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Solid-state cooling under pressure and electric field: novel multicaloric strategies to improve material performance

Project description

Cooling solutions for a greener future

The urgency need for sustainable cooling alternatives has never been clearer. Traditional cooling systems, reliant on the compression and release of potent greenhouse gases, have become major contributors to global warming. With the support of Marie Skłodowska-Curie Actions, the SCOPE project aims to revolutionise the way we keep things cool. Caloric materials, a class of substances known for their unique thermal properties, are at the heart of this endeavour: they offer energy-efficient cooling without harmful emissions. Among these materials, barocalorics (BCs) stand out thanks to their impressive caloric effects and structural resilience. Overall, SCOPE explores the synergy of pressure and electric fields in polar barocaloric materials. By harnessing these multicaloric effects, it will enhance the efficiency and reversibility of BC cooling.

Objective

There is an increasing need to find novel and sustainable alternatives to current dominating cooling systems. These systems are based on the compression and expansion of powerful greenhouse polluters and thus contribute notably to global warming when released to the atmosphere. Caloric materials, which display thermal changes upon variations on the corresponding applied field, are promising candidates because 1) they can be energy efficient and 2) do not compel the direct use of greenhouse gases. Among the different caloric families, those sensitive to hydrostatic pressure (barocalorics (BC)) are of particular interest because of the wide range of candidates, their very large caloric effects and no mechanical breakdown. Nevertheless, BC materials suffer from high intrinsic irreversibilities that limit their caloric efficiency. Interestingly, some BC materials exhibit ferroelectric transitions that make them sensitive to the application of electric fields and, hence, display electrocaloric (EC) effects as well. The goal of this MSCA project is thus to take advantage of multicaloric effects to improve the caloric performance in polar barocaloric materials. To do so, for the first time we will simultaneously apply pressure and an electric field to these materials by performing unprecedented experiments of calorimetry and dielectric spectroscopy under these two fields. From these measurements, we will be able to define novel multicaloric routes to enhance the reversibility and, thus, report improved caloric performances. Additionally, a detailed characterisation of the lattice dynamics will be performed to understand the physical origin of these novel multicaloric strategies. This proposal joins the expertise in barocalorics of the Host Group and the expertise in electrocalorics of the Applicant. The successful achievement of our proposal will represent a breakthrough in the material science community, both at the fundamental and applied level.

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Programme(s)

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Topic(s)

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Funding Scheme

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HORIZON-TMA-MSCA-PF-EF - HORIZON TMA MSCA Postdoctoral Fellowships - European Fellowships

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Call for proposal

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(opens in new window) HORIZON-MSCA-2022-PF-01

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Coordinator

UNIVERSITAT POLITECNICA DE CATALUNYA
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 165 312,96
Address
CALLE JORDI GIRONA 31
08034 BARCELONA
Spain

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Region
Este Cataluña Barcelona
Activity type
Higher or Secondary Education Establishments
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Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

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