Perovskite solar cells with enhanced stability and applicability

Project Information

VALHALLA

Grant agreement ID: 101082176

DOI

10.3030/101082176

Project closed

EC signature date 20 September 2022

Start date 1 January 2023

End date 31 December 2025

Funded under

• Climate, Energy and Mobility

Total cost

€ 3 877 396,50

EU contribution

€ 3 877 396,50

Coordinated by

UNIVERSITAT DE VALENCIA
Spain

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Deliverables

Documents, reports (3)

Identify accelerated stress conditions that lead to similar degradation as in real life outdoor stress conditions

In this deliverable we will give guidelines on how to stress perovskite solar cells in indoor conditions such that the results on degradation are meaningfull to predict the stability of these cells in outdoor (real world) conditions.This deliverable is related to tasks 4.1

Ethics assesment of the consortium

We will perform a detailed ethics selfassesment and report on this in this deliverable It is related to WP7 managementThis deliverable is related to tasks 72

Identification of initial perovskite absorber composition for each interval of interest

We have selected three main spectral ranges of interest for the development of perovskite semiconductors with different bandgaps Best performing perovskites for each of the bandgap ranges will be identified and used as a starting point From there improvements will be made using compositional changes and also via upscalable processes This deliverable is related to task 11

Publications

Peer reviewed articles (25)

Charge-Phonon Coupling in Tin Halide Perovskites

Author(s): Lorenzo Gatto; Isabella Poli; Daniele Meggiolaro; Federico Grandi; Giulia Folpini; Antonella Treglia; Eugenio Cinquanta; Annamaria Petrozza; Filippo De Angelis; Caterina Vozzi
Published in: ACS Energy Letters, 2025, ISSN 2380-8195
Publisher: American Chemical Society
DOI: 10.1021/ACSENERGYLETT.4C02558

Close-Space Sublimation as a Scalable Method for Perovskite Solar Cells

Author(s): Nathan Rodkey; Inma Gomar-Fernández; Federico Ventosinos; Cristina Roldan-Carmona; L. Jan Anton Koster; Henk J. Bolink
Published in: ACS Energy Letters, 2024, ISSN 2380-8195
Publisher: ACS Publications
DOI: 10.1021/ACSENERGYLETT.3C02794

Effects of Bi and Sb ion incorporation on the optoelectronic properties of mixed lead–tin perovskites

Author(s): F. M. Rombach; L. Gregori; A. Sidler; J. Whitworth; S. Zeiske; H. Jin; E. Y.-H. Hung; S. Motti; P. Caprioglio; A. Armin; M. Lenz; D. Meggiolaro; F. De Angelis; H. J. Snaith
Published in: Journal of Materials Chemistry C, Issue 13, ISSN 2050-7534
Publisher: Royal Society of Chemistry
DOI: 10.1039/D4TC02162B

Nonfullerene Self-Assembled Monolayers As Electron-Selective Contacts for n-i-p Perovskite Solar Cells

Author(s): Drajad S. Utomo; Lauryna M. Svirskaite; Adi Prasetio; Vida Malinauskiene; Pia Dally; Erkan Aydin; Artem Musiienko; Vytautas Getautis; Tadas Malinauskas; Randi Azmi; Stefaan De Wolf
Published in: ACS Energy Letters, Issue 9, 2024, ISSN 2380-8195
Publisher: ACS Publications
DOI: 10.1021/ACSENERGYLETT.4C00306

Vacuum-Deposited Bifacial Perovskite Solar Cells

Author(s): Abhyuday Paliwal; Kassio P. S. Zanoni; Cristina Roldán-Carmona; Nathan Rodkey; Henk J. Bolink
Published in: ACS Energy Letters, 2024, ISSN 2380-8195
Publisher: American Chemical Society
DOI: 10.1021/ACSENERGYLETT.4C01536

Multifunctional sulfonium-based treatment for perovskite solar cells with less than 1% efficiency loss over 4,500-h operational stability tests

Author(s): Jiajia Suo, Bowen Yang, Edoardo Mosconi, Dmitry Bogachuk, Tiarnan A. S. Doherty, Kyle Frohna, Dominik J. Kubicki, Fan Fu, YeonJu Kim, Oussama Er-Raji, Tiankai Zhang, Lorenzo Baldinelli, Lukas Wagner, Ayodhya N. Tiwari, Feng Gao, Andreas Hinsch, Samuel D.
Published in: Nature Energy, Issue 9, 2024, ISSN 2058-7546
Publisher: Nature
DOI: 10.1038/S41560-023-01421-6

How Photogenerated I2 Induces I-Rich Phase Formation in Lead Mixed Halide Perovskites

Author(s): Yang Zhou, Simone C. W. van Laar, Daniele Meggiolaro, Luca Gregori,Samuele Martani, Jia-Yong Heng, Kunal Datta, Jesús Jiménez-López, Feng Wang,E Laine Wong, Isabella Poli, Antonella Treglia, Daniele Cortecchia, Mirko Prato,Libor Kobera, Feng Gao, Ni Zhao,
Published in: Advanced Materials, Issue 36, 2023, ISSN 1521-4095
Publisher: Wiley Online Library
DOI: 10.1002/ADMA.202305567

Room Temperature Pulsed Laser Deposition of Aluminum Zinc Oxide (AZO): Enabling Scalable Indium-Free Transparent Conductive Oxides

Author(s): Joost W. C. Reinders; Jons Bolding; Cristina Roldán-Carmona; Federico Ventosinos; Abhyuday Paliwal; Lidón Gil-Escrig; Francisco Palazon; Michele Sessolo; Kassio P. S. Zanoni; Henk J. Bolink
Published in: Advanced Functional Materials, ISSN 1616-301X
Publisher: Wiley-VCH
DOI: 10.1002/ADFM.202418069

Determining the Ion Mobility in Perovskite Solar Cells from Impedance Spectroscopy

Author(s): Fransien D. Elhorst; Javier E. Sebastián Alonso; Henk J. Bolink; L. Jan Anton Koster
Published in: ACS Energy Letters, 2025, ISSN 2380-8195
Publisher: The American Chemical Society
DOI: 10.1021/ACSENERGYLETT.5C01690

Role of the monovalent cation in the self-doping of tin halide perovskites

Author(s): Isabella Poli; Edoardo Albanesi; Cesare Boriosi; Corinna Ponti; Luca Gregori; Giovanna Bruno; Daniele Meggiolaro; Pietro Rossi; Antonella Treglia; Davide Ruzza; Paola Delli Veneri; Lucia V. Mercaldo; Antonio Abate; Mario Caironi; Filippo De Angelis; Annamaria Petrozza
Published in: EES Solar, 2025, ISSN 3033-4063
Publisher: The Royal Society of Chemistry
DOI: 10.1039/D5EL00010F

Coevaporated Formamidinium Tin Triiodide with Suppressed p-Type Self-Doping

Author(s): Junhyoung Park, Andrea Olivati, Mirko Prato, Min Kim, Annamaria Petrozza
Published in: ACS Energy Letters, Issue 11, 2026, ISSN 2380-8195
Publisher: American Chemical Society (ACS)
DOI: 10.5281/ZENODO.18455148

Origin of Broad Emission Induced by Rigid Aromatic Ditopic Cations in Low-Dimensional Metal Halide Perovskites

Author(s): Marta Morana; Waldemar Kaiser; Rossella Chiara; Benedetta Albini; Daniele Meggiolaro; Edoardo Mosconi; Pietro Galinetto; Filippo De Angelis; Lorenzo Malavasi
Published in: Journal of Physical Chemistry Letters, Issue 14, 2023, ISSN 1948-7185
Publisher: American Chemical Society (ACS)
DOI: 10.26434/chemrxiv-2023-5s4nc

Plasma-Driven Atomic-Scale Tuning of Metal Halide Perovskite Surfaces: Rationale and Photovoltaic Application

Author(s): Alberto Perrotta; Sara Covella; Francesca Russo; Fabio Palumbo; Antonella Milella; Vincenza Armenise; Francesco Fracassi; Aurora Rizzo; Silvia Colella; Waldemar Kaiser; Asma A. Alothman; Edoardo Mosconi; Filippo De Angelis; Andrea Listorti
Published in: Solar RRL, Issue 7, 2023, ISSN 2367-198X
Publisher: Wiley Online Library
DOI: 10.1002/SOLR.202300345

High Light Utilization and Color Rendering in Vacuum‐Deposited Semitransparent Perovskite Solar Cells

Author(s): Abhyuday Paliwal; Manuel Romero; Lennart van den Hengel; Nathan Rodkey; Kassio P. S. Zanoni; Gabriel Lozano; Cristina Roldán‐Carmona; Michele Sessolo; Hernán Míguez; Henk J. Bolink
Published in: Advanced Materials, 2025, ISSN 1521-4095
Publisher: Wiley Online Library
DOI: 10.1002/ADMA.202512861

Stabilizing the Chemistry of NiO<sub>x</sub> in Perovskite Solar Cells to Pass the Damp Heat Test

Author(s): Marion Dussouillez; Mounir Mensi; Ivan Marozau; Quentin Jeangros; Sylvain Nicolay; Christophe Ballif; Adriana Paracchino
Published in: Materials and Sustainability, 2025, ISSN 2982-2785
Publisher: Scilight Press
DOI: 10.53941/MATSUS.2025.100006

How Halide Alloying Influences the Optoelectronic Quality in Tin-Halide Perovskite Solar Absorbers

Author(s): Felix J. Berger, Isabella Poli, Ece Aktas, Samuele Martani, Daniele Meggiolaro, Luca gergori, Munirah D. Albaqami, Antonio Abate, Filippo de Angelis, Annamaria Petrozza
Published in: ACS Energy Letters, Issue 8, 2023, ISSN 2380-8195
Publisher: ACS Publications
DOI: 10.1021/ACSENERGYLETT.3C01241

Asymmetric Triphenylethylene-Based Hole Transporting Materials for Highly Efficient Perovskite Solar Cells

Author(s): Julius Petrulevicius; Yi Yang; Cheng Liu; Matas Steponaitis; Egidijus Kamarauskas; Maryte Daskeviciene; Abdulaziz S. R. Bati; Tadas Malinauskas; Vygintas Jankauskas; Kasparas Rakstys; Mercouri G. Kanatzidis; Edward H. Sargent; Vytautas Getautis
Published in: ACS Applied Materials & Interfaces, Issue 16, 2024, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/ACSAMI.3C17811

Asymmetric Perinone-Based Electron-Collecting Monolayer Materials for n-i-p Perovskite Solar Cells

Author(s): Julius Petrulevicius; Minh Anh Truong; Maryte Daskeviciene; Giedre Bubniene; Shota Hira; Yasuko Iwasaki; Tadas Malinauskas; Atsushi Wakamiya; Vytautas Getautis
Published in: Journal of Materials Chemistry C, ISSN 2050-7526
Publisher: The Royal Society of Chemistry
DOI: 10.1039/D5TC01485A

Rationalizing Electron–Phonon Interactions and Hot Carriers Cooling in 2D to 3D Metal Halide Perovskites

Author(s): Arup Mahata, Edoardo Mosconi, Daniele Meggiolaro, Simona Fantacci, Filippo De Angelis
Published in: Advanced Energy Materials, 2023, ISSN 1614-6840
Publisher: Wiley Online Library
DOI: 10.1002/AENM.202303405

In Situ Thermal Cross-Linking of 9,9′-Spirobifluorene-Based Hole-Transporting Layer for Perovskite Solar Cells

Author(s): Sarune Daskeviciute-Geguziene; Minh Anh Truong; Kasparas Rakstys; Maryte Daskeviciene; Ruito Hashimoto; Richard Murdey; Takumi Yamada; Yoshihiko Kanemitsu; Vygintas Jankauskas; Atsushi Wakamiya; Vytautas Getautis
Published in: ACS Applied Materials & Interfaces, Issue 16, 2023, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/ACSAMI.3C13950

Synergistic Role of Water and Oxygen Leads to Degradation in Formamidinium-Based Halide Perovskites

Author(s): Juanita Hidalgo; Waldemar Kaiser; Yu An; Ruipeng Li; Zion Oh; Andrés-Felipe Castro-Méndez; Diana K. LaFollette; Sanggyun Kim; Barry Lai; Joachim Breternitz; Susan Schorr; Carlo A. R. Perini; Edoardo Mosconi; Filippo De Angelis; Juan-Pablo Correa-Baena
Published in: Journal of the American Chemical Society, Issue 145, 2023, ISSN 0002-7863
Publisher: ACS Publications
DOI: 10.1021/JACS.3C05657

Tuning substrate temperature for enhanced vacuum-deposited wide-bandgap perovskite solar cells: insights from morphology, charge transport, and drift-diffusion simulations

Author(s): Lidón Gil-Escrig; Jasmeen Nespoli; Fransien D. Elhorst; Federico Ventosinos; Cristina Roldán-Carmona; L. Jan Anton Koster; Tom J. Savenije; Michele Sessolo; Henk J. Bolink
Published in: EES Solar, 2025, ISSN 3033-4063
Publisher: The Royal Society of Chemistry
DOI: 10.1039/D5EL00021A

Combining Trivalent Ion-Doping with Halide Alloying to Increase the Efficiency of Tin Perovskites

Author(s): Luca Gregori; Daniele Meggiolaro; Filippo De Angelis
Published in: Small, 2024, ISSN 1613-6829
Publisher: Wiley Online Library
DOI: 10.1002/SMLL.202403413

A universal ligand for lead coordination and tailored crystal growth in perovskite solar cells

Author(s): Bowen Yang, Jiajia Suo, Dmitry Bogachuk, Waldemar Kaiser, Clemens Baretzky, Oussama Er-Raji, Georgios Loukeris, Asma A. Alothman, Edoardo Mosconi, Markus Kohlstädt, Uli Würfel, Filippo De Angelis, Anders Hagfeldt
Published in: Energy & Environmental Science, Issue 4, 2024, ISSN 1754-5706
Publisher: Royal Society of Chemistry
DOI: 10.1039/D3EE02344C

Journal of Materials Chemistry C

Author(s): F. M. Rombach; L. Gregori; A. Sidler; J. Whitworth; S. Zeiske; H. Jin; E. Y.-H. Hung; S. Motti; P. Caprioglio; A. Armin; M. Lenz; D. Meggiolaro; F. De Angelis; H. J. Snaith
Published in: Journal of Materials Chemistry C, 2025, ISSN 2050-7534
Publisher: Royal Society of Chemistry RSC Publishing
DOI: 10.1039/D4TC02162B