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Atomic-scale Photochemistry

Objective

Photochemistry entails natural and artificial reactions that are activated optically, and is at the heart of fundamental processes such as photosynthesis, vision, polymerization, catalysis, or energy conversion Innovative approaches to gain control over photochemical reactions that relied on macro- and mesoscale manipulations of light (e.g. chemistry in an optical cavity, plasmon-enhanced reactions, etc.) were reported recently, but no strategy was proposed to address the photochemistry of a molecule with atomic-scale precision. AETHER aims to provide a disruptive photochemical method whose fundamental concept is based on the manipulation of light with ultimate spatial accuracy. This approach relies on the confinement of a laser excitation pulsed or continuous into an extremely small volume at the apex of a scanning probe tip, eventually acting as a plasmonic picocavity. This confined electromagnetic field can then be moved on top of organic structures where it locally generates photo reactions.

AETHER aims at addressing questions in a wide range of fields related to physical chemistry:

- Can one generate photochemical reactions in a sub-unit of a molecule while preserving the rest of it? Can one use this site-specific approach to synthesize new molecular species?

- To what extent can we deepen our understanding of fundamental natural processes (e.g. energy transfer, photo-isomerization) at play, for example, in photosynthesis and vision?

- Can we combine this atomic-scale optical approach with time-resolved techniques to follow photochemical reactions in real time and real space?

Answering these questions requires probing, manipulating, and exciting molecules with atomic and sub-picosecond precisions. To this end, a scanning probe microscope associated with laser excitation sources will be developed to provide simultaneous spatial, spectral, and temporal control over different types of photochemical reactions.

Fields of science (EuroSciVoc)

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Keywords

Project’s keywords as indicated by the project coordinator. Not to be confused with the EuroSciVoc taxonomy (Fields of science)

Programme(s)

Multi-annual funding programmes that define the EU’s priorities for research and innovation.

Topic(s)

Calls for proposals are divided into topics. A topic defines a specific subject or area for which applicants can submit proposals. The description of a topic comprises its specific scope and the expected impact of the funded project.

Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

HORIZON-ERC - HORIZON ERC Grants

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) ERC-2023-ADG

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Host institution

CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 2 499 534,00
Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 2 499 534,00

Beneficiaries (1)

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