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Hydrogen from Seawater Electrolysis

Project description

Turning seawater into clean hydrogen

Seawater is brimming with potential for producing clean hydrogen, but the current methods of electrolysis face challenges due to performance issues and the high cost of rare materials. In this context, the EU-funded HySEas project is developing a bipolar membrane water electrolyser that combines cation and anion exchange layers with a water-splitting catalyst, all in one unit, specifically designed for seawater. Additionally, the project is breaking new ground by finding ways to extract valuable metals from seawater brine and swapping out rare catalysts like iridium and platinum for more abundant alternatives. With the addition of innovative plasma treatments and advanced simulations, HySEas is paving the way for an efficient and sustainable approach to harnessing hydrogen from the ocean.

Objective

HySEas introduces an innovative approach to direct seawater electrolysis through the integration of a Bipolar Membrane (BPM), incorporating both a cation exchange layer akin to a proton exchange membrane (PEM) and an anion exchange layer similar to anion exchange membrane (AEM) as well as a water dissociation catalyst layer, within a Bipolar Membrane Water Electrolyser (BPMWE) device. Thus far, BPMWEs have been tested using conventional borrowed components from PEM and AEM water electrolysers. These tests have revealed limitations in terms of both durability and overall performance.
Here, the development of the BPMWE is combined with the recovery/reuse of salts and compounds from seawater brine through the development of innovative technological solutions: a) metal ion removal from seawater through direct reduction/photoreduction on oxide particles; and b) oxide particle regeneration through acid treatment to capture and reuse metals. Moreover, the drastic reduction of CRM will be achieved by: a) conducting a mitigation strategy to reduce Ir loading: sputter deposition on powder substrates to deposit the conductive layer of various morphologies between iridium catalyst and TiO2 support; b) using Fe, Ni, Mo oxide catalysts and other high entropy compounds to replace Ir-based catalysts; and c) using metal phosphides, sulphides and carbides (CoP, MoS2, Mo2C, etc.) to replace Pt-based catalysts.
Plasma treatment is used to engineer defects and vacancies and increase the active site density on the catalyst surface as well as to promote transport by manipulating particle size and enhanced pore distribution. HySEas also deploys customized computational models via multiphysics simulations, integrating microkinetic and microscopic models into a novel multiscale model of a salty water electrolyser. Finally, extensive stack assessment is conducted in terms of performance and durability.

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Programme(s)

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Topic(s)

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Funding Scheme

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HORIZON-JU-RIA - HORIZON JU Research and Innovation Actions

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Call for proposal

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(opens in new window) HORIZON-JTI-CLEANH2-2024

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Coordinator

ETHNIKO KENTRO EREVNAS KAI TECHNOLOGIKIS ANAPTYXIS
Net EU contribution

Net EU financial contribution. The sum of money that the participant receives, deducted by the EU contribution to its linked third party. It considers the distribution of the EU financial contribution between direct beneficiaries of the project and other types of participants, like third-party participants.

€ 734 312,50
Address
CHARILAOU THERMI ROAD 6 KM
57 001 THERMI THESSALONIKI
Greece

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Region
Βόρεια Ελλάδα Κεντρική Μακεδονία Θεσσαλονίκη
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Total cost

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Participants (7)

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