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Handshake Complexes of Chiral Nanoparticles and Proteins

Project description

Chiral nanoparticles for optically active nanofibres

Chirality, the property of lacking mirror symmetry, is a feature of both biological and synthetic materials. While advancements in chiral inorganic nanoparticles have demonstrated their potential across various fields, their tailored design for biological interactions remains a challenge. The ERC-funded CHIRAL-PRO project aims to develop a systematic methodology for engineering chiral NPs with exceptional optical activity, enabling precise enantioselective interactions with biological structures such as proteins and amyloid fibrils. By uncovering the role of chirality in molecular recognition, the project will facilitate the programmed assembly of optically active nanofibres and explore applications in biosensing and metamaterials. This research seeks to deepen our understanding of chiral nanostructures and provide a versatile toolkit for designing them with targeted properties.

Objective

Chirality, or the absence of mirror symmetry, is omnipresent in both biological and abiological forms of matter. Rapid progress has recently been achieved in the synthesis of chiral inorganic nanoparticles (NPs), of great interest because of the giant optical activity observed in individual NPs and their assemblies. Such nanostructures yield chiral features at multiple length scales, resulting in a huge diversity of chiral morphologies. The field is expanding toward connecting chirality across the worlds of nano and bio, linking optical and biological chiral functionalities. However, what is currently hampering real-world applications is the step from intuitive synthesis of chiral nanostructures to a purposeful design for specific interactions with biological components.

The main objective of CHIRAL-PRO is to develop a widely applicable methodology to design chiral NPs with exceptional optical activity, for strong and predictable enantioselective interactions with nanoscale biological entities, such as proteins and amyloid fibrils. The fundamental understanding of the role of chirality in the recognition between inorganic and biological chiral structures will be used for the programmed assembly into optically active nanofibers and for case studies in sensing and metamaterials. To reach this ambitious goal, the complementary expertise of all three partners involved will be essential: synthesis and assembly of chiral plasmonic NPs (Liz-Marzán); three-dimensional electron microscopy of NPs, and the visualization of their interactions with biomolecules in liquid (Bals); and self-assembly methods and computational predictions for chiral multiscale interactions (Kotov).

In addition to groundbreaking advancements in fundamental research, the high gain of this work can be found in the generation of a toolbox enabling the scientific community to shift from guessing to precise design of chiral nanostructures with predefined properties.

Fields of science (EuroSciVoc)

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Programme(s)

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Topic(s)

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Funding Scheme

Funding scheme (or “Type of Action”) inside a programme with common features. It specifies: the scope of what is funded; the reimbursement rate; specific evaluation criteria to qualify for funding; and the use of simplified forms of costs like lump sums.

HORIZON-ERC-SYG - HORIZON ERC Synergy Grants

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Call for proposal

Procedure for inviting applicants to submit project proposals, with the aim of receiving EU funding.

(opens in new window) ERC-2024-SyG

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Host institution

ASOCIACION CENTRO DE INVESTIGACION COOPERATIVA EN BIOMATERIALES- CIC biomaGUNE
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 2 027 350,00
Address
PASEO MIRAMON 182, PARQUE TECNOLOGICO DE SAN SEBASTIAN EDIFICIO EMPRESARIAL C
20009 San Sebastian
Spain

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Region
Noreste País Vasco Gipuzkoa
Activity type
Research Organisations
Links
Total cost

The total costs incurred by this organisation to participate in the project, including direct and indirect costs. This amount is a subset of the overall project budget.

€ 2 027 350,00

Beneficiaries (4)

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