molecular Level: A Different Perspective to Understand and Exploit the Phenomenon

Autores: Alessandro Chiesa, Alberto Privitera, Elena Garlatti, Giuseppe Allodi, Robert Bittl, Michael R. Wasielewski, Roberta Sessoli, Stefano Carretta
Publicado en: The Journal of Physical Chemistry Letters, Edición 16, 2025, ISSN 1948-7185
Editor: American Chemical Society (ACS)
DOI: 10.1021/ACS.JPCLETT.5C00755

Chiral-induced spin selectivity in photo-induced electron transfer: Investigating charge and spin dynamics in a master equation framework

Autores: Emilio Macaluso; Alessandro Chiesa; Paolo Santini; Robert Bittl; Stefano Carretta
Publicado en: The Journal of Chemical Physics, 2023, ISSN 1089-7690
Editor: American Institute of Physics
DOI: 10.17169/refubium-40304

Conclusive Insight into the Coordination Complexes of a Flexible Bis(β‐diketonato) Ligand and Their Phase‐Dependent Structure: A Multi‐Technique Approach

Autores: Manuel Imperato; Alessio Nicolini; Olga Mironova; Enrico Benassi; Nicola Demitri; Lara Gigli; Adele Mucci; Andrea Cornia
Publicado en: Chemistry – A European Journal, 2025, ISSN 1521-3765
Editor: Wiley, Wiley-VCH
DOI: 10.1002/CHEM.202500697

Oxovanadium(IV) Thiocarboxylate Paddlewheels Containing Ancillary Group 10 Metals: A Comparative Study on Pd and Pt Derivatives

Autores: Olga Mironova, Giacomo Bellini, Alessio Nicolini, Manuel Imperato, Antonio Ranieri, Marco Borsari, Matteo Briganti, Rodolphe Clérac, Mathieu Rouzières, Enrico Salvadori, Maria Chiara Pagliero, Mario Chiesa, Andrea Cornia
Publicado en: Inorganic Chemistry, Edición 65, 2025, ISSN 0020-1669
Editor: American Chemical Society (ACS)
DOI: 10.5281/ZENODO.17865582

Room-Temperature Optical Spin Polarization of an Electron Spin Qudit in a Vanadyl-Free Base Porphyrin Dimer

Autores: Alberto Privitera, Alessandro Chiesa, Fabio Santanni, Angelo Carella, Davide Ranieri, Andrea Caneschi, Matthew D. Krzyaniak, Ryan M. Young, Michael R. Wasielewski, Stefano Carretta, Roberta Sessoli
Publicado en: Journal of the American Chemical Society, Edición 147, 2025, ISSN 0002-7863
Editor: American Chemical Society (ACS)
DOI: 10.1021/JACS.4C10632

Molecular nanomagnets: a viable path toward quantum information processing?

Autores: A. Chiesa, P. Santini, E. Garlatti, F. Luis, S. Carretta
Publicado en: Reports on Progress in Physics, 2024, ISSN 1361-6633
Editor: IOP Publishing
DOI: 10.1088/1361-6633/ad1f81

A Lewis Base Hydrogen Bond Donor (LB/HBD) Organocatalytic Approach to Dithiabridged Triarylamine Hetero[4]helicenes

Autores: M. Lupi, O. Salmi, C. Viglianisi and S. Menichetti
Publicado en: Advanced Synthesis & Catalysis, 2023, ISSN 1615-4150
Editor: John Wiley & Sons Ltd.
DOI: 10.1002/adsc.202300238

Chirality‐Induced Spin Selectivity: An Enabling Technology for Quantum Applications

Autores: Chiesa, Alessandro; Privitera, Alberto; Macaluso, Emilio; Mannini, Matteo; Bittl, Robert; Naaman, Ron; Wasielewski, Michael R.; Sessoli, Roberta; Carretta, Stefano
Publicado en: Advanced Materials, 2023, ISSN 1521-4095
Editor: Wiley, Wiley-VCH
DOI: 10.17169/refubium-40306

Many-Body Models for Chirality-Induced Spin Selectivity in Electron Transfer

Autores: A. Chiesa, E. Garlatti, M. Mezzadri, L. Celada, R. Sessoli, M. R. Wasielewski, R. Bittl, P. Santini, S. Carretta
Publicado en: Nano Letters, 2024, ISSN 1530-6984
Editor: American Chemical Society
DOI: 10.48550/arXiv.2406.15135

Spin-selective charge transfer pathways in photoexcited helicene-perylenediimide dyads

Autores: Giulia Agnoloni, Angelo Carella, Jakob K. Staab, Maksim Arsentev, Michela Lupi, Stefano Menichetti, Caterina Viglianisi, Ryan M. Young, Federico Totti, Michael R. Wasielewski, Alberto Privitera, Roberta Sessoli
Publicado en: Journal of Materials Chemistry C, Edición 14, 2026, ISSN 2050-7526
Editor: Royal Society of Chemistry (RSC)
DOI: 10.1039/D6TC01492E

The Role of Chirality-Induced Spin Selectivity in Helicene-Based Photogenerated Radical Pairs

Autores: Giulia Agnoloni, Alessandro Chiesa, Ryan M. Young, Federico Totti, Stefano Menichetti, Caterina Viglianisi, Michael R. Wasielewski, Stefano Carretta, Alberto Privitera, Roberta Sessoli
Publicado en: Journal of the American Chemical Society, Edición 148, 2026, ISSN 0002-7863
Editor: American Chemical Society (ACS)
DOI: 10.1021/JACS.6C02634

Journal of the American Chemical Society

Autores: Alberto Privitera; Alessandro Chiesa; Fabio Santanni; Angelo Carella; Davide Ranieri; Andrea Caneschi; Matthew D. Krzyaniak; Ryan M. Young; Michael R. Wasielewski; Stefano Carretta; Roberta Sessoli
Publicado en: Journal of the American Chemical Society, 2025, ISSN 0002-7863
Editor: American Chemical Society
DOI: 10.1021/JACS.4C10632

Vibrationally Mediated Dzyaloshinskii-Moriya Interactionas the Origin of Chirality-Induced Spin Selectivity in Donor–AcceptorMolecules

Autores: Alessandro Chiesa, D. K. Andrea Phan Huu, Arianna Cantarella, Leonardo Celada, Michael R. Wasielewski, Paolo Santini, Stefano Carretta
Publicado en: Nano Letters, Edición 26, 2026, ISSN 1530-6984
Editor: American Chemical Society (ACS)
DOI: 10.1021/ACS.NANOLETT.6C01653

Efficient Spin-Selective Electron Transport at Low Voltages of Thia-Bridged Triarylamine Hetero[4]helicenes Chemisorbed Monolayer

Autores: N. Giaconi, L. Poggini, M. Lupi, M. Briganti, A. Kumar, T. K. Das, A. L. Sorrentino, C. Viglianisi, S. Menichetti, R. Naaman, R. Sessoli and M. Mannini
Publicado en: ACS Nano, 2023, ISSN 1936-0851
Editor: American Chemical Society
DOI: 10.1021/acsnano.3c04878

Direct observation of chirality-induced spin selectivity in electron donor–acceptor molecules

Autores: Hannah J. Eckvahl; Nikolai A. Tcyrulnikov; Alessandro Chiesa; Jillian M. Bradley; Ryan M. Young; Stefano Carretta; Matthew D. Krzyaniak; Michael R. Wasielewski
Publicado en: Science, 2023, ISSN 1095-9203
Editor: merican Association for the Advancement of Science
DOI: 10.48550/arxiv.2311.03599

Multiple Dimerization Modes in Thiocarboxylate Paddlewheel Complexes: A Comprehensive View of Energy Landscapes from DFT Calculations and Statistics

Autores: Olga Mironova, Giacomo Bellini, Alessio Nicolini, Andrea Cornia
Publicado en: Chemistry – A European Journal, 2025, ISSN 0947-6539
Editor: Wiley
DOI: 10.5281/ZENODO.17793316

Circularly Polarized Luminescence and Photoinduced Spin Polarization in Helicene-Bis-TEMPO Diradicals

Autores: Stefano Cadeddu, Rituparno Chowdhury, Chiara Delpiano Cordeiro, Saurav Parmar, Augusta Kramer, Marie Cordier, Anne Pensel, Nicolas Vanthuyne, Roberta Sessoli, Mario Chiesa, Yu-Kai Liao, Richard H. Friend, Enrico Salvadori, Jochen Autschbach, Jeanne Crassous
Publicado en: Journal of the American Chemical Society, Edición 147, 2025, ISSN 0002-7863
Editor: American Chemical Society (ACS)
DOI: 10.1021/JACS.5C04887

Organic and Biomolecular Chemistry

Autores: M. Lupi, M. Fabbri, G. Mazzeo, G. Longhi, S. Abbate, C. Viglianisi and S. Menichetti
Publicado en: Organic & Biomolecular Chemistry, 2024, ISSN 1477-0520
Editor: Royal Society of Chemistry
DOI: 10.1039/D4OB00979G

Detecting chirality-induced spin selectivity in chromophore-linked DNA hairpins using photogenerated radical pairs

Autores: Elisabeth I. Latawiec, Alessandro Chiesa, Yunfan Qiu, Nikolai A. Tcyrulnikov, Ryan M. Young, Stefano Carretta, Matthew D. Krzyaniak, Michael R. Wasielewski
Publicado en: Proceedings of the National Academy of Sciences, Edición 122, 2025, ISSN 0027-8424
Editor: Proceedings of the National Academy of Sciences
DOI: 10.1073/PNAS.2515120122

Quantum spin coherence and electron spin distribution channels in vanadyl-containing lantern complexes

Autores: Manuel Imperato, Alessio Nicolini, Marco Borsari, Matteo Briganti, Mario Chiesa, Yu-Kai Liao, Antonio Ranieri, Arsen Raza, Enrico Salvadori, Lorenzo Sorace, Andrea Cornia
Publicado en: Inorganic Chemistry Frontiers, 2023, ISSN 2052-1545
Editor: Royal Sociaty of Chemistry
DOI: 10.1039/d3qi01806g

Efficient Chirality-Induced Spin Selectivity in Self-Assembled Monolayers of Ru ₂ ⁵ ⁺ Paddlewheel Complexes

Autores: Isabel Coloma, Niccolò Giaconi, Francesco Parmeggiani, Thierry Buffeteau, Gilles Pécastaings, Santiago Herrero, Elizabeth A. Hillard, Patrick Rosa, Lorenzo Poggini, Matteo Mannini, Miguel Cortijo, Mathieu Gonidec
Publicado en: Journal of the American Chemical Society, Edición 148, 2026, ISSN 0002-7863
Editor: American Chemical Society (ACS)
DOI: 10.1021/JACS.6C02811

Challenges in the Direct Detection of Chirality‐induced Spin Selectivity: Investigation of Foldamer‐based Donor‐acceptor Dyads

Autores: Privitera, Alberto; Faccio, Davide; Giuri, Demetra; Latawiec, Elisabeth I.; Genovese, Damiano; Tassinari, Francesco; Mummolo, Liviana; Chiesa, Mario; FONTANESI, Claudio; Salvadori, Enrico; Cornia, Andrea; Wasielewski, Michael; Claudia, Tomasini; Sessoli, Roberta
Publicado en: Chemistry- A European Journal, 2023, ISSN 1521-3765
Editor: Wiley, Wiley-VCH
DOI: 10.1002/chem.202301005

Weak Exchange Interactions in Multispin Systems: EPR Studies of Metalloporphyrins Decorated with {Cr7Ni} Rings

Autores: F. Santanni, E. Little, S. J. Lockyer, G. F. S. Whitehead, E. J. L. McInnes, G. A. Timco, A. M. Bowen, R. Sessoli and R. E. P. Winpenny
Publicado en: Inorganic Chemistry, 2024, ISSN 0020-1669
Editor: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c01248