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Modelling the chemiosmotic mode of ATP synthesis in protocells

Objective

All modern organisms feature chemiosmosis (ion-motive-force driven processes, including membrane transport and ATP production), and therefore the Last Common Universal Ancestor (LUCA) is believed to be chemiosmotic; although contradictorily. As for chemiosmosis to happen, cells utilise membranes relatively impermeable to the coupling ion (H+ or Na+). It has previously been shown that, theoretically, LUCA could drive chemiosmosis using a geo-chemical H+-gradient but only if it had a leaky membrane. However, a leaky membrane rapidly achieves electrochemical equilibrium offsetting the
H+ influx. For the H+ influx, and therefore chemiosmosis, to continue, the membrane needs a system to pump H+.

Paradoxically, pumping H+ across a leaky membrane is futile. A potential solution has previously been hypothesised in the form of membranes leaky to H+ that harboured: an ATP-synthase coupled to both H+ and Na+, and an antiporter that pumps out Na+ for incoming H+. Such a Na+/H+ antiporter could convert the geochemical H+ gradient into a Na+-gradient. It would be advantageous to do so as a Na+-gradient could be better sustained by the LUCA membrane and could drive ATP production via the promiscuous ATP-synthase. My project aims at obtaining empiricalmvalidation for this hypothesis. To do so, a promiscuous ATP-synthase will be co-reconstituted, alongside a Na+/H+ antiporter, into fatty-acid-containing hybrid liposomes (made from fatty acids and other amphiphilic (phospho)lipids). Ion-gradients will be imposed on the liposomes by pH-jump or
decarboxylase-catalysed alkalisation methods to test whether the system could: a) convert the H+-gradient into a Na+-gradient via the Na+/H+ antiporter, and b) use the Na+- gradient to drive ATP production via the promiscuous ATP-synthase. This study is critical to understand the evolution of chemiosmotic systems and will have implications in evolutionary and synthetic biology as well as astrobiology.

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HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

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(opens in new window) HORIZON-MSCA-2022-PF-01

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Coordinator

RIJKSUNIVERSITEIT GRONINGEN
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 187 624,32
Address
Broerstraat 5
9712CP Groningen
Netherlands

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Activity type
Higher or Secondary Education Establishments
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Total cost

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